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Języki publikacji
Abstrakty
An influence of the molar ratio of cis, trans, trans-1,5,9-cyclododecatriene to tert-butyl hydroperoxide, the concentration of the catalyst and the reaction time on the performance of the epoxidation process of cis, trans, trans-1,5,9-cyclodecatriene with tert-butyl hydroperoxide at the presence of molybdenum hexacarbonyl Mo(CO)6 was examined. Examinations were performed using statistical methods of the design of experiments. A mathematical model describing the influence of the parameters on conversion cis, trans, trans-1,5,9-cyclododecatriene was obtained. An analysis of the data and rests was performed and an optimal value of conversion of cis, trans, trans-1,5,9-cyclododecatriene was established.
Czasopismo
Rocznik
Tom
Strony
68--71
Opis fizyczny
Bibliogr. 9 poz., rys., tab.
Twórcy
autor
autor
- Institute of Organic Chemical Technology, Szczecin University of Technology, ul. Pułaskiego 10, 70-322 Szczecin, grzegorz.lewandowski@ps.pl
Bibliografia
- 1. Fisher R. A.: Design of experiments, Oliver & Boyd, London, 1935.
- 2. Mańczak K.: Technika planowania eksperymentu, WNT, Warszawa, 1976.
- 3. http://www.statsoft.com/textbook/stathome.html
- 4. Polański Z.: Planowanie doświadczeń w technice, PWN, Warszawa, 1984.
- 5. Sharpless K. B., Verhoeven T. R.: Metal catalysed, highly selective oxygenation of olefins and acetylenes with tert-butyl hydroperoxide. Practical consideration and mechanisms, Aldrichim. Acta, 1979, 12, 63 - 74.
- 6. Montgomery D. C.: Design and analysis of experiments, John Wiley & Sons Inc., 2005.
- 7. Czermiński J. B., Iwasiewicz A., Paszek Z., Sikorski A.: Metody statystyczne dla chemików, PWN, Warszawa, 1992.
- 8. Draper N. R., Smith H.: Applied regression analysis, John Wiley & Sons Inc, 1998.
- 9. Jobson J. D.: Applied multivariate data analysis, Springer-Verlag, New York, 1991.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPS2-0047-0016