Counter electrodes for WO/sub 3/-based electrochromic coatings

• Autorzy: Żelazowska E. , Ziemba B. , Lachman W.
• Języki publikacji: EN

Abstrakty

EN

Thin polycrystalline electrochromic tungsten trioxide as well as nickel, vanadium and titanium oxide films with and without lithium additive were prepared by spray pyrolysis on glass coated with SnO/sub 2/:F, using acetylacetonates as precursor materials. The substrate temperature was held at 600 degrees C for WO/sub 3/ and 680 degrees C for the other metal oxide films. Electrochromic colouration and bleaching characteristics were examined in the transmissive electrochromic cell arrangement, using LiClO/sub 4/-poly(ethylene oxide) polymer electrolyte and significant changes of optical transmission in the visible and solar range, up to 70%, were observed. The obtained films were electrochemically stable and colouration and bleaching cycles were reversible at a voltage of +or-(1-25) V. The start of the electrochemical reactions for most of the films obtained was observed in the range of +or-(0.3-4) V.

Słowa kluczowe

EN

counter electrodes; electrochromic coatings; thin films; spray pyrolysis; glass; acetylacetonates; precursor materials; substrate temperature; electrochromic colouration

PL

przeciwelektroda; elektrochromowanie; szkło; cienka warstwa

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Optica Applicata
• Rocznik: 2000
• Tom: Vol. 30, nr 4
• Strony: 663--670
• Opis fizyczny: Bibliogr. 17 poz., rys. 7

Twórcy

autor

Żelazowska E.

autor

Ziemba B.

autor

Lachman W.

• Institute of Glass and Ceramics, Cracow Branch, 30-702 Kraków, ul. Lipowa 3, Poland.