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Flotation of antimony ores with high arsenic content

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Języki publikacji
EN
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EN
Efficient evaluation of antimony ores, which are on the critical raw materials list due to the supply risk by the European Union, is an important necessity. In this context, ore preparation and enrichment processes are very important during the process from ore to metal. Especially for sulfide antimony ores, the most common beneficiation method is flotation. Therefore, antimony ore consisting of stibnite mineral obtained from Tokat-Turkey region was used in this study. Due to the low antimony (5.06%Sb) and the high Arsenic (1.38%As) content, it is an important requirement to increase the Sb content of this ore by flotation, as well as to reduce the As content to certain levels. Stibnite as an antimony mineral and arsenopyrite as arsenic mineral, are minerals that have a sulphurous structure in mineralization and their flotation properties are quite close to each other. Therefore, in this study, it is aimed to selectively separate the bulk concentrate taken from rougher flotation by cleaning steps. A bulk sulfur concentrate with 24.54% Sb and 3.69% As content obtained as a result of the rougher flotation was obtained with a recovery of 98.9%. This product was subjected to 6 stages of cleaning flotation and a concentrate with a content of 63.8% Sb and 0.31% As was produced with an antimony recovery of 83% Sb.
Słowa kluczowe
Rocznik
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art. no. 152865
Opis fizyczny
Bibliogr. 22 poz., rys., tab., wykr.
Twórcy
  • Istanbul Technical University, Mining Faculty, Mineral Processing Engineering Department, 34469 /Istanbul-Turkey
Bibliografia
  • ANDERSON, C.G., 2012. The metallurgy of antimony. Chem. der Erde 72, 3–8. https://doi. org/10.1016/j.chemer.2012.04.001.
  • EALEDONA, N.S., FUJITA, T., 2006. Stibnite recovery from complex Tolukuma ore, in: XXIII International Mineral Processing Congress. Istanbul.
  • EUROPEAN COMMISSION, 2010. Critical raw materials for the EU. Report of the Ad-hoc Working Group on defining critical raw materials. [WWW Document]. URL https:// ec.europa.eu/growth/sectors/raw-materials/specific-interest/critical_en (accessed 5.6.20).
  • EUROPEAN COMMISSION, 2014. Report on critical raw materials for the EU. Report of the Ad hoc Working Group on defining critical raw materials. [WWW Document]. URL https://ec.europa.eu/growth/sectors/raw-materials/specific-interest/critical_en (accessed 5.6.20).
  • EUROPEAN COMMISSION, 2017a. Study on the review of the list of Critical Raw Materials - Critical Raw Materials Factsheets. https://doi.org/10.2873/398823.
  • EUROPEAN COMMISSION, 2017b. Study on the review of the list of Critical Raw Materials - Criticality Assessments. https://doi.org/10.2873/876644.
  • EUROPEAN COMMISSION, 2020. Communication from the Commission to the European Parliament, the Council, the European Economic and Social Committee and the Committee of the Regions. Critical Raw Materials Resilience: Charting a Path towards greater Security and Sustainability. COM/2020/474 final. [WWW Document]. URL https://eur-lex.europa.eu/legal-content/EN/TXT/?uri=CELEX: 52020DC0474 (accessed 9.16.20).
  • FUERSTENAU, M. C., JAMESON, G., & YOON, R. H., 2007 “Froth flotation: a century of innovation“, Society for Mining, Metallurgy, and Exploration. Inc., Littleton, CO, USA, 8975.
  • GRUND, S.C., HANUSCH, K., BREUNIG, H.J., WOLF, H.U., 2011. Antimony and Antimony Compounds, in: Wiley-VCH (Ed.), Ullmann’s Encyclopedia of Industrial Chemistry. Wiley-VCH, Weinheim, pp. 11–42.
  • GÜLCAN E., CAN İ.B, CAN N.B., ERGÜN L.Ş., 2019. Concentration characteristics of a complex antimony ore, Physicochemical Problems of Mineral Processing. 55(4), 823-839, DOI:10.5277/ppmp19003.
  • HERRERA-URBINA, R., HANSON, J.S., HARRIS, G.H., FUERSTENAU, D.W., 1990. Principles and practice of sulphide mineral flotation. In: Gray, P.M.J., Bowyer, G.J., Castle, J.F., Vaughan, D.J., Warner, N.A. (Eds.), Sulphide Deposits—Their Origin and Processing. Springer, Dordrecht, pp. 87–101..
  • KOCABAŞ, B., GÜVEN, O., ÖZER, M., KANGAL, O., 2012 The Beneficiation of Antimony Ore by Flotation, XIII International Mineral Processing Symposium, 10-12 October 2012, Bodrum, Turkey, pp.207-210.
  • LAGER, T., FORSSBERG, K.S.E., 1989a. Beneficiation characteristics of antimony minerals a review- part 1. Miner. Eng. 2, 321–336.
  • LAGER, T., FORSSBERG, K.S., 1989b. Current processing technology for antimony-bearing ores a review, part 2. Miner. Eng. 2, 543–556.
  • OBERBILLIG, E. (1964). Flotation of antimony ores. Mining Mag, 110.
  • OU LEMING FENG QIMING CHEN JIN, 1998 The Pulp Electrochemistry of Flotation Separation for Stibnite-Arsenopyrite Bulk Concentrate J. Cent. South Univ. Technol. Volume:5/1, May 1998
  • OZCAN, O., 1992. Classification of minerals according to their critical surface tension of wetting values. Int. J. Miner. Process. 34, 191–204.
  • POPOV, S.R., VUCINIC, D.R., CALIC, N.M., 1987. Surface phenomena of antimonite in solutions of different flotation reagents. Colloids Surf. 23, 171–183.
  • RICHARDS, R.G., 1977. Laboratory flotation of Endeavour Inlet, N. Z. Antimony ore. Proc. Australas. Inst. Min. Metall. 263, 39–46
  • SEGURA-SALAZAR J. AND BRITO-PARADA P.R., 2021. Stibnite froth flotation: A critical review. Minerals Engineering 163 (2021) 106713.
  • SUNDQVIST OKVIST, L., HU, X., ERIKSSON, J., KOTNIS, J., YANG, Y., YLI-RANTALA, E., BACHER, J., PUNKKINEN, H., RETEGAN, T., GONZALEZ ´ MOYA, M., DRZAZGA, M., 2018. Production technologies of critical raw materials from secondary resources - SCRREEN Project D 4.2. [WWW Document]. URL http://scrreen.eu/results/ (accessed 6.3.20).
  • USGS, 2020a. Mineral Commodity Summaries 2020. https://doi.org/10.3133/mcs2020.
Uwagi
Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-89d012ff-c01f-4d96-9215-d4b11c6e79ee
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