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Microstructure and Corrosion Resistance of Composite nc-TiO2/Ni Coating on 316L Steel

Ledwig P., Dubiel B.

Archives of Metallurgy and Materials

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2017

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Vol. 62, iss. 4

2455--2460

EN

The aim of this work was to obtain composite of nc-TiO2/Ni coatings on 316L steel and to characterize their corrosion resistance. In order to investigate the influence of the addition of TiO2 nanoparticles, both pure Ni and composite nc-TiO2/Ni coatings were electrodeposited from nickel citrate baths. The microstructure of the coatings was examined by scanning and transmission electron microscopy. The nc-TiO2/Ni coatings were about 10 μm thick. Their microstructure consisted of TiO2 nanoparticles uniformly distributed in nanocrystalline Ni matrix. The corrosion resistance of the coatings was measured using impedance spectroscopy and polarization curves techniques in Ringer’s solution. It was determined that the addition of nano-TiO2 particles improved corrosion resistance and reduced corrosion rate of the coated steel.

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Electrophoretic deposition of nc-TiO2/chitosan composite coatings on X2CrNiMo17-12-2 stainless steel

Ledwig P., Kot M., Moskalewicz T., Dubiel B.

Archives of Metallurgy and Materials

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2017

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Vol. 62, iss. 1

405--410

EN

This paper presents the results of the optimization of electrophoretic deposition parameters for manufacturing of nc-TiO2/chitosan composite coatings on X2CrNiMo17-12-2 steel as well as characterization of their microstructure, electrochemical properties and adhesion to the substrate. The parameters of the deposition, such as composition, pH and zeta potential of suspensions as well as voltage and process time were investigated. The microstructure of the coatings was characterized using scanning and transmission electron microscopy. Obtained coatings were crack-free and uniform. The adhesion strength to the substrate was measured by scratch-test method. The deposited coatings improve corrosion resistance of steel, what was confirmed by the results of the potentiodynamic polarization test in Ringer’s solution.

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Preparation and preliminary study of the properties of electrophoretically depositied nc-TiO2 coatings on 316L steel

Ledwig P., Dubiel B.

Inżynieria Materiałowa

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2016

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Vol. 37, nr 6

300--305

EN

TiO2 coatings on 316L steel were obtained by use of electrophoretic deposition (EPD) method. Potential zeta of nc-TiO2 particles in suspensions containing water and ethanol in different ratios was measured. Suspensions’ pH was stabilized by addition of acetic or citric acid and ammonia solution. Addition of citric acid in small amount decreased the zeta potential. Optimal suspensions’ parameters for cathodophoretic and anodophoretic deposition were selected based on the results of zeta potential measurements versus pH for suspensions with different water–ethanol concentration. For the chosen suspensions the rate of TiO2 deposition was measured. Coatings’ cohesion was improved by sintering or addition of biopolymer (chitosan) into suspension. The microstructure of coatings was examined by scanning electron microscopy. The roughness and thickness of the coatings were measured by optical profilometer. The corrosion resistance in Ringer’s solution was examined by use of polarization curves. The corrosion resistance of coated steel was higher than that of uncoated one. For sintered coatings the corrosion currents were lower, but the passive area was larger for not sintered ones. The contact angle of the coatings was measured using a sitting drop method and superhydrophilic properties of TiO2 coatings were confirmed. Manufactured coatings may be potentially used as self-cleaning materials. Additionally, TiO2 coatings improve corrosion resistance of steel and exhibit good bactericidal properties. These characteristics may make this sort of materials potentially useful also for medical purposes.

PL

Celem pracy było wytworzenie powłok nc-TiO2 na stali 316L metodą osadzania elektroforetycznego zarówno anodowego, jak i katodowego, a także zbadanie ich mikrostruktury, odporności na korozję oraz zwilżalności.

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Polimerowe, ceramiczne i kompozytowe powłoki osadzane elektroforetycznie poprawiające wybrane właściwości materiałów metalowych

Moskalewicz T., Dubiel B., Sak A., Ratajski D., Jugowiec D., Ledwig P., Cieniek Ł., Kalemba-Rec I., Radziszewska A., Kopia A., Zimowski S., Kot M., Łukaszczyk A.

Hutnik, Wiadomości Hutnicze

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2016

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Vol. 83, nr 4

170--180

PL

W pracy przedstawiono przykłady wytwarzania różnych powłok polimerowych, ceramicznych i kompozytowych na modelowych materiałach metalowych metodą osadzania elektroforetycznego. W celu uzyskania dobrej jakości powłok dobrano optymalny skład chemiczny roztworów koloidalnych i zawiesin stosowanych do osadzania, wyznaczono ich pH i potencjał elektrokinetyczny dzeta. W oparciu o badania makroskopowe osadzonych powłok dobrano napięcie prądu i czas osadzania elektroforetycznego. Wykonano badania mikrostruktury powłok i ich wybranych właściwości, takich jak odporność na korozję, odporność na zużycie ścierne i wyznaczono współczynnik tarcia. Wykazano, że osadzanie elektroforetyczne jest perspektywiczną metodą wytwarzania powłok: polimerowych (chitozanu i polieteroeteroketonu (PEEK)), ceramicznych (SiO2), kompozytowych (szkło żelowe/chitozan, TiO2/chitozan, SiO2/HA i Ni/SiO2) oraz porowatych (szkło żelowe/PEEK).

EN

This work presents the examples of electrophoretic deposition of various polymer, ceramic and composite coatings on model metallic materials. To obtain good quality coatings, chemical composition of colloidal solutions and suspensions as well as their pH and Zeta potential were optimized. The voltage and deposition time were experimentally selected by macroscopic examination of as-deposited coatings. Investigation of the coatings comprised microstructural analysis as well as determination of their corrosion resistance, wear resistance and friction coefficient. It was demonstrated that electrophoretic deposition is a prospective method for obtaining various coatings: polymer chitosan and polyetheroetheroketone (PEEK), ceramic SiO2, composite gel glass/chitosan, TiO2/chitosan, SiO2/HA and Ni/SiO2 as well as porous sol-gel glass/PEEK coatings.