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Alkaline leaching of zinc from stainless steel electric arc furnace dusts

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Stainless steel production generates dust and sludge that are considered as a harmful waste. These dusts contain also valuable metals but extraction and recovery of valuables is difficult due their complex composition. Zinc is the most troublesome element in the dust and it hinders direct recycling of dust back into furnaces. In this paper two different stainless steel electric arc furnace dusts (EAF1 and EAF2) from Outokumpu Stainless (Tornio, Finland), were leached using NaOH solutions. The purpose was to selectively leach out zinc from the dusts and to find factors that affected most dissolution of zinc. From all leaching factors temperature, agitation speed and NaOH concentration were found to be statistically strongly significant, whereas a liquid-to-solid ratio and bubbling gas were only somehow significant. Two experiments from the test series gave clearly higher zinc extraction, that is around 60% for EAF1 and 30% for EAF2. For those experiments, a strong 8 M NaOH solution with the high temperature and agitation speed was used but bubbling gas and liquid-to-solid ratio changed. Zinc was leached selectively and practically no iron, chromium and nickel dissolved.
Rocznik
Strony
293--302
Opis fizyczny
Bibliogr. 21 poz., rys., tab.
Twórcy
autor
  • Aalto University, Department of Materials Science and Engineering, PO Box 16200, FI-00076, Aalto, Finland
autor
  • Aalto University, Department of Materials Science and Engineering, PO Box 16200, FI-00076, Aalto, Finland
autor
  • Aalto University, Department of Materials Science and Engineering, PO Box 16200, FI-00076, Aalto, Finland
Bibliografia
  • 1. ATKINSON, M., KOLARIK, R., 2001, Chapter 4: Environmental Leadership. Steel Technology Roadmap, pp, 83 - 120.
  • 2. DENTON, G.M., BARCZA, N.A., SCOTT, P.D., FULTON, T., 2005, EAF Stainless Steel Dust Processing. In: M. Nilmani, Rankin, W.J. (Ed.), Sustainable developements in metals processing, Melbourne, Australia, pp. 273-283.
  • 3. HAVLIK, T., SOUZA, B.V., BERNARDES, A.M., SCHNEIDER, I.A.H., MISKUFOVA, A., 2006, Hydrometallurgical processing of carbon steel EAF dust. Journal of Hazardous Materials, B135, 311-318.
  • 4. JHA, M.K., KUMAR, V., SINGH, R.J., 2000, Review of hydrometallurgical recovery of zinc from industrial wastes. Resources Conservation & Recycling, 33(2001), 1-22.
  • 5. KEKKI, A., AROMAA, J., FORSEN, F., 2012, Leaching characteristics of EAF and AOD stainless steel production dusts, Physicochemical Problems of Mineral Processing, 48, 599-606.
  • 6. KUKURUGYA, F., HAVLIK, T., KEKKI, A., FORSÉN, O., 2013, Characterization of dusts from three types of stainless steel production equipment, Metall-Forschung, 67, 154-159.
  • 7. LAFOREST, G., DUCHESNE, J., 2006, Characterization and leachability of electric arc furnace dust made from remelting of stainless steel, Journal of Hazardous Materials, B135, 156-164.
  • 8. LECLERC, N., MEUX, E., LECUIRE, J-M., 2002, Hydrometallurgical recovery of zinc and lead from electric arc furnace dust using monotrilotriacetate anion and hexahydrated ferric chloride, Journal of Hazardous Material, B91, 257-270.
  • 9. MA, G., GARBERS-CRAIG, A.M., 2006, A review on the characteristics, formation mechanism and treatment processes of Cr (VI)-containing pyrometallurgical wastes, The Journal of Southern African Institute of Mining and Metallurgy, 106: 753-763.
  • 10. MAJUSTE, D., MANSUR, M.B., 2009, Leaching of the fraction of the argon oxygen decarburization with lance (AOD-L) sludge for the potential removal of iron, Journal of Hazardous Material, 153(1-2): 89-95.
  • 11. MONTGOMERY, D.C., 2009, Design and Analysis of Experiment, John Wiley & Sons Inc.
  • 12. NAKAMURA, T., 2005, Zinc recycling technology now and in the future, In: T. Fujisawa (Ed.), Lead & Zinc '05. MMIJ, Kyoto, Japan.
  • 13. NAKAMURA, T., SHILBATA, E., TAKASU, T., ITOU, H., 2008, Basic consideration on EAF dust treatment using hydrometallurgical processes, Resources Processing, 55, 144-148.
  • 14. NYIRENDA, R.L., 1992, The reduction of zinc-rich ferrites and its implication for a caron-type process for carbon steelmaking dust, Dissertation Thesis, Delft University of Technology.
  • 15. ORHAN, G., 2005, Leaching and cementation of heavy metals from electric arc furnace dust in alkaline medium, Hydrometallurgy, 78, 236-245.
  • 16. OUSTADAKIS, P., TSAKIRIDIS, P.E., KATSIAPI, A., AGATZINI-LEONARDOU, S., 2010, Hydrometallurgical process for zinc recovery from electric arc furnace dust (EAFD), Part I: Characterization and leaching by diluted sulphuric acid, Journal of Hazardous Material, 179, 1-7.
  • 17. PALENCIA, I., ROMERO, R., IGLESIAS, N., CARRANZA, F., 1999, Recycling EAF dust leaching residue to the furnace: A simulation study, JOM, 28-32.
  • 18. RAO, S.R., 2006A, Chapter 8: Metallurgical slags, dust and fumes, Waste Management Series: Resource Recovery and Recycling from Metallurgical Wastes, pp. 269-327.
  • 19. RAO, S.R. (ED.), 2006B, Metallurgical slags, dust and fumes, Waste Management Series: Resource Recovery and Recycling from Metallurgical Wastes, pp. 269-327.
  • 20. XIA, D.K., PICKLES, C.A., 1999, Caustic roasting and leaching of electric arc furnace dust. Canadian Metallugical Quarterly, 38(3), 175-186.
  • 21. YOUCAI, Z., STANFORTH, R., 2000, Integrated hydrometallurgical process for production of zinc from electric arc furnace dust in alkaline medium, Journal of Hazardous Material, B80, 223-240.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-ae70cc51-a75f-4a55-bc72-fcfa3331cf6b
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