PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
Tytuł artykułu

Elemental and mineral inventory of tailing impoundments near Pezinok, Slovakia and possible courses of action for their remediation

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
An effective remediation strategy for a polluted site should take the absolute amount of the pollutant(s) into account. Here, we present an elemental budget for As, Sb and Fe in two tailing impoundments of the former Sb-Au deposit near Pezinok, Slovakia. The two impoundments contain 5,740 X103 kg As, 6,360 X103 kg Sb and 50,105 X103 kg Fe. An estimated total Au content in the impoundments is 132 kg. The most abundant minerals in the tailings are quartz, illite, and chlorite. The content of carbonates in the tailings is 3.5-10.5 wt% calcite equivalent and we estimate that the carbonates are sufficiently abundant to buffer the pH at circumneutral values, up to the point when all pyrite decomposes. The possible courses of action are i) do nothing, ii) build an active barrier to capture the released As and Sb, iii) isolate the impoundments from rain and ground water and iv) use the impoundments as a source of Sb and redeposit the waste in a safer form. The simplest approach is to do nothing, which seems to be the most likely course of events, given the current economic, political and societal state of the Slovak Republic. Although this action costs nothing in the short term, it may cause significant damage to the environment, especially to the alluvial sediments and associated water resources in the long term.
Słowa kluczowe
Czasopismo
Rocznik
Strony
55--74
Opis fizyczny
Bibliogr. 26 poz., rys., tab., wykr.
Twórcy
autor
  • Institute of Geosciences, Burgweg 11, Friedrich-Schiller University, Jena, D-07749 Germany
autor
  • Institute of Geosciences, Albertstraße 23b, Albert-Ludwig University, Freiburg, D-79104, Germany
autor
  • Department of Mineralogy and Petrology, Mlynská dolina G, Comenius University, Bratislava, SK-842 15, Slovakia
autor
  • Department of Mineralogy and Petrology, Mlynská dolina G, Comenius University, Bratislava, SK-842 15, Slovakia
  • Department of Zoology and Anthropology, Nábrežie Mládeže 91, Constantine the Philosopher University, SK-949 74 Nitra, Slovakia
autor
  • Department of Geology of Mineral Deposits, Mlynská dolina G, Comenius University, Bratislava, SK-842 15, Slovakia
Bibliografia
  • Ahmed, M.F. (2001). An overview of arsenic removal technologies in Bangladesh and India. Proceedings of the BUET-UNU International Workshop on Technologies for Arsenic Removal from Drinking Water, Bangladesh University of Engineering and Technology, Dhaka, Bangladesh.
  • Ali, M.A., Badruzzaman, A.B.M., Jalil, M.A., Hossain, M.D., Hussainuzzaman, M.M., Badruzzaman, M., Mohammad, O.I., & Akter, N. (2001). Development of low-cost technologies for removal of arsenic from groundwater. Proceedings of the BUET-UNU International Workshop on Technologies for Arsenic Removal from Drinking Water, Bangladesh University of Engineering and Technology, Dhaka, Bangladesh.
  • Arvensis, M., Tupý, P., Kupcová, Z., Fodorová, V., Mudráková, M., Čechovská, K., Čamaj, P., & Klačan, J. (1994). Dúbrava – tailings, preliminary research. Manuskript – Geologický prieskum Spišská Nová Ves, 188 pp. (in Slovak).
  • Beránek, M. (Ed.) (1977). 30th anniversary of Rudné bane Banská Bystrica. Martin: Osveta. (in Slovak).
  • Chovan, M., Andráš, P., Čerňanský, S., Dlapa, P., Fľaková, R., Hudáček, M., Krčmář, D., Kušnierová, M., Lalinská, B., Lux, A., Majzlan, J., Milovská, S., Moravanský, D., Ševc, J., Šimonovičová, A., Šlesárová, A., Šottník, P., Uhlík, P., Urík, M., & Ženišová, Z. (2006). Determination of the contamination risk in the vicinity of the Sb, Au, S deposit Pezinok and a proposal for remediation: Toxicity of As, Sb, and acidification. Bratislava: Comenius University (Project no. AV/901/2002 (VTP25), final report) (in Slovak).
  • Filippi, M., Goliáš, V., & Pertold, Z. (2004). Arsenic in contaminated soils and anthropogenic deposits at the Mokrsko, Roudný, and Kašperské Hory gold deposits, Bohemian Massif (CZ). Environmental Geology, 45, 716-730.
  • Fľaková, R., Ženišová, Z., Drozdová, Z., & Milovská, S. (2005). Distribution of arsenic in surface and groundwater in Kolársky vrch mining area (Malé Karpaty Mts.). Podzemná Voda, 9, 90-103. (in Slovak with English summary).
  • Grexová, A. (1991). Mineralogy of the technological products at the Sb deposit Pezinok. Unpublished Diploma thesis, Comenius University, Bratislava. (in Slovak).
  • Heikkinen, P.M., Räisänen, M.L., & Johnson, R.H. (2009). Geochemical characterisation of seepage and drainage water quality from two sulphide mine tailings impoundments: Acid mine drainage versus neutral mine drainage. Mine Water and the Environment, 28, 30-49.
  • Koděra, M., Andrusovová-Vlčeková, G., Belešová, O., Briatková, D., Dávidová, Š., Fejdiová, V., Hurai, V., Chovan, M., Nelišerová, E., & Ženiš, P. (1990). Topographic mineralogy of Slovakia, Band 2. Bratislava: Veda, vyd. Slovenskej akadémie vied.
  • Lindsay, M.B.J., Condon, P.D., Jambor, J.L., Lear, K.G., Blowes, D.W., & Ptacek, C.J. (2009). Mineralogical, geochemical and microbial investigation of a sulfide-rich tailings deposit characterized by neutral drainage. Applied Geochemistry, 24(12), 2212-2221. DOI: 10.1016/j.apgeochem.2009.09.012.
  • Loredo, J., Ordónez, A., Baldo, C., & García-Iglesias, J. (2003). Arsenic mobilization from waste piles of the El Terronal mine, Asturias, Spain. Geochemistry: Exploration, Environment, Analysis, 3, 229-237.
  • Majzlan, J., Lalinská, B., Chovan, M., Jurkovič, L., Milovská, S., & Göttlicher, J. (2007). The formation, structure, and ageing of As-rich hydrous ferric oxide at the abandoned Sb deposit Pezinok (Slovakia). Geochimica Cosmochimica Acta, 71, 4206-4220.
  • Majzlan, J., Chovan, M., Andráš, P., Newville, M., & Wiedenbeck, M. (2010). The nanoparticulate nature of invisible gold in arsenopyrite from Pezinok (Slovakia). Neues Jahrbuch für Mineralogie Abhandlungen, 187, 1-9.
  • Majzlan, J., Lalinská, B., Chovan, M., Bläß, U., Brecht, B., Göttlicher, J., Steininger, R., Hug, K., Ziegler, S., & Gescher, J. (2011). A mineralogical, geochemical, and microbiogical assessment of the antimony- and arsenic-rich neutral mine drainage tailings near Pezinok, Slovakia. American Mineralogist, 96(1), 1-13. DOI: 10.2138/am.2011.3556
  • Moldovan, B.J., & Hendry, M.J. (2005). Characterizing and quantifying controls on arsenic solubility over a pH range of 1-11 in a uranium mill-scale experiment. Environmental Science & Technology, 39, 4913-4920.
  • Moravanský, D., Chovan, M., & Lipka, J. (2001). Phyllosilicates from hydrothermally altered granitoid rocks in the Pezinok Sb-Au deposit, Western Carpathians, Slovakia. Geologica Carpathica, 52, 127-138.
  • Moore, D.M., & Reynolds, R.C. (1997). X-Ray Diffraction and the Identification and Analysis of Clay Minerals (2 ed.). New York: Oxford University Press, USA.
  • Paktunc, D., Foster, A., & Laflamme, G. (2003). Speciation and characterization of arsenic in Ketza River mine tailings using X-ray absorption spectroscopy. Environmental Science & Technology, 37, 2067-2074.
  • Pomorský, F., Hanas, P., Mokráš, L., Bendíková, Z., & Stašík, Ľ. (2002). Complex evaluation of the closed deposit Pezinok. Bratislava, Slovakia: Ministry of the Environment of the Slovak Republic. (in Slovak).
  • Rauret, G., López-Sánchez, J.F., Sahuquillo, A., Rubio, R., Davidson, C., Ure, A., & Quevauviller, P. (1999). Improvement of the BCR three step sequential extraction procedure prior to the certification of new sediment and soil reference materials. Journal of Environmental Monitoring, 1, 57-61.
  • Root, R.A., Dixit, S., Campbell, K.M., Jew, A.D., Hering, J.G., & O'Day, P.A. (2007). Arsenic sequestration by sorption processes in high-iron sediments. Geochimica et Cosmochimica Acta, 71, 5782-5803.
  • Simonic, M. (2009). Removal of inorganic As5+ from a small drinking water system. Journal of the Serbian Chemical Society, 74, 85-92.
  • Suter II, G.W., & Tsao, C.L. (1996). Toxicological Benchmarks for Screening Potential Contaminants of Concern for Effects on Aquatic Biota. 1996 Revision. Oak Ridge, Tennessee: Oak Ridge National Laboratory. (ES/ER/TM-96/R2; http://www.hsrd.ornl.gov/ecorisk/tm96r2.pdf).
  • Tapak, M., Kiripolský, J., Richter, S., & Slavkovská, M. (1990). Geological reserves of ore deposits of the Slovak Republic as of January 1, 1990. Bratislava: Geofond Bratislava. (in Slovak).
  • Wills, B.A. (2008). Wills’ Mineral Processing Technology (7 ed.). Oxford: Butterworth-Heinemann.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-f836fbf5-d8dd-4dda-b675-b2e017940c87
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.