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Hydrocarbon species in SI and HCCI engine using winter grade commercial gasoline

Elghawi Usama, Mayouf Ahmed, Tsolakis Athanasios

Combustion Engines

2020

R. 59, nr 1

17--24

The study provides a qualitative and quantitative analysis of the C5-C11 hydrocarbon species generated in Spark Ignition - Homogeneous Charge Compression Ignition (SI/HCCI) gasoline direct injection (GDI) engine at range of operating conditions. The presented results and data were obtained from the combustion of winter grade commercial gasoline containing 2% w/w ethanol (C2H5OH) for the engine operated in steady-state, fully warmed-up condition. The hydrocarbon analysis in exhaust gases was executed on a Gas Chromatography-Mass Spectrometer (GC-MS) apparatus directly connected to the engine exhaust via heated line. The highest concentration of the total hydrocarbon emissions was obtained under low load HCCI engine operation at stoichiometric fuel-air ratio. The major hydrocarbon compounds detected in the collected samples were benzene, toluene, p-xylene, and naphthalene. Benzene originates from the incomplete combustion of toluene and other alkylbenzenes which are of considerable environmental interest. During the SI engine operation, increase of the engine speed and load resulted in the increase of benzene and the total olefinic species with simultaneous decrease in isopentane and isooctane. The same trends are seen with the engine operating under HCCI mode, but since the combustion temperature is always lower than SI mode under the same engine conditions, the oxidation of fuel paraffin in the former case was less. As a result, the total olefins and benzene levels in HCCI mode were lower than the corresponding amount observed in SI mode. Aromatic compounds (e.g., toluene), except for benzene, were produced at lower levels in the exhaust when the engine speed and load for both modes were increased.

An overview of emissions of reactive nitrogen compounds from modern light duty vehicles featuring SI engines

Bielaczyc P, Szczotka A., Woodburn J.

Combustion Engines

2014

R. 53, nr 4

48--53

This paper examines emissions of reactive nitrogen compounds in the exhaust gas flux of vehicles featuring spark ignition (SI) engines. A range of technical, legal and environmental aspects are considered. A discussion of the fundamentals of the phenomenon of emission of these compounds is presented, together with a brief summary of the negative environmental impacts of these gases. Selected data obtained during chassis dynamometer testing at BOSMAL are presented, together with certain important observations presented in the technical literature. The reader is directed to recent publications of note for further information on emissions to the less well known reactive nitrogen compounds, namely NH3 and N2O. The orders of magnitude of the various reactive nitrogen compounds found in the exhaust gas emitted from SI engines are briefly considered and commented upon. Data are presented on the impact of different fuel types used in SI engines and the reader is directed to various publications on that subject. Finally, important research directions (both current and future) are identified.

W artykule zawarto analizę problematyki emisji reaktywnych związków azotu w spalinach silników samochodowych o zapłonie iskrowym (ZI). Omówiono przyczyny powstawania tych związków w spalinach silnikowych, ich emisję oraz negatywny wpływ na środowisko. Przedstawiono wybrane wyniki badań emisji reaktywnych związków azotu w odniesieniu do pojazdów zasilanych paliwami konwencjonalnymi i alternatywnymi, uzyskane w testach emisji na hamowni podwoziowej. Prezentowane wyniki porównano do wyników z tego zakresu opisanych w literaturze. Przedstawiono obecne i przyszłe kierunki badań emisji związków azotu w spalinach silnikowych.