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Effect of PVP and Polybond Compatibilizers on Dynamic Properties of Polymer Blends Analyzed with DMTA

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The properties of the polymer blends depend significantly on the type of the components. That kind of influence is manifested especially in the change of physical properties. The crucial condition for reaching the homogeneity and the properties of a polymer material is its mutual miscibility. Additional agents that make mixing easier are usually applied. They have reactive effect which results in a chemical modification of output polymer along with the change in its chemical structure and the structure of macrochains. In order to achieve this within the confines of the carried research, the polyvinylpyrrolidone (PVP) and polybond has been used. Some results concerning mechanical properties of polypropylene (PP) and polyamide (PA) blends with the addition of PVP and polybond are presented in the paper. In case of mixing PP with PVP, the hydrophobic interactions occur in the created macromolecules with the participation of the hydrocarbon chains. In case of mixing PA with PVP, the PVP solution in PA is created, with strong intermolecular interactions, including the hydrogen ones. The intermolecular interactions occur and they differently influence parameters of the modified materials in the blends on the basis of such polymers. Therefore the aim of the research was to evaluate the influence of the compatibilizers such as PVP and Polybond 3150 on the dynamic properties of PP/PA blends. The analysis of dynamic proprieties of polymer blends was performed with the Dynamic Mechanical Thermal Analysis (DMTA). The mixing of polymers in different proportions with compatibilizers (PVP, Polybond 3150) results in materials of completely different properties in comparison to the base materials. Detailed results concerning response to sinusoidal load in function of temperature and frequency are presented in the paper.
Rocznik
Strony
36--40
Opis fizyczny
Bibliogr. 18 poz., fig., tab.
Twórcy
  • Czestochowa University of Technology Faculty of Mechanical Engineering and Computer Science 21 Armii Krajowej Av 42-200 Czestochowa Poland
  • Jan Dlugosz University in Czestochowa, Faculty of Mathematics and Natural Sciences 13/15 Armii Krajowej Av, 42-200 Czestochowa, Poland
Bibliografia
  • 1. Jakubowska P., Sterzyński T., Samujło B., Rheological Studies of Highly-Filled Polyolefin Composites Taking Into Consideration P-V-T Characteristics Polimery 2010, 5, pp. 379.
  • 2. Żuchowska D.: Construction polymers. WNT, Warsaw, 2000.
  • 3. Gnatowski A., Koszkul J., Investigations of the Influence of Compatibilizer and Filler Type on the Properties of Chosen Polymer Blends, Journal Material Processing Technology 2005, Vol. 162–163, 52–58.
  • 4. Gnatowski A., Ziewiec A., Gnatowska R.: Impact analysis performance injection in polymer composites processing shrinkage, AIP Conference Proceedings 1648, 850127, 2015, http://doi. org/10.1063/1.4913182.
  • 5. Koning C., Duin M. V., Paagnoulle Ch., Jerome R., Strategies for compatibilization of polymer blends, Progress in Polymer Science, Vol. 23, 1998, 707–757.
  • 6. Bucknall, C.; Paul, D.R. Polymer Blends, Formulation and Performance; JohnWiley and Sons: New York, NY, USA, 2000.
  • 7. Dharmarajan N., Datta S., Ver Strate G., Ban L., Compatibilized polymer blends of isotactic polypropylene and styrene-maleic anhydride copolymer. Polymer, Vol. 36, No. 20, 1995, 3849–3861.
  • 8. Manning S.C., Moore R. B., Reactive compatibilization of polypropylene and polyamide-6.6 with carboxylated and maleated polypropylene, Polymer Engineering and Science Vol. 39, No 10, 1999, 1921–1926.
  • 9. Campoy J., Arribas J. M., Zaporta U. M., Crystallization kinetics of polypropylene-polyamide compatibilized blends, European Polymer Journal, Vol. 31, No 5, 1995, 475–480.
  • 10. Ohlsson B., Hassander H., Törnell B., Effect of the mixing procedure on the morphology and properties of compatibilized polypropylene/polyamide blends, Polymer Engineering and Science, Vol. 39, No 20, 1998, 4715–4721.
  • 11. Robeson, L.M. Polymer Blends, A Comprehensive Review; Carl Hanser: Cincinnati, OH, USA, 2007
  • 12. Isayev, A. Encyclopedia of polymer blends. Fundamentals; Wiley-VCH: Weinheim, Germany, 2011.
  • 13. Papadopoulou, C.P.; Kalfoglou, N.K. Comparison of compatibilizer effectiveness for PET/PP blends:Their mechanical, thermal and morphology characterization. Polymer 2000, 41, 2543–2555.
  • 14. Stary, Z.; Pemsel, T.; Baldrian, J.; Munstedt, H. Influence of a compatibilizer on the morphology development in polymer blends under elongation. Polymer 2012, 53, 1881–1889.
  • 15. Koszkul J., Polymeric materials, Publication of Technical University of Czestochowa, 1999.
  • 16. Sidielkowskaja F.P., Chemistry of N-vinylpyrrolidone and of his polymers. Science – Moscow, 1970.
  • 17. Gnatowski A., Suberlak O., Postawa P., Functional materials based on PA6/PVP blends, Journal of Achievements in Materials and Manufacturing Engineering, Vol. 18, 2006, 91–94.
  • 18. Catalog UNIROYAL CHEMICA LIMITED 3/93.
Uwagi
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-463b766f-02a8-49e9-9a6e-6e9b1bc78914
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