Spektrofotometryczne i elektrochemiczne metody oznaczania aktywności antyoksydacyjnej

Małyszko, J.; Karbarz, M.

Artykuł - szczegóły

Tytuł artykułu

Spektrofotometryczne i elektrochemiczne metody oznaczania aktywności antyoksydacyjnej

Autorzy

Małyszko J. , Karbarz M.

Wybrane pełne teksty z tego czasopisma

Identyfikatory

Warianty tytułu

Spectrophotometric and electrochemical methods for determination of antioxidant activity

Języki publikacji

Abstrakty

In the last decades, free radicals have been discussed to play a key role in the pathology of several diseases, such as cancer, artheriosclerosis or inflammatory diseases [1, 2]. Numerous dietary antioxidants, e.g. vitamin C, phenolic and polyphenolic compounds as well as carotenoides are considered as effective agents in prevention of these diseases [4]. The chemical diversity of antioxidants occurring in food makes it difficult to separate individual antioxidant compounds from the animal or vegetable matrix and quantify them. Antioxidant activity is widely used as a parameter to characterize the redox status of different biological or dietary samples. Many analytical methods for determining of total antioxidant activity (TAA) have been proposed in the literature of the last decade. The present review deals with the methods involving electron-transfer reactions with chromogen compounds: the trolox equivalent antioxidant capacity (TEAC) [6-29], the DPPH assay [31-41], the ferric reducing antioxidant power (FRAP) assay [42-48], the cupric reducing antioxidant capacity (CUPRAC) assay [49-55], and the Folin-Ciocalteu (FC) method [56]. These assays enable to measure the activity of an antioxidant through the reduction of an oxidizing agent, which changes colour during the redox reaction. The degree of colour change corresponds to the concentration of antioxidant in the sample. The main purpose of this review is to describe and discuss the chemical fundamentals of these methods. The applications of voltammetry and other electroanalytical methods were also demonstrated [58-71]. In addition, properties and the use of reference compounds in the antioxidant activity assessment was considered [72-85]. The summary contains conclusions on the scope of application, the most important advantages and shortcomings of the methods described [50, 86-88].

Słowa kluczowe

antyoksydanty przeciwutleniacze wolne rodniki całkowita aktywność antyoksydacyjna

antioxidants free radicals total antioxidant capacity

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Wiadomości Chemiczne

Rocznik

2009

Tom

[Z] 63, 1-2

Strony

17--38

Opis fizyczny

bibliogr. 94 poz., wykr.

Twórcy

autor

Małyszko J.

autor

Karbarz M.

Uniwersytet Humanistyczno-Przyrodniczy Jana Kochanowskiego, Instytut Chemii, ul. Świętokrzyska 15, 25-408 Kielce, malyszko@pu.kielce.pl

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Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUS5-0017-0038