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Content available remote Discharge plasma treatment of wood surfaces
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EN
The water contact angle of various wood species treated by radio-frequency discharge (RFD) plasma in air decreased with activation time from 75 up to 40 deg. The growth of water contact angle of plasma-treated wood from 37 up to 68 deg during aging was faster within 2 days after the plasma pre-treatment. The water contact angles of tested wood species showed a steep decrease after activation by RFD plasma in air. Water contact angles were markedly increased during the first 2 days of aging. RFD plasma-treated wood surfaces should be treated up to 2 days after modification by plasma. The unmodified beech wood sample shows lower roughness compared to wood surface treated by RF-plasma. Higher roughness of the plasma-treated wood samples is related to the ablation of amorphous lignin on the surface of the beech wood.
EN
An investigation was made of wood of the species oak (Quercus petraea), beech (Fagus sylvatica L.), maple (Acer pseudoplatanus) and ash (Fraxinus excelsior) pre-treated using radio-frequency (RF) plasma in air at reduced pressure. Physical and chemical changes for all of the wood species were determined using measurements of water contact angles and FTIR-ATR spectroscopy. The results confirmed an increase in the wood’s hydrophilicity/polarity in all cases, caused by an increase in –OH group concentration due to irradiation by RF plasma. The content of oxygen-containing functional groups after treatment by RF plasma significantly increased, and the water contact angles were diminished. FTIR-ATR spectroscopy confirmed that RF plasma modification of the surfaces of all investigated wood samples led to certain changes, which were also dependent on the time of plasma exposure.
EN
The effects of laccase from the white-rot basidiomycete fungus Trametes versicolor on Norway spruce wood (Pices abies) surface were studied. Experiments were performed at room temperature and at pH 4.6, without the addition of mediators. Biological, chemical and physical properties of the treated wood surface were examined by a wood decay test, a scanning electron microscopy (SEM), a Fourier transform infrared (FTIR) spectroscopy and a copper leaching test. Laccase pre-treatment of Norway spruce wood surface was shown to reduce wood decay by brown-rot fungus, Gloeophyllum trabeum and white-rot fungus, Trametes versicolor. SEM images showed expanded wood cell walls, closed pits and a more even surface after laccase treatment. FTIR analysis indicated that laccase not only catalyse depolymerisation of lignin, but also affect other wood cell wall components, such as hemicellulose and cellulose. We showed that laccase treatment altered wood properties in a way that improved wood resistance to decay and prevented leaching of copper from impregnated wood.
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