The paper discusses several aspects of degradation of Super 304H steel subjected to long-term aging up to 50,000 h at 650 and 750°C. The study includes microstructure examination by scanning and transmission electron microscopy along with X-ray microanalysis of a wide range of precipitates. The Super 304H steel has a structure characteristic for austenitic steels with annealing twins and single primary NBX precipitates of various sizes. Long-term aging leads to precipitation of several phases such as M23C6, MX carbides, σ phases, Z phase and ε-Cu phase. The precipitation processes lead to changes in the creep strength of the tested steel, the value of which strongly depends on the aging temperature used, which is measurably shown by the creep tests carried out with the elongation measured during the test.
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