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EN
This research studied the potential use of local basalt and feldspar from Lampung Province, Indonesia, as glaze materials. Frit(s) are composed of changing basalt-to-feldspar weight ratios of A (30:70), B (50:50), C (70:30), and D (100:0) w/w%. The added 20% boric acid to the total weight reduces the process temperature to 1,000oC with holding times of 1, 4, and 8 hr(s). Based on the chemical composition test of the specimen, the four variations of the sample have SiO2 content above 40%, and the average SiO2/Al2O3 ratio is 4 and 5, which is usually a low-alumina glaze that will cause a glossy effect and have an amorphous structure. At point 2theta 29o, amorphous forms. Quartz (SiO2), albite (NaAlSi3O8), anorthite (CaAl2Si2O8), and coesite (SiO2) phases were discovered in the glaze specimens. The anorthite phase in glass-ceramic glaze gives a transparent glaze color due to the amorphous glassy phase formed during heat treatment. The findings of this study suggest that local materials based on basalt and feldspar may be used as glaze materials to provide a smooth texture and surface; the glaze layer is evenly distributed, can follow the full surface contour of the test specimen, and has low porosity.
EN
Methods for the fabrication of metallic sinters via powder metallurgy techniques have been widely discussed in materials engineering for many years. Depending on the final purpose of the finished products, it is primarily important to ensure their appropriate mechanical properties. Numerous works on this topic are devoted mainly to the modification of conventional metallic materials, and one of the promising research directions is the addition of refractory metals to metal alloys. Thanks to the advantageous impact on thermal stability, mechanical properties, and corrosion resistance, the proposed solutions fit perfectly into the trends of searching for new, functional engineering materials. This work presents a review of scientific reports on the modification of metal alloys with the addition of refractory metals published over the last 15 years. First, a brief characterization of refractory metals along with a description of the basics of processing metallic materials using powder metallurgy are presented. In the following part of the article, the research results on the influence of the addition of high-melting metals on the mechanical properties and corrosion resistance of heavy and light metal alloys are discussed. The conclusion consists of data on the global metal alloys market, taking into account its current state and forecasted changes for the next few years.
PL
Metody spieków metalicznych technikami metalurgii proszków są szeroko omawiane w inżynierii materiałowej od wielu lat. Niezależnie od przewidywanego przeznaczenia gotowych wyrobów istotne jest przede wszystkim zapewnienie produktom odpowiednich własności mechanicznych. Liczne prace poświęcone tej tematyce skupiają się głównie na modyfikacji konwencjonalnych materiałów metalicznych, a jednym z obiecujących kierunków badań jest wzbogacanie stopów metali dodatkiem metali wysokotopliwych. Dzięki korzystnemu wpływowi na stabilność termiczną, własności mechaniczne i odporność na korozję proponowane rozwiązania doskonale wpisują się w poszukiwania nowych, funkcjonalnych materiałów inżynierskich. Praca stanowi przegląd doniesień naukowych opublikowanych w ciągu ostatnich 15 lat, traktujących o modyfikacji stopów metali dodatkiem metali wysokotopliwych. W pierwszej kolejności przedstawiono krótką charakterystykę metali wysokotopliwych wraz z omówieniem podstaw przetwarzania materiałów metalicznych z wykorzystaniem metalurgii proszków. W dalszej części artykułu przeprowadzono analizę wyników badań nad wpływem dodatku metali wysokotopliwych na własności mechaniczne oraz odporność korozyjną stopów metali ciężkich i lekkich. W podsumowaniu przybliżono dane dotyczące stanu globalnego rynku stopów metali wraz z uwzględnieniem zmian prognozowanych na najbliższe lata.
PL
Poferment z fermentacji biomasy (DR) i popiół lotny (FA) zmieszano z biowęglem z osadów ściekowych (SSC) w stosunku 10:10:80 i spiekano w temp. 1050°C. Produkt został zgranulowany z przeznaczeniem na materiały budowlane i przetestowany zgodnie z chińskimi normami krajowymi. Wszystkie wskaźniki jakości granulatu spełniły wymagania chińskich norm krajowych dla granulatu budowlanego. Wskaźnik potencjalnego ryzyka ekologicznego związanego z obecnością metali ciężkich był niski, a produkt był bezpieczny.
EN
Biomass fermentation digestate and fly ash were mixed with sludge biochar in the ratio of 10:10:80 and sintered at 1050°C. The product was pelletized to building materials and tested according to China national stds. All the qual. indicators of the pellets met the requirements of the China national stds. for construction pellets. The potential ecol. risk index of heavy metals was low, and the product was safe.
EN
This paper presents the results of studies on the consolidation of metallic and composite powders by the hot isostaticpressing (HIP) process intended for electrical contact materials. Ag, Cu metallic powders, as well as AgW48Re2, AgRe1 and CuW47Re3 composite powders were used in the investigations. Green compacts for consolidation and hot sintering under pressure were prepared by double-sided axial pressing in steel dies. The density, electrical conductivity, and hardness were measured on the obtained sinters after the HIP process, and the microstructure was examined on selected ones. The research indicates that applying this technology allows good quality electrical material to be obtained, intended for electrical contact material.
EN
Kaolin-based geopolymers are alternatives for producing high-strength ceramics for construction materials. Creating high-performing kaolin ceramics utilizing the regular technique requires a high handling temperature (higher than 1200°C). Thus, the structure and properties such as pore size and distribution are affected at higher sintering temperatures. Along these lines, information with respect to the sintering system and related pore structure is essential for advancing the properties of the previously mentioned materials. This study investigated the microstructure and the density of a kaolin-based geopolymer at various sintering temperatures. The unsintered sample has the highest density of 1610 kg/cm3 , while the samples sintered at 1100°C haves the lowest density of 1203 kg/cm3 . The result also shows that increasing the sintering temperature to 1100°C resulted in increasing the water absorption of the kaolin-based geopolymer ceramic.
EN
The research aims to develop a novel and safer milling route to produce Hard Metals. Considering the risks associated with milling fine particles under organic solvents, especially the increased fire and explosion risks, we propose milling under aqueous milling media to diminish the risks associated with fire hazards, while maintaining the oxidation level at a minimum. The samples were sintered in an industrial sintering oven under vacuum at 1380°C subsequent to milling and drying. The characterisation of the materials has been done by X-ray diffraction, scanning electron microscopy, particle size analysis, optical microscopy, and a magnetometer. The obtained results indicate that appropriate properties of the powders after milling and drying as well as the desired biphasic (Co-WC) phases were obtained after sintering, thus proving the feasibility of such a route and diminishing specific fire hazards.
EN
In this study, the effects of calcite and mica contents in nepheline syenite (NS) samples beneficiated by high intensity dry magnetic separation and flotation methods on ceramic bodies were investigated in detail. The NS samples were, first, sintered to observe the physical and surface roughness properties, and characterized based on the change of NS samples such as color, shrinkage, water absorption, and surface roughness after the sintering process. L-a-b color and Ra, Rz, Rt values for the NS samples were determined. The decrease in calcite and mica contents affected the surface of sintered specimens positively by reducing roughness values. Additionally, the water absorption values were found to be directly proportional to Ra values for unglazed surfaces. In conclusion, calcite and mica minerals in NS samples negatively affected surface quality by forming pinholes due to dehydroxylation and outgassing reactions in the sintering process.
EN
The reliability of the mechanical properties of any product plays an important role in the longevity of the product to work properly under various working conditions. In the present study, the effect of preparing brass alloy on its mechanical properties was experimentally studied. Samples of brass (60% Cu-40% Zn) were prepared by hot iso-stating pressing (HIP) sintering method and some main mechanical tests were performed on them included porosity, density, hardness and compression tests. Results of these tests were compared with corresponding tests on commercial brass alloys produced by casting in order to show the effect of the method of preparing on their mechanical properties. There was a significant improvement in the hardness and strength of the sintered alloy due to the increasing in density and decreasing in porosity comparing with the corresponding other casting's alloys. Results showed an improvement in the density values by 8.4% as a result of the significant reduction in the porosity values from 8.65% to about 0.43%. As a result, the strength of the alloys prepared by the heat pressing method has jumped to a value of 600MPa compared to the traditional castings that have a strength of 343MPa.
EN
This work presents the development of a safer processing route for hard metals. Traditional processing of fine particles under organic solvents presents significant explosion risks. The milling under dichloromethane (DCM) reduces the risks associated with fire hazards. After milling and drying, the samples have been sintered in an industrial sintering furnace under a vacuum at 1380°C. The materials’ characterisation has been done by X-ray diffraction, scanning electron microscopy, particle size analysis, optical microscopy, and by magnetic measurements. The present work results reveal the powders’ appropriate properties after milling and drying and the desired biphasic (Co-WC) phases obtained after sintering, thus proving the feasibility of such a route, therefore the diminishing of specific fire hazards.
PL
W pracy przedstawiono badania odpowiednie do wytworzenia głównego składnika cementu portlandzkiego − krzemianu trójwapnia. Przeprowadzone badania obejmowały ujednorodnienie zestawu, ocenę stałości jego składu z wykorzystaniem rentgenowskiej analizy fazowej w połączeniu z metodą Rietvelda oraz wyniki XRD wytworzonego spieku. Zaprezentowane wyniki potwierdzają adekwatność przyjętych metod badawczych do wytworzenia jednorodnego spieku zawierającego alit (krzemian trójwapnia).
EN
The paper presents tests suitable for the production of the main component of Portland cement - tricalcium silicate. The tests carried out included homogenization of the batch of raw material sets, assessment of the constancy of its composition with the use of X-ray phase analysis in conjunction with the analysis of the results using the Rietveld method, and the XRD results of the sinter produced. The presented results confirm the adequacy of the adopted research methods for the production of a homogeneous sintered alite (tricalcium silicate).
11
Content available remote Nowa metoda wtryskowego formowania szkła jak polimerów
EN
The study investigates the ability to remove copper, tin and arsenic from iron ore, scrap and liquid steel based on the literature and thermodynamic calculations using the FactSage 7.2 software. Methods of removing Cu, Sn and As from iron-bearing materials, feasible in industrial conditions in the near term, were selected. Simulation tests with the use of the FactSage 7.2 software showed that under reduced pressure conditions Cu and Sn can be removed from the steel bath, while As evaporation is not possible. Laboratory tests were carried out, including the removal of Sn and Cu in the process of degassing of liquid steel in a deep vacuum in a vacuum induction furnace and the removal of Sn from iron ore in the sintering process. Under conditions of deep vacuum (below 40 Pa), high temperature (1670°C) and a correspondingly long vacuum treatment time (over 30 minutes), the efficiency of removing the copper and tin contents from the liquid steel of approximately 14 and 17% respectively was obtained. The iron ore sintering test with a high Sn content showed the effectiveness of reducing the Sn content during this process, amounting to approx. 30%.
PL
Zbadano możliwości usuwania miedzi, cyny i arsenu z rudy żelaza, złomu i ciekłej stali na podstawie literatury oraz termodynamicznych obliczeń za pomocą oprogramowania FactSage 7.2. Wybrano sposoby usuwania Cu, Sn i As z materiałów żelazonośnych możliwe do realizacji w warunkach przemysłowych w najbliższej perspektywie czasowej. Badania symulacyjne z zastosowaniem oprogramowania FactSage 7.2 wykazały, że w warunkach obniżonego ciśnienia można usunąć Cu i Sn z kąpieli stalowej, natomiast nie jest możliwe odparowanie As. Przeprowadzono próby laboratoryjne, obejmujące usuwanie Sn i Cu w procesie odgazowania ciekłej stali w głębokiej próżni w próżniowym piecu indukcyjnym oraz usuwanie Sn z rudy żelaza w procesie spiekania. W warunkach głębokiej próżni (poniżej 40 Pa), wysokiej temperatury (1670°C) i odpowiednio długiego czasu obróbki próżniowej (powyżej 30 minut) uzyskano skuteczności usunięcia zawartości miedzi i cyny w ciekłej stali, wynoszące odpowiednio około 14 i 17%. Próba spiekania rudy żelaza z wysoką zawartością Sn wykazała skuteczność zmniejszenia zawartości Sn w czasie tego procesu, wynoszącą ok. 30%.
EN
Aurivillius Bi5Ti3Feo15 (BTF) and Bi5-xNdxTi3Feo15 (BNTF) ceramics were successfully synthesized by a simple solid state reaction method. Ceramics were prepared from simple oxide powders Bi2O3, TiO2, Nd2O3 and Fe2O3. The microstructure, structure, chemical composition and dielectric properties of the obtained materials were examined. Dielectric properties were investigated in a wide range of temperatures (T = 25ºC-550ºC) and frequencies (20Hz-1MHz).
EN
In this study, the effect of the addition of ZrO2 and Al2O3 ceramic powders to Cu-Mo-Cr alloy was studied by examining the physical properties of the composite material. The ceramic additives were selected based on the thermodynamic stability calculation of the Cu-Mo-Cr alloys. Elemental powders, in the ratio Cu:Mo:Cr = 60:30:10 (wt.%), and approximately 0-1.2 wt.% of ZrO2 and Al2O3 were mixed, and a green compact was formed by pressing the mixture under 186 MPa pressure and sintering at 1250°C for 5 h. The raw powders were evenly dispersed in the mixed powder, as observed by scanning electron microscopy. After sintering, the microstructures, densities, electrical conductivities, and hardness of the composites were evaluated. We found that the addition of ZrO2 and Al2O3 increased the hardness and decreased the electrical conductivity and density of the composites.
EN
Aiming at the problems of delay and couple in the sintering temperature control system of lithium batteries, a fuzzy neural network controller that can solve complex nonlinear temperature control is designed in this paper. The influence of heating voltage, air inlet speed and air inlet volume on the control of temperature of lithium battery sintering is analyzed, and a fuzzy control system by using MATLAB toolbox is established. And on this basis, a fuzzy neural network controller is designed, and then a PID control system and a fuzzy neural network control system are established through SIMULINK. The simulation shows that the response time of the fuzzy neural network control system compared with the PID control system is shortened by 24s, the system stability adjustment time is shortened by 160s, and the maximum overshoot is reduced by 6.1%. The research results show that the fuzzy neural network control system can not only realize the adjustment of lithium battery sintering temperature control faster, but also has strong adaptability, fault tolerance and anti-interference ability.
16
Content available remote Zirconium alloyed tungsten borides synthesized by spark plasma sintering
EN
Tungsten borides (WBx; x = 2.5 or 4.5) with an increasing substitution of tungsten by zirconium from 0 to 24 at.% were synthesized by spark plasma sintering (SPS) for the first time. The influence of the holding time (2.5–30 min) on the densification behavior, microstructure evolution and development of the properties of W–Zr–B compounds were studied. The samples were characterized using scanning electron microscopy (SEM) for microstructure analysis, X-ray diffraction (XRD) for phase identification, Vickers micro-indentation for microhardness measurements, tribological tests to determine the coefficient of friction and specific wear rate, as well as measurements of electrical conductivity. The XRD results confirm the presence of the WB4 phase in the microstructure, despite the high sintering temperature (1800 °C) and small overstoichiometric excess of boron (4.5) addition in the sintered samples. This is caused by the high heating rate (400 °C/min), short holding time (2.5 min) and addition of zirconium. The Vickers hardness (HV) values measured at 1 N are 24.8 ± 2.0 and 26.6 ± 1.8 GPa for 24 at.% zirconium in WB2.5 and for 0 at.% zirconium in WB4.5, respectively. In addition, the hardest sample (W0.76Zr0.24B2.5) showed electrical conductivity up to 3.961·106 S/m, which is similar to WC–Co cemented carbides. The friction and wear test results reveal the formation of a boron-based film which seems to play the role of a solid lubricant.
EN
This article describes the manufacturing of silicon carbide composites with the addition of quasi-two-dimensional titanium carbide Ti3C2, known as MXene. The composites were obtained by the powder metallurgy technique, consolidated with the use of the Spark Plasma Sintering method at 1900 °C and dwelled for 30 min. The influence of the Ti3C2 MXene addition on the microstructure and mechanical properties of the composites was investigated. The structure of the MXene phase after the sintering process was also analyzed. The results showed a significant increase (almost 50%) of fracture toughness for composites with the addition of 0.2 wt% Ti3C2 MXene. In turn, the highest hardness, 23.2 GPa, was noted for the composite with the addition of the 1.5 wt% Ti3C2 MXene phase. This was an increase of over 10% in comparison to the reference sample. The analysis of chemical composition and observations using a transmission electron microscope showed that the Ti3C2 MXene phase oxidizes during sintering, resulting in the formation of crystalline, highly defected, disordered graphite structures. The presence of these structures in the microstructure, similarly to graphene, significantly affects the hardness and fracture toughness of silicon carbide.
EN
Purpose: Recently, titanium (Ti) and its alloys have been widely used in dental and surgical implants in the last few decades. However, there is a loosening effect over a long period usage. Therefore, the present study aimed to increase life of an implant by its surface modification. Methods: In present study, sol-gel process has been applied to create tantalum pentoxide (Ta2O5) layer coating on Ti-substrate. In this technique, polyethylene glycol (PEG) plays an important role to form uniform porous coating, which can have potential application in formation of strong bonding to the natural bone. Results: Microstructural, elemental, structural and binding energy results showed that the material with 100% PEG-enhanced sol-gel Ta2O5 with spin coating onto Ti substrate followed by an optimized sintering temperature (500 °C) has better porous structure than that of 5% PEG-enhanced sol-gel Ta2O5 coating, and would be suitable for tissue in-growth properties. Conclusions: Therefore, it was concluded that the present spin coated 100% PEG-enhanced Ta2O5 coating onto Ti, having the most suitable morphology with enhanced roughness, could be noteworthy for potential tissue in-growth and it could provide desired bonding at the interface of Ti-implant coating and host tissues in biomedical applications.
PL
W pracy przedstawiono zastosowanie metody spiekania impulsowo-plazmowego (PPC) w dziedzinie spiekanych kompozytów diamentowych w warunkach termodynamicznej niestabilności diamentu do wytwarzania narzędzi przeznaczonych do cięcia i urabiania różnych kamieni. Węgliki wzmocnione diamentem (DEC – ang. Diamond Enchanced Carbide), w dalszej części tekstu nazywane skrótowo DEC, jako materiał kompozytowy zawierający 30 obj. cząstek diamentu wytworzono, stosując mieszaninę submikronową WC6Co [ wag.]. Dzięki warunkom spiekania PPC uzyskano spieki o wysokiej gęstości z silnym wiązaniem pomiędzy cząstkami diamentu a osnową węglika spiekanego. Badano wartości energii właściwej skrawania i współczynnika tarcia pozornego frezu DEC w porównaniu z podobnymi narzędziami z PCD i zwykłego węglika wolframu. Wyniki badań materiałów DEC spiekanych przez GeniCore potwierdziły dobre perspektywy rynkowe dla tych materiałów do zastosowań w cięciu i górnictwie.
EN
The paper presents the application of the pulse plasma consolidation (PPC) method in the field of diamond composites sintered under conditions of thermodynamic instability of diamond for the manufacture of tools intended for the cutting of different stones. Diamond enhanced carbides (DEC) are a composite material containing 30 vol of diamond particles and were produced using a mixture of submicron WC6Co (wt ). Due to PPC sintering conditions, dense sinters with a strong bond between the diamond particles and the sintered carbide matrix were obtained. The values of the specific cutting energy and the apparent friction coefficient of DEC cutter were investigated in comparison with the similar devices from PCD and ordinary tungsten carbide. DEC materials sintered in GeniCore confirmed the good market prospects for these materials in both cutting and mining applications.
EN
The paper presents the application of the pulse plasma consolidation (PPC) method in the field of diamond composites sintered under conditions of thermodynamic instability of diamond for the manufacture of tools intended for the cutting of different stones. Diamond enhanced carbides (DEC) are a composite material containing 30 vol of diamond particles and were produced using a mixture of submicron WC6Co (wt ). Due to PPC sintering conditions, dense sinters with a strong bond between the diamond particles and the sintered carbide matrix were obtained. The values of the specific cutting energy and the apparent friction coefficient of DEC cutter were investigated in comparison with the similar devices from PCD and ordinary tungsten carbide. DEC materials sintered in GeniCore confirmed the good market prospects for these materials in both cutting and mining applications.
PL
W pracy przedstawiono zastosowanie metody spiekania impulsowo-plazmowego (PPC) w dziedzinie spiekanych kompozytów diamentowych w warunkach termodynamicznej niestabilności diamentu do wytwarzania narzędzi przeznaczonych do cięcia i urabiania różnych kamieni. Węgliki wzmocnione diamentem (DEC – ang. Diamond Enchanced Carbide), w dalszej części tekstu nazywane skrótowo DEC, jako materiał kompozytowy zawierający 30 obj. cząstek diamentu wytworzono, stosując mieszaninę submikronową WC6Co [ wag.]. Dzięki warunkom spiekania PPC uzyskano spieki o wysokiej gęstości z silnym wiązaniem pomiędzy cząstkami diamentu a osnową węglika spiekanego. Badano wartości energii właściwej skrawania i współczynnika tarcia pozornego frezu DEC w porównaniu z podobnymi narzędziami z PCD i zwykłego węglika wolframu. Wyniki badań materiałów DEC spiekanych przez GeniCore potwierdziły dobre perspektywy rynkowe dla tych materiałów do zastosowań w cięciu i górnictwie.
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