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The role of dissolved iron in the flotation of zinc/lead sulphide ores

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The results of air exposure of a pulp containing dissolved iron have been studied using laboratory batch flotation experiments. Sulphide ore from three different stockpiles of a complex zinc/lead deposit was used. The pulp parameters such as pH, Eh, ion concentrations and dissolved oxygen concentrations were monitored along with metallurgical performance in zinc and lead differential flotation. Changes in iron concentration are correlated with most of the pulp parameters observed. A mechanism is proposed to explain this behaviour. This mechanism, combined with the metallurgical results, indicates that dissolved iron protects the surface of the minerals in the pulp against oxidation by scavenging oxygen dissolved in the slurry. The most visible influence of this phenomenon was observed on pyrite deportment; however, galena and sphalerite grades and recoveries were also affected.
Słowa kluczowe
Rocznik
Strony
22--25
Opis fizyczny
Bibliogr. 24 poz., rys., tab.
Twórcy
Bibliografia
  • (1) Forssberg, E. and Subrahmanyam, T. V., Grinding, pulp chemistry and particle flotability, proceedings of XVIII International Mineral Processing Congress, Sydney, 1993.
  • (2) Hanson, J. S. and Furstenau, D. W., The mechanism of xanthate adsorption on pyrite, Proceedings of XVIII International Mineral Processing Congress, Sydney, 1993.
  • (3) Xiang-Huai Wang, Interfacial electrochemistry of pyrite oxidation and flotation, J .Colloid Interface Sci., 1995, 171, 413.
  • (4) Konigsmann, K. V., Aeration in plant practice, Canadian Mining Joumal, 1973, 94(6), 52.
  • (5) Spira, P. and Rosenblum, F., Application of oxygen demand measurements to aeration design, Proceedings of the 10th Annual Meeting of CMP, 1978.
  • (6) Konigsmann, K.V., Flotation techniques for complex ores, Complex Sulfides: Processing of Ores, Concentrates and By-Products (Proceedings of a Symposium held at the TMS-AIME Fali Extractive Meeting.), San Diego, USA, 1985.
  • (7) C. J. Martin, S. R. Rao, J. A. Finch and M. Leroux, Complex sulphide flotation using nitrogen, Proceedings of the 20th Annual Meeting of CMP, 1988.
  • (8) H. Nakazawa and l. Iwasaki, Effect of pyrite-pyrrhotite contact on their flotabilities, Minerais and Metallurgical Processing, 1985, 2, 206.
  • (9) Tao, D. P., Li, Y. Q., Richardson, P. E. and Yoon, R.-H., The incipient oxidation of pyrite, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1994, 93, 229
  • (10) Zhu, Ximeng, Li, Jun and Wadsworth, M.E., Characterization of surface layers forrned during pyrite oxidation, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 1994, 93.
  • (11) Martin, C. J. and Zieliński, P. A., Surface analysis by TOF-LlMS of plant sampies from Red Dog, 1995, AMTEL internal report 95/08.
  • (12) Van Weert, G., Van Der Werff, D. and Derksen, J. J., Transfer of O2 from air to mineral slurries in a Rushton turbine agitated tank, Minerais Engineering, 1995, 8, 1109.
  • (13) Saprygin, A. F. and Gusar, L. S., Kinetic aspects of oxidation of ferrous sulphate by oxygen, Zh. Prikl. Khim., 1974, 47(8), 1690.
  • (14) Qingsong Zhang, Sphalerite activation in the presence of iron ions, PhD Thesis, McGill University, March, 1994.
  • (15) Mitra, A. K. and Matthews, M. L., Effect of pH and phosphate on the oxidation of iron in aqueous solutions, Int. J. Pharmaceutics, 1985, 23, 185.
  • (16) Posher, A. M., The kinetics of oxidation of ferrous ions in concentrated HCI solutions, Trans. Faraday Soc., 1953, 49, 382.
  • (17) Lamb, A. B. and Elder, L. W., "The electromotive activation of oxygen", J. Am. Chem. Soc., 1931, 53, 137.
  • (18) Cher, M. and Davidson, N., The kinetics of the oxidation of ferrous iron in phosphoric acid solution, J. Am. Chem. Soc., 1955, 77, 793.
  • (19) King, J. and Davidson, N., Kinetics of the ferrous ironoxygen reaction in acidic phosphate-pyrophosphate solutions, J. Am. Chem. Soc., 1958, 80, 1542.
  • (20) Kurimura, Y., Ochiai, R. and Matsuura, N., Oxygen oxidation of ferrous ions induced by chelation, BulI. Chem. Soc. Jap., 1968,41, 2234.
  • (21) Tiwari, B. L., Kolbe, J. and Hayden, Jr, H. W., Oxidation of ferrous sulfate in acid solution by mixture of sulfur dioxide and oxygen, MetalI. Trans. B, 10B, 1979, 607.
  • (22) McBain, J. W., Oxidation of ferrous solutions by free oxygen, J. Phys. Chem, 1991, 5, 23.
  • (23) Metelitsa, D.J. and Demisov, E. T., Mechanism of phenol oxidation with molecular oxygen in the presence of iron and copper ions, Kinetika i Kataliz, 1968, 9(4), 733.
  • (24) Healy, T. W., Pulp chemistry, surface chemistry and flota tion, Principles of Mineral Flotation: The Wark Symposium, Eds: Jones, M. H. and Woodcool, J. T., 1984, 40, 147.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPS3-0002-0092
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