Optimization of the epoxidation process of (1Z,5E,9E)-1,5,9-cyclododecatriene to 1,2-epoxy-(5Z,9E)-5,9-cyclododecadiene with tert-buthyl hydroperoxide — the influence of technological parameters on the hydroperoxide conversion

• Autorzy: Lewandowski G. , Rytwińska E. , Milchert E.
• Języki publikacji: EN

Abstrakty

EN

The optimization studies of the epoxidation process of (1Z,5E,9E)-1,5,9-cyclododecatriene (CDT) with tert-buthyl hydroperoxide (TBHP) over the molybdenum catalyst Mo(CO)6 were performed. The reaction was examined in terms of a uniform-rotatable design. Three factors were analyzed: the reaction time, CDT:TBHP molar ratio, and the molar concentration of the catalyst (Mo(CO)6). According to the design 20 experiments were performed at the constant temperature of 70°C.

Słowa kluczowe

EN

epoxidation; tert-butyl hydroperoxide; (1Z,5E,9E)-1,5,9-cyclododecatriene; 1,2-epoxy-(5Z,9E)-5,9-cyclododecadiene; design of experiments; optimization

PL

epoksydowanie; wodoronadtlenek tert-butylu; (1Z,5E,9E)-1,5,9-cyklododekatrien; 1,2-epoksy-(Z,E)-5,9-cyklododekadien; planowanie doświadczeń; optymalizacja

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2007
• Tom: Vol. 9, nr 3
• Strony: 105--107
• Opis fizyczny: Bibliogr. 4 poz., rys., tab.

Twórcy

autor

Lewandowski G.

autor

Rytwińska E.

autor

Milchert E.

• Szczecin University of Technology, Institute of Organic Chemical Technology, Pulaskiego 10, 70-322 Szczecin,

Bibliografia

• 1. Kirk-Othmer Encyclopedia of Chemical Technology, Vol. 9, 4th ed., Wiley, New York, 1991.
• 2. Arends I. W. C. E., Sheldon R. A.: Recent developments in selective catalytic epoxidations with H2O2, Topics in Catalysis, 2002, 19, 133.
• 3. Sheldon R. A., In. Ugo R. (Ed.): Aspects of Homogenous Catalysis, Vol. 4, Reidel, Dordrecht, 1981.
• 4. Polański Z.: Metodyka badań doświadczalnych, Kraków 1984.