Synthesis and photochemical stability of acrylamide and succinic anhydride copolymer with dyes

• Autorzy: Mousa Souad A. , Awad Sana Hitur , Martincigh Bice S. , Al-Baidhani Mohammed

Identyfikatory

DOI

10.14314/polimery.2024.11.1

Warianty tytułu

PL

Synteza i stabilność fotochemiczna kopolimeru akrylamidu i bezwodnika bursztynowego z barwnikami

• Języki publikacji: EN

Abstrakty

EN

A copolymer of acrylamide (PAM) and succinic anhydride (SA) was obtained. The effect of dye (anthocyanin, bromophenol blue, thymol blue) on the photochemical stability of the copolymer (PAM-g-SA) was studied. X-ray diffraction, FT-IR, UV-Vis, NMR, DSC and TGA were used to evaluate PAM-g-SA. FT-IR analysis showed the disappearance of two bands at wavenumbers 3450 and 3380 cm-1 characteristic of the stretching vibrations of the primary amine, which indicates the formation of amides. UV photolysis of aqueous solutions with different concentrations of the copolymer was studied. PAM-g-SA showed an increase in the degree of polymerization under the influence of light (ca. 50%) for a solution of 200 mg/L after 10 h of irradiation. PAM-g-SA-anthocyanin also showed an increase in the degree of polymerization (26%) for the 1000 mg/L solution after 10 h of irradiation. Similar behavior was observed for anthocyanin (23%) at the dye concentration of 15000 mg/L. On the other hand, PAM-g-SA-bromophenol and PAM-g-SA-thymol were photodegraded after UV irradiation. It was shown that the photodegradation of PAM-g-SA can be prevented by the addition of appropriate dye.

PL

Otrzymano kopolimer akrylamidu (PAM) i bezwodnika bursztynowego (SA). Zbadano wpływ dodatku barwnika (antocyjan, bromofenol, tymol) na stabilność fotochemiczną kopolimeru (PAM-g-SA). Do oceny PAM-g-SA stosowano dyfrakcję rentgenowską, FT-IR, UV-Vis, NMR, DSC i TGA. Analiza FT-IR wykazała zanik dwóch pasm przy liczbie falowej 3450 i 3380 cm-1 charakterystycznych dla drgań rozciągających aminy pierwszorzędowej, co wskazuje na tworzenie się amidów. Zbadano fotolizę UV roztworów wodnych o różnych stężeniach kopolimeru. PAM-g-SA wykazał wzrost stopnia polimeryzacji pod wpływem światła (ok. 50%) dla roztworu 200 mg/L po 10 h naświetlania. PAM-g-SA-antocyjan również wykazał wzrost stopnia polimeryzacji (26%) dla roztworu 1000 mg/L po 10 h naświetlania. Podobne zachowanie zaobserwowano w przypadku antocyjanu (23%) przy stężeniu barwnika 15 000 mg/L. Natomiast PAM-g-SA-bromofenol i PAM-g-SA- tymol uległy fotodegradacji po naświetlaniu UV. Wykazano, że fotodegradacji PAM-g-SA można zapobiec poprzez dodatek odpowiedniego barwnika.

Słowa kluczowe

EN

polyacrylamide; photodegradation; anthocyanin; bromophenol blue; thymol blue

PL

poliakrylamid; fotodegradacja; antocyjany; błękit bromofenolowy; błękit tymolowy

• Wydawca: Sieć Badawcza Łukasiewicz – Instytut Chemii Przemysłowej
• Czasopismo: Polimery
• Rocznik: 2024
• Tom: Vol. 69, nr 11-12
• Strony: 619--634
• Opis fizyczny: Bibliogr. 40 poz., rys., tab., wykr.

Twórcy

autor

Mousa Souad A.

• Department of Chemistry, College of Science for Women, University of Baghdad, Baghdad 10071, Iraq

• https://orcid.org/0000-0001-6333-3417

autor

Awad Sana Hitur

• Department of Chemistry, College of Science for Women, University of Baghdad, Baghdad 10071, Iraq

• https://orcid.org/0000-0003-1973-8745

autor

Martincigh Bice S.

• School of Chemistry and Physics, University of KwaZulu-Natal, Westville Campus, Private Bag X54001, Durban 4000, South Africa

• https://orcid.org/0000-0003-1426-5328

autor

Al-Baidhani Mohammed

• Department of Physics, College of Science, Al-Nahrain University, 10072 Baghdad, Iraq

Bibliografia

• [1] Awad S.H., Saeed R.S., Hussein F.A.: Biochemical and Cellular Archives 2020, 20(2), 6317.
• [2] Adel N., Hassan S.S., Awad S.H.: Journal of Green Engineering 2021, 11(2), 1195.
• [3] Awad S.H., Sahib S.A., Hussein F.A. et al.: IOP Conference Series: Materials Science and Engineering 2019, 571, 012093. https://doi.org/10.1088/1757-899X/571/1/012093
• [4] Alsahib S.A.: Baghdad Science Journal 2020, 17(2), 471, https://doi.org/10.21123/bsj.2020.17.2.0471
• [5] Al Sahib S.A., Awad S.H.: Baghdad Science Journal 2022, 19(6), 1265. https://doi.org/10.21123/bsj.2022.5655
• [6] Saeed R.S., Hussein F.A., Awad S.H. et al.: Journal of Physics: Conference Series 2021, 1879, 022070. https://doi.org/10.1088/1742-6596/1879/2/022070
• [7] Awd S.H., Mahmood T.A., Hussein F.A. et al.: International Journal of Pharmaceutical Research 2019, 11(4), 1238.
• [8] Hussein F.A., Awd S.H., Abdulsahib S. et al.: Journal of Global Pharma Technology 2019, 11(2), 466.
• [9] Wang W., Wang J., Zhao Y. et al.: Environmental Pollution 2020, 257, 113574. https://doi.org/10.1016/j.envpol.2019.113574
• [10] Lazzari S., Pfister D., Diederich V. et al.: Industrial and Engineering Chemistry Research 2014, 53(22), 9035. https://doi.org/10.1021/ie403544d
• [11] Rigolini J., Bombled F., Ehrenfeld F. et al.: Macromolecules 2011, 44(11), 4462. https://doi.org/10.1021/ma200706j
• [12] Alb A.M., Enohnyaket P., Craymer J.F. et al.: Macromolecules 2007, 40(3), 444. https://doi.org/10.1021/ma062241i
• [13] He G., He T., Lu P. et al.: Journal of Applied Polymer Science 2022, 139(24), 52371. https://doi.org/10.1002/app.52371
• [14] Hood C., de Souza V.R., Keener K. et al.: Journal of Applied Polymer Science 2022, 139(18), 52072. https://doi.org/10.1002/app.52072
• [15] Yoosefian M., Pakpour A., Zahedi M.: Physica E: Low-dimensional Systems and Nanostructures 2020, 124, 114299. https://doi.org/10.1016/j.physe.2020.114299
• [16] Salas S.D., Romagnoli J.A., Tronci S. et al.: Computers and Chemical Engineering 2019, 126, 391. https://doi.org/10.1016/j.compchemeng.2019.04.026
• [17] Caulfield M.J., Qiao G.G., Solomon D.H.: Chemical Reviews 2002, 102(9), 3067. https://doi.org/10.1021/cr010439p
• [18] Caulfield M.J., Hao X., Qiao G.G. et al.: Polymer 2003, 44(5), 1331. https://doi.org/10.1016/S0032-3861(03)00003-X
• [19] Zamani-Babgohari F., Irannejad A., Kalantari Pour M. et al.: International Journal of Biological Macromolecules 2024, 269(1), 132053. https://doi.org/10.1016/j.ijbiomac.2024.132053
• [20] Sawut A., Wu T., Simayi R. et al.: Polymers 2023, 15(20), 4174. https://doi.org/10.3390/polym15204174
• [21] Lin X., Liu Z., Chen R. et al.: International Journal of Biological Macromolecules 2023, 246, 125613. https://doi.org/10.1016/j.ijbiomac.2023.125613
• [22] Mula S., Ray A.K., Banerjee M. et al.: The Journal of Organic Chemistry 2008, 73(6), 2146. https://doi.org/10.1021/jo702346s
• [23] Plouzeau M., Piogé S., Peilleron F. et al.: Journal of Applied Polymer Science 2022, 139(36), e52861. https://doi.org/10.1002/app.52861
• [24] Jackman R.L., Smith J.L.: “Anthocyanins and betalains” in “Natural Food Colorants” (edit.: Hendry G.A.F., Houghton J.D.), Springer, Boston 1996. p. 244. https://doi.org/10.1007/978-1-4615-2155-6_8
• [25] Sauer T., Neto G.C., José H. et al.: Journal of Photochemistry and Photobiology A: Chemistry 2002, 149(1-3), 147. https://doi.org/10.1016/S1010-6030(02)00015-1
• [26] Edinger D., Weber H., Žagar E. et al.: ACS Applied Polymer Materials 2021, 3(4), 2018. https://doi.org/10.1021/acsapm.1c00084
• [27] Zhang H.P., Cao J.J., Jiang W.B. et al.: Energies 2022, 15(15), 5714. https://doi.org/10.3390/en15155714
• [28] Patterson A.L.: Physical Review 1939, 56, 978. https://doi.org/10.1103/PhysRev.56.978
• [29] Noreen H., Iqbal J., Arshad A. et al.: Journal of Solid State Chemistry 2019, 275, 141. https://doi.org/10.1016/j.jssc.2019.03.045
• [30] Buenviaje S.C., Usman K.A.S., Payawan L.M.: AIP Conference Proceedings 2018, 1958(1), 020015. https://doi.org/10.1063/1.5034546
• [31] Fatimah I., Pratiwi E.Z., Wicaksono W.P.: Egyptian Journal of Aquatic Research 2020, 46(1), 35. https://doi.org/10.1016/j.ejar.2020.01.001
• [32] Khan Z., Ali F., Said A. et al.: Environmental Research 2022, 215(2), 114148. https://doi.org/10.1016/j.envres.2022.114148
• [33] Razavi M.R., Absalan Y., Gholizadeh M. et al.: Environmental Technology and Innovation 2022, 26, 102385. https://doi.org/10.1016/j.eti.2022.102385
• [34] Azmat R., Khalid Z., Haroon M. et al.: Advances in Natural Science 2013, 6(3), 38.https://doi.org/10.3968/j.ans.1715787020130603.1628
• [35] Kisała J., Ferraria A.M., Mitina N. et al.: RSC Advances 2022, 12, 22465. https://doi.org/10.1039/D2RA03362C
• [36] Chabalala M.B., Zikalala S.A., Ndlovu L. et al.: Chemical Engineering Research and Design 2023, 197, 307. https://doi.org/10.1016/j.cherd.2023.07.029
• [37] Cong Q., Ren M., Zhang T. et al.: RSC Advances 2021, 11, 29896. https://doi.org/10.1039/D1RA04533D
• [38] Shimada T., Tochinai K., Hasegawa T.: Bulletin of the Chemical Society of Japan 2019, 92(10), 1759. https://doi.org/10.1246/bcsj.20190118
• [39] Hussein F.H., Alkhateeb A.N., Ismail J.K.: E-Journal of Chemistry 2008, 5(2), 243. https://doi.org/10.1155/2008/936751
• [40] Mohamed A.J., Ibtesam A., Firas H.A.: AIP Conference Proceedings 2020, 2213, 020315. https://doi.org/10.1063/5.0000032

Uwagi

Opracowanie rekordu ze środków MNiSW, umowa nr POPUL/SP/0154/2024/02 w ramach programu "Społeczna odpowiedzialność nauki II" - moduł: Popularyzacja nauki (2025).