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The aim of this paper was to investigate the corrosion resistance of Mg66Zn30Ca4 and Mg68Zn28Ca4 metallic glasses and evaluate the ability of this amorphous alloy use for medical applications as biodegradable medical implants. Taking into account the amount of Mg, Zn, Ca elements dissolved in multielectrolyte physiological fluid (MPF) from Mg66+xZn30-xCa4 (x=0.2) alloys the daily dose of evolved ions from alloys components was determined. Additional goal of the paper was determination of corrosion rate (Vcorr) and amount of hydrogen evolved from amorphous magnesium alloys in simulated environment of human body fluids during 24h immersion and during electrochemical tests. Corrosion studies were done in the multielectrolyte physiological fluid (MPF) at 37°C. The amount of hydrogen evolved [ml/cm2] and corrosion rate Vcorr [mm/year] of amorphous Mg66Zn30Ca4 and Mg68Zn28Ca4 alloys were compared. The work also presents characterization of Mg-based bulk metallic glasses structure in the form of 2 mm thickness plates. Samples structure was analyzed by means of X-ray diffraction. Fracture and surface morphology of magnesium alloy samples were identified using scanning electron microscopy.
Wydawca
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Rocznik
Tom
Strony
807--810
Opis fizyczny
Bibliogr. 23 poz., rys.
Twórcy
autor
- Silesian University of Technology, Institute of Engineering Materials and Biomaterials, 18a Konarskiego Str., 44-100 Gliwice, Poland
autor
- Silesian University of Technology, Institute of Engineering Materials and Biomaterials, 18a Konarskiego Str., 44-100 Gliwice, Poland
autor
- Silesian University of Technology, Institute of Engineering Materials and Biomaterials, 18a Konarskiego Str., 44-100 Gliwice, Poland
autor
- Silesian University of Technology, Department of Inorganic, Analytical Chemistry and Electrochemistry, Faculty of Chemistry, Strzody 9, 44-100 Gliwice, Poland
autor
- Silesian University of Technology, Department of Inorganic, Analytical Chemistry and Electrochemistry, Faculty of Chemistry, Strzody 9, 44-100 Gliwice, Poland
autor
- Silesian University of Technology, Institute of Engineering Materials and Biomaterials, 18a Konarskiego Str., 44-100 Gliwice, Poland
Bibliografia
- [1] B. Heublein, R. Rohde, V. Kaese, M. Niemeyer, W. Hartung, A. Haverich, Heart 89, 651-656 (2003).
- [2] G. Nawrat. W. Simka. L. Nieużyła, I. Zdziech, Chemical Industry 85, 1204-1207 (2006).
- [3] Y. F. Zheng, X.N. Gu, F. Witte, Mater Sci Eng.: R. Reports. 77, 1-34 (2014).
- [4] F. Witte, I. Abeln, E. Switzer, V. Kaese, A. Meyer-Lindenberg, H. Windhagen, J Biomed Mater Res A 86, 1041-1047 (2008).
- [5] Z. Li, X. Gu, S. Lou, Y. Zheng, Biomaterials 29, 1329-1344, (2008).
- [6] S. Zhang, X. Zhang, Ch. Zhao, J. Li, Y. Song, Ch. Xie, H. Tao, Y. Zhang, Y. He, Y. Jiang, Y. Bian, Acta Biomater. 6, 626-640, (2010).
- [7] F. Rosalbino, S. De Negri, A. Saccone, E. Angelini, S. Delfino, J Mater Sci Mater Med. 21,(4), 1091-1098 (2010).
- [8] M. Liu, P. Schmutz, P.J. Uggowitzer, G. Song, A. Atrens, Corros Sci. 52, 3687-3701 (2010).
- [9] A.C. Hänzi, I. Gerber, M. Schinhammer, J.F. Löffler, P.J. Uggowitzer, Acta Biomater. 6, 1824-1833 (2010).
- [10] X. Gu, Y. Zheng, S. Zhong, T. Xi, J. Wang, W. Wang, Biomaterials 31, 1093-1103 (2010).
- [11] R. Nowosielski, R. Babilas, G. Dercz, L. Pająk, Sol St Phen 163, 165-168 (2010).
- [12] R. Babilas, K. Cesarz-Andraczke, R. Nowosielski, A. Burian, J Mater Eng Perform. 23, (6), 2241-2246 (2014).
- [13] R. Nowosielski, K. Cesarz-Andraczke, R. Babilas, A. Maciej, G. Nawrat, Solid State Phenom. 227, 439-442 (2015).
- [14] G. Song, Corros Sci. 49, (4), 1696-1701 (2007).
- [15] Y.Y. Zhao, X. Zhao, J Alloy Compd. 515, 154-160 (2012).
- [16] H. Li, S. Pang, Y. Liu, L. Sun, P. K. Liaw, T. Zhang, Mater Design 67, 9-19 (2015).
- [17] G. Song, A. Atrens, Adv Eng Mater 5. (12), 837-58 (2003).
- [18] J. Wang, S. Huang., Y. Li., Y. Wei, X. Xi, K. Cai, Mater Sci Eng C 33, 3832-3838 (2013).
- [19] A. Kabata-Pendias, H. Pendias, Biogeochemistry of trace elements, PWN, Warsaw 2004.
- [20] D. Cao, L. Wu, Y. Sun, G. Wang, Y. Lv, J Power Sources 177, 624-63 (2008).
- [21] G. Song, Adv Eng Mater. 7, 563-586 (2005).
- [22] Li Z., Gu X., Lou S., Zheng Y., Biomaterials 29, 1329-44 (2008).
- [23] Zhang W., Li M., Chen Q., Hu W., Zhang W., Xin W., Mater Design 39, 379-383 (2012).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-83aa6074-84d8-46d2-95c4-54aee8ae773b