Metal-Ion-Directed Synthesis of the New Macrocyclic and Acyclic Homo- and Heterodinuclear Schiff Base Complexes Derived from Putrescine

• Autorzy: Radecka-Paryzek W. , Kaczmarek M. , Luks E. , Pospieszna-Markiewicz I.
• Języki publikacji: EN

Abstrakty

EN

The template reaction of 2,6-diacetylpyridine with putrescine, a biogenic diamine, in the presence of lanthanum(III) and zinc(II) ions produces homo- and heteronuclear complexes of 22-membered macrocyclic ligand with an N6 set of donor atoms as a result of the [2+2] Schiff base cyclocondensation. Complexes containing Schiff base acyclic ligands terminated by two carbonyl groups or one carbonyl and one amine group as products of the partial metal-promoted condensation have been also isolated. They might be regarded as possible intermediates in the formation of the macrocyclic complexes. The complexes have been characterized by spectral data (IR, 1H NMR, ESI-MS) and elemental analyses.

Słowa kluczowe

EN

dinuclear complexes; Schiff base macrocycles; Schiff base acyclic complexes; lanthanum; zinc; template synthesis

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2005
• Tom: Vol. 79 / nr 10
• Strony: 1597--1604
• Opis fizyczny: Bibliogr. 26 poz., rys.

Twórcy

autor

Radecka-Paryzek W.

• Department of Bioinorganic Chemistry, Adam Mickiewicz University, 60-780 Poznań, Poland

autor

Kaczmarek M.

• Department of Bioinorganic Chemistry, Adam Mickiewicz University, 60-780 Poznań, Poland

autor

Luks E.

• Department of Bioinorganic Chemistry, Adam Mickiewicz University, 60-780 Poznań, Poland

autor

Pospieszna-Markiewicz I.

• Department of Bioinorganic Chemistry, Adam Mickiewicz University, 60-780 Poznań, Poland

Bibliografia

• 1.Vigato P.A. and Tamburini S., Coord. Chem. Rev., 248, 1717 (2004).
• 2.Sakamoto M., Manaseki K. and Okawa H., Coord. Chem. Rev., 219-221, 379 (2001).
• 3.Fenton D.E., Chem. Soc. Rev., 28, 159 (1999).
• 4.Roat-Malone R.M, Bioinorganic Chemistry, Wiley-lnterscience, New Jersey, 2002.
• 5.Haner R. and Hall J., Antiseme Nucleic Acid Drug Dev., 7, 423 (1997).
• 6.Pratviel G., Bernadou J. and Meunier B., Adv. Inorg. Chem., 45, 251 (1998).
• 7.Franklin S.J., Curr. Opin. Chem. Biol., 5, 201 (2001).
• 8.Liu C., Wang M., Zhang T. and Sun H., Coord. Chem. Rev., 248, 147 (2004).
• 9.Koike T., Takashige M., Kimura E., Fujioka H. and Shiro M., Chem. Eur. J., 2, 617 (1996).
• 10.Inouye Y., Kanamori T., Sygiyama M., Yoshida T., Koike T., Shionoya M., Enomoto K., Suehtro K and Kimura E., Antiviral Chem. Chemotherapy, 6, 337 (1995).
• 11.Bunzli J.-C.G. and Piguet C., Chem. Rev., 102, 1897 (2002) and refs therein.
• 12.Karigiannis G. and Papaioannou D., Eur. J. Org. Chem., 1841 (2000).
• 13.Bums M.R., Carlson C.L., VanderwerfS.M.,Ziemer J.R., Weeks R.S., Cai F., Webb H.K. and Gramin: G.F., J. Med. Chem., 44, 3632 (2001).
• 14.Radecka-Paryzek W., Patroniak V. and Lisowski J., Coord. Chem. Rev., in press, available online 5 April 2005.
• 15.Radecka-Paryzek W., Kaczmarek M., Patroniak V. and Pospieszna-Markiewicz I., Inorg. Chem. Commun., 6, 26 (2003).
• 16.Kaczmarek M., Pospieszna-Markiewicz I. and Radecka-Paryzek W.,J. Inclusion Phenom. Macrocyc Chem., 49, 115(2004).
• 17.Pospieszna-Markiewicz I. and Radecka-Paryzek W., J. Alloys Compd., 374, 254 (2004).
• 18.Patroniak V., Kubicki M., Mondry A., Lisowski J. and Radecka-Paryzek W., Dalton Trans., 3295 (200'
• 19.Caneschi A., Sorace L., Casellato U., Tomasin P. and Vigato P.A., Eur. J. Inorg. Chem., 3887 (2004
• 20.Videva V., Chauvin A.-S., Varbanov S., Baux C., Scopelliti R., Mitcwa M. and BUnzli J.-C.G., Eur. Inorg. Chem., 2173 (2004).
• 21.Nierengarten H., Rojo J., Leize E., Lehn J-M. and Van Dorsselaer A., Eur. J. Inorg. Chem., 513 (2002).
• 22.Romero F.M., Ziessel R., Dupont-Gervais A. and Van Dorsselaer A., Chem. Commun., 551 (1996).
• 23.Williams S.M., Brodbelt J.S., Marchand A.P.,CaI D. and Mlinaric-Majerski K,,Annal. Chem.,74,44 (2002).
• 24.Radecka-Paryzek W. and Litkowska H., J. Alloys Comp., 300-301, 435 (2000).
• 25.Thunus L. and Lejeune R., Coord. Chem. Rev., 184, 125 (1999).
• 26.Wang K, Li R., Cheng Y. and Zhu B., Coord. Chem. Rev., 190-192, 297 (1999).