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Fabrication of ternary Ca-Mg-Zn bulk metallic glasses

Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: The paper describes the preparation, structure and thermal properties of ternary Ca-Mg-Zn bulk metallic glass in form of as-cast rods. Design/methodology/approach: The investigations on the ternary Ca-Mg-Zn glassy rods were conducted by using X-ray diffraction (XRD), scanning electron microscopy (SEM) which energy dispersive X-ray analysis (EDS). Findings: The X-ray diffraction investigations have revealed that the studied as-cast rod was amorphous. The fractures of studied alloy could be classified as mixed fracture with indicated “river” and “smooth” fractures. Both type of the fracture surfaces consist of weakly formed “river” and “shell” patterns and “smooth” regions. The “river” patterns are characteristic for metallic glassy alloys. Practical implications: The studied Ca-based bulk metallic glasses is a relatively new group of material. Ca-based bulk metallic glasses are applied for many applications in different elements. Ca-based bulk metallic glasses have many unique properties such as low density (~2.0 g/cm³), low Youn g’s modulus ( ~20 to 30 GPa). The elastic modulus of Ca-b ased BMGs is comparable to that of hum an bone s, and Ca, Mg, and Zn are biocompatible. These features make the Ca-Mg-Zn–based alloys attractive for use in biomedical applications. Originality/value: Fabrication of amorphous alloy in the form of rod ternary Ca-Mg-Zn alloy by pressure die casting method.
Rocznik
Strony
67--74
Opis fizyczny
Bibliogr. 25 poz., rys., tab.
Twórcy
  • Faculty of Mechanical Engineering, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland
autor
  • Faculty of Mechanical Engineering, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland
autor
  • Faculty of Mechanical Engineering, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland
autor
  • Faculty of Mechanical Engineering, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland
Bibliografia
  • [1] W. Klement, R.H. Willens, P. Duwez, Non-crystalline structure in solidified gold-silicon alloys, Nature 187 (1960) 869-870.
  • [2] H.S. Chen, Thermodynamic considerations on the formation and stability of metallic glasses, Acta Metallurgica 22 (1974) 1505-1511.
  • [3] A. Inoue, N. Nishiyama, H. Kimura, Preparation and thermal stability of bulk amorphous Pd40Cu30Ni10P20 alloy cylinder of 72 mm in diameter, Materials Transactions 38 (1997) 179-183.
  • [4] J.F. Loeffler, Bulk metallic glasses, Intermetallics 11 (2003) 529-540.
  • [5] K. Amiya, A. Inoue, Formation, thermal stability and mechanical properties of Ca-based bulk glassy, Materials Transactions 43 (2002) 81-84.
  • [6] K. Amiya, A. Inoue, Formation and thermal stability of Ca-Mg-Ag-Cu bulk glassy alloys, Materials Transactions 43 (2002) 2578-2581.
  • [7] O.N. Senkov, D.B. Miracle, V. Keppens, P.K. Liaw, Development and characterization of low-density Ca-based bulk metallic glasses, An overview, Metallurgical and Materials Transactions A 39 (2008) 1888-1900.
  • [8] E.S. Park, D.H. Kim, Formation of Ca-Mg-Zn bulk glassy alloy by casting into cone-shaped copper mold, Journal of Materials Research 19 (2004) 685-688.
  • [9] O.N. Senkov, J.M. Scott, New calcium based bulk metallic glasses, Materials Research Society Publications 806 (2003) 145-150.
  • [10] A. Takeuchi, A. Inue, Classification of bulk metallic Glasses by atomic size difference, Heat of mixing and period of constituent elements and its application to characterization of the nain alloying element, Materials Transactions 46 (2005) 2817-2829.
  • [11] O.N. Senkov, J.M. Scott, Specific criteria for selection of alloy compositions for bulk metallic glasses, Scripta Materialia 50 (2004) 449-452.
  • [12] R. Nowosielski, R. Babilas, A. Guwer, A. Gawlas-Mucha, A. Borowski, Fabrication of Mg65Cu25Y10 bulk metallic glasses, Archives of Materials Science and Engineering 53/2 (2012) 77-84.
  • [13] Z. Zhang, V. Keppens, O.N. Senkov, D.B. Miracle, Elastic properties of Ca-based bulk metallic glasses studied by resonant ultrasound spectroscopy, Materials Science and Engineering A 471 (2007) 151-154.
  • [14] G. Wang, P.K. Liaw, O.N.Senkov, D.B Miracle, M.L. Morrison, Mechanical and fatigue behaviour of Ca65Mg15Zn20 bulk metallic glass, Advanced Engineering Materials 11 (2009) 27-34.
  • [15] R. Barnard, P.K. Liaw, R.A. Buchanan, O.N. Senkov, D.B. Miracle, Oxidation Behavior of Ca-based bulk amorphous materials, Materials Transactions 48 (2007) 1870-1878.
  • [16] Y.B. Wang, X.H. Xie, H.F. Li, X.L. Wang, M.Z. Zhao, E.W. Zhang, Y.J. Bai, Y.F. Zheng, L. Qin, Biodegradable CaMgZn bulk metallic glass for potentiall skelet alapplication, Acta Biomaterialia 7 (2011) 3196-3208.
  • [17] G. Wang, P.K. Liaw, O.N.Senkov, D.B. Miracle, M.L. Morrison, Mechanical and fatigue behavior of Ca65Mg15Zn20 bulk-metallic glass, Advanced Engineering Materials 11 (2009) 27-34.
  • [18] J.D. Cao, N.T. Kirkland, K.J. Laws, N. Birbilis, M. Ferry, Ca-Mg-Zn bulk metallic glasses as bioresorbable metals, Acta Biomaterialia 8 (2012) 2375-2383.
  • [19] R. Babilas, R. Nowosielski, Iron-based bulk amorphous alloys, Archives of Materials Science and Engineering 44/1 (2010) 5-27.
  • [20] R. Nowosielski, R. Babilas, Preparation, structure and properties of Fe-based bulk metallic glasses, Journal of Achievements in Materials and Manufacturing Engineering 40/2 (2010) 123-130.
  • [21] S. Lesz, Preparation of Fe-Co-based bulk amorphous alloy from high purity and industrial raw materials, Archives of Materials Science and Engineering 48/2 (2011) 77-88.
  • [22] E. David, Nanocrystalline magnesium and its properties of hydrogen sorption, Journal of Achievements in Materials and Manufacturing Engineering 20 (2007) 87-90.
  • [23] M. Spilka, S. Griner, A. Kania, Influence of thermal activity on the changes of physical properties and structure of cobalt-based metallic glass, Materials Science and Engineering 56/2 (2012) 61-68.
  • [24] R. Nowosielski, A. Januszka, Thermal stability and GFA parameters of Fe-Co-based bulk metallic glasses, Archives of Materials Science and Engineering 48/2 (2011) 161-168.
  • [25] A. Pusz, A. Januszka, S. Lesza, R. Nowosielski, Thermal conductivity measuring station for metallic glasses, Archives of Materials Science and Engineering 47/2 (2011) 95-102.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-8188fc50-f4d2-4e48-8812-d78847dacd19
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