Paper presents the application of the photoemission electron spectroscopy (PES) for investigation of the valance band electronic structure of clean CdTe (110) surface relaxed 1 x 1 and this surface sequentially covered by small amount (from 0.2 to 20 ML) of Fe atoms. In the first stages of the Fe depositon (0.2 ML up to 0.6 ML) the creation of the ternary alloy Cd1-xFexTe mainly occurs. For further Fe deposition the Fe layers if formed over the Cd1-xFexTe surface. Diffusion of the Fe atoms occurs under the sample heating, and it leads to the creation of the Fe enriched Cd1-xFexTe ternary alloy.
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