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The free volume holes and light transmission of hydrogel and silicone-hydrogel polymer contact lenses were investigated. As the material, the Proclear family (omafilcon A) of hydrogel contact lenses and the Biofinity family (comfilcon A) of silicone-hydrogel contact lenses were used. Positron annihilation lifetime spectroscopy was used to characterize geometrical sizes and fractions of the free volume holes in the investigated samples. There was a clear difference in the size of free volume holes and the fractional free volume between silicone-hydrogel and hydrogel polymer contact lenses. These changes are shown by a thorough analysis of the long-lived component of lifetime of ortho-positronium. At the same time, UV-vis-NIR in the spectral range 200-1000 nm studies were performed on the same samples of contact lenses spectrometry.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
35--45
Opis fizyczny
Bibliogr. 32 poz., rys.
Twórcy
autor
- Jan Długosz University in Częstochowa, Faculty of Mathematics and Natural Science, Institute of Physics, Armii Krajowej 13/15, 42-200 Częstochowa, Poland
autor
- Jan Długosz University in Częstochowa, Faculty of Mathematics and Natural Science, Institute of Physics, Armii Krajowej 13/15, 42-200 Częstochowa, Poland
autor
- Jan Długosz University in Częstochowa, Faculty of Mathematics and Natural Science, Institute of Physics, Armii Krajowej 13/15, 42-200 Częstochowa, Poland
- Institute of Physics, Faculty of Production Engineering and Materials Technology, Częstochowa University of Technology, Armii Krajowej 19, 42-200 Częstochowa, Poland
autor
- Jan Długosz University in Częstochowa, Faculty of Mathematics and Natural Science, Institute of Physics, Armii Krajowej 13/15, 42-200 Częstochowa, Poland
Bibliografia
- [1] TRANOUDIS I., EFRON N., In-eye performance of soft contact lenses made from different material, Contact Lens and Anterior Eye 27(3), 2004, pp. 133–148.
- [2] GUILLON M., MAISSA C., Bulbar conjunctival staining in contact lens wearers and non lens wearers and its association with symptomatology, Contact Lens and Anterior Eye 28(2), 2005, pp. 67–73.
- [3] PULT H., PURSLOW C., BERRY M., MURPHY P.J., Clinical tests for successful contact lens wear: relationship and predictive potential, Optometry and Vision Science 85(10), 2008, pp. E924–E929.
- [4] WOLFFSOHN J.S., HUNT O.A., BASRA A.K., Simplified recording of soft contact lens fit, Contact Lens and Anterior Eye 32(1), 2009, pp. 37–42.
- [5] POLSE K.A., Tear flow under hydrogel contact lenses, Investigative Ophthalmology and Visual Science 18(4), 1979, pp. 409–413.
- [6] BONANNO J.A., STICKEL T., NGUYEN T., BIEHL T., CARTER D., BENJAMIN W.J., SARITA SONI P., Estimation of human corneal oxygen consumption by noninvasic measurement of tear oxygen tension while wearing hydrogel lenses, Investigative Ophthalmology and Visual Science 43(2), 2002, pp. 371–376.
- [7] RYDZ M., New trends in vision correction with silicone hydrogel contact lenses, Kontaktologia i Optyka Okulistyczna (Contactology and Optics Eyepiece), No. 1, 2004, pp. 34–39.
- [8] ICHIJIMA H., HAYASHI T., MITSUNAGA S., HAMANO H., Determination of oxygen tension on rabbit corneas under contact lenses, CLAO Journal 24(4), 1988, pp. 220–226.
- [9] JEAN Y.C., VAN HORN J.D., WEI-SONG HUNG, KUIER-RARN LEE, Perspective of positron annihilation spectroscopy in polymers, Macromolecules 46(18), 2013, pp. 7133–7145.
- [10] BYAKOV V.M., GOLDANSKII V.I., SHANTAROVICH V.P., About the possible role of “dry” electrons in positronium formation in a liquid, Doklady Physical Chemistry 219, 1974, pp. 1090–1093.
- [11] MOGENSEN O.E., Spur reaction model of positronium formation, The Journal of Chemical Physics 60(3), 1974, pp. 998–1004.
- [12] HYLA M., FILIPECKI J., MANDECKI Z., MERVINSKII R.I., Positron annihilation and diffraction studies of the photopolymers based on the acrylate oligomers, Journal of Non-Crystalline Solids 232–234, 1998, pp. 446–452.
- [13] PETHRICK R.A., Positron annihilation – a probe for nanoscale voids and free volume?, Progress in Polymer Science 22(1), 1997, pp. 1–47.
- [14] JEAN Y.C., NATO Advanced Research Workshop, Advances with Positron Spectroscopy of Surfaces, Yarenna, Italy, 1993.
- [15] SHAO-JIE W., ZHONG-XUN T., DE-CHONG T., Positron Annihilation, World Scientific Publishing Co. Pte. Ltd., Singapore, 1985.
- [16] DRYZEK J., Wstęp do spektroskopii anihilacji pozytonów w ciele stałym, Wydawnictwo Uniwersytetu Jagiellońskiego, Kraków, Poland, 1997 (in Polish).
- [17] BRANDT W., BERKO S., WALKER W.W., Positronium decay in molecular substances, Physical Review 120(4), 1960, pp. 1289–1295.
- [18] TAO S.J., Positron annihilation in molecular substances, The Journal of Chemical Physics 56(11), 1972, pp. 5499–5510.
- [19] ELDRUP M., LIGHTBODY D., SHERWOOD J.N., The temperature dependence of positron lifetimes in solid pivalic acid, Chemical Physics 63(1–2), 1981, pp. 51–58.
- [20] SANE P., TUOMISTO F., HOLOPAINEN J.M., Void volume variations in contact lens polymers, Contact Lens and Anterior Eye 34(1), 2011, pp. 2–6.
- [21] JEAN Y.C., Positron annihilation spectroscopy for chemical analysis: a novel probe for microstructural analysis of polymers, Microchemical Journal 42(1), 1990, pp. 72–102.
- [22] HARRIS M.G., CHIN R.S., LEE D.S., TAM M.H., DOBKINS C.E., Ultraviolet transmittance of the vistakon disposable contact lenses, Contact Lens and Anterior Eye 23(1), 2000, pp. 10–15.
- [23] MOORE L., FERREIRA J.T., Ultraviolet (UV) transmittance characteristics of daily disposable and silicone hydrogel contact lenses, Contact Lens and Anterior Eye 29(3), 2006, pp. 115–122.
- [24] NOWICKA-JANKOWSKA T., WIETESKA E., GORCZYŃSKA K., MICHALIK A., Spektrofotometria UV/VIS, PWN, Warsaw, 1988 (in Polish).
- [25] KOCELA A., FILIPECKI J., KORZEKWA P., GOLIS E., Investigation of the free volume changes in one day hydrogel and one day silicone-hydrogel contact lenses by means of positron annihilation lifetime spectroscopy, Polymers in Medicine 42(1), 2012, pp. 61–68.
- [26] FILIPECKI J., KOCELA A., KORZEKWA P., MIEDZIŃSKI R., FILIPECKA K., GOLIS E., KORZEKWA W., Structural study of polymer hydrogel contact lenses by means of positron annihilation lifetime spectroscopy and UV–vis–NIR methods, Journal of Materials Science: Materials in Medicine 24(8), 2013, pp. 1837–1842.
- [27] FILIPECKI J, SITARZ M., KOCELA A., KOTYNIA K., JELEN P., FILIPECKA K., GAWEDA M., Studying functional properties of hydrogel and silicone–hydrogel contact lenses with PALS, MIR and Raman spectroscopy, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 131, 2014, pp. 686–690.
- [28] FILIPECKI J., GOLIS E., REBEN M., FILIPECKA K., KOCELA A., WASYLAK J., Positron life time spectroscopy as a method to study of the defect degree materials with disordered structure, Journal of Optoelectronics and Advanced Materials: Rapid Communications 7(11–12), 2013, pp. 1029–1031.
- [29] KANSY J., Microcomputer program for analysis of positron annihilation lifetime spectra, Nuclear Instruments and Methods in Physics Research Section A 374(2), 1996, pp. 235–244.
- [30] FILIPECKI J., CHAMERSKI K., BOYKO O., KOTYNIA K., Ageing phenomenon in acrylic polymer dental materials detected by means of positron annihilation lifetime spectroscopy, Polymers in Medicine 44(1), 2014, pp. 21–28.
- [31] SZCZOTKA-FLYNN L., Lens distinctions, Contact Lens Spectrum 6, 2007, pp. 1–4.
- [32] YUCHEN HUO, KETELSON H., PERRY S.S., Ethylene oxide-block-butylene oxide copolymer uptake by silicone hydrogel contact lens materials, Applied Surface Science 273, 2013, pp. 472–477.
Uwagi
PL
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-4986f111-2a51-4757-b88b-cecf814c1427