Nanocrystalline glass-ceramics formation

• Autorzy: Stoch L.
• Konferencja: 6th Seminar Porous Glasses-Special Glasses, PGL 2002, Szklarska Poręba, 22-26.IX.2002 r.
• Języki publikacji: EN

Abstrakty

EN

The atomic scale mechanism of the transition of the glass structure into the structure of a compound crystallizing in it has been studied. It has been demonstrated that near the glass transformation temperature Tg the crystallization by direct ordering of the amorphous glass structure through local displacements of its elements can take place. TiO2 nucleated crystallization of SiO2-Al2O3-MgO glass-ceramics is the example. Up to now, it has been thought that amorphous phase separation is an indispensable step in the glass-ceramization. Crystallization with the direct ordering mechanism creates the compounds whose chemical composition and structure are close to those of glass network or to the domains and clusters in it. The (Mg, Al)-titanate, and high quartz structure solid solutions appearence are here the example.

Słowa kluczowe

EN

glass; glass crystallization; nanocrystallization; nucleation mechanism; glass-ceramics

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Optica Applicata
• Rocznik: 2003
• Tom: Vol. 33, nr 1
• Strony: 115--123
• Opis fizyczny: Bibliogr. 19 poz., rys.

Twórcy

autor

Stoch L.

• University of Mining and Metallurgy, Faculty of Materials Science and Ceramics, al. Adama Mickiewicza 30, 30-059 Kraków

Bibliografia

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