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Calcium carbonate equilibria in water supply systems

Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Water corrosion causes substantial damage to ductile, cast iron and steel water distribution systems. The corrosiveness of water depends on many physical, chemical, and even microbiological parameters. Stability indexes in respect of calcium carbonate like the Langelier Saturation Index (LSI) are also considered. First, the roles of inorganic complexes of calcium and manganese are discussed with respect to the accuracy of the calcium carbonate equilibrium calculations. As long as the drinking water parameters were below the EC Directive permissible values, neglecting these complexes had a small effect on the results of LSI computations. A model for computing LSI in water mixtures closed to the atmosphere was presented and partially verified on a small laboratory scale. Waters produced by all water treatment plants serving Kraków were evaluated in respect of the LSI, buffer capacity, and other parameters characterizing corrosive properties of water - in respect to iron. In general, the waters differed significantly in buffer capacity but all were evaluated as not presenting serious problems in internal corrosion of iron and cast iron, or more recently ductile iron pipes. This conclusion was verified based on a survey of main pipelines transporting water from the largest intake to the town, on the computations of the pipe roughness coefficient and on the mass balance of iron along the main transit pipes.
Rocznik
Strony
75--94
Opis fizyczny
bibliogr. 14 poz.
Twórcy
autor
  • Department of Water Supply and Environmental Engineering, Cracow University of Technology, ul. Warszawska 24, 31-155 Kraków, wdabrow@usk.pk.edu.pl
Bibliografia
  • [1] BENEFIELD L.D., JUDKINS J.F., WEAND B.L., Process chemistry for water and wastewater treatment, Prentice-Hall, Inc. Englewoods Cliffs, New Jersey, 1982.
  • [2] BUCHTA R., Carbonate equilibrium in drinking water mixtures (in Polish), PhD Dissertation, Cracow University of Technology, Kraków, 1998.
  • [3] DĄBROWSKI W., BUCHTA R., MACKIE R.I., Impact of water blending on calcium carbonate equilibrium in water distribution systems – technical note, Journal of Environmental Engineering, ASCE, September, 2004, 130, 9, 1059–1062.
  • [4] DĄBROWSKI W., DĄBROWSKA B., ZIELINA M., KANIEWSKI J., GAJEWSKI A., Difference between buffer capacities of water flowing through land of various geological origin, XXI Congresso Nazionale di Merceologia con partecipazione internazionale, Fioggia, 22–24 September 2004, (CD-rom edition).
  • [5] DĄBROWSKI W., BUCHTA R., Statistical evaluation of calcium carbonate equilibrium in natural water, Lakes & Reservoirs: Research and Management, 2000, 5, 99–104.
  • [6] JORDAN C., The mean pH of mixed fresh waters, Water Resources, 1989, 23(10), 1331–1334.
  • [7] LANGELIER W.F., The analytical control of anti-corrosion water treatment, Journal AWWA. 1936, 28(10), 1500.
  • [8] PANKOW J.E., Aquatic Chemistry Concepts, Lewis Publishers. Michigan, 1991.
  • [9] PISIGAN R.A., SINGLEY J.E., Calculating the pH of calcium carbonate saturation, Journal AWWA, October 1985, 83–91.
  • [10] ROQUES H., Chemical Water Treatment – Principles and Practice, VCH Publishers Inc., New York– Weinheim–Cambridge, 1996.
  • [11] ROSSOTI H., Równowagi jonowe, PWN, Warszawa, 1993.
  • [12] Standards Methods. For the Examination of Water and Wastewater. 1989. American Public Health Association. 1015 Fifteenth Street NW. Washington. DC 20005. 1989.
  • [13] STUMM W., Investigation on the corrosive behavior of waters, Journal of the Sanitary Engr. Div. Proc. ASCE, 1960, 86(SA 6), 27–45.
  • [14] STUMM W., MORGAN J.J., Aquatic chemistry, 2nd edition, Wiley, New York, 1981.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW8-0011-0112
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