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Efficiency of Reverse Osmosis and Ion Exchange in Water Purification from Nitrates

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The process of extracting nitrates from water by the methods of reverse osmosis and ion exchange was investigated in the paper. In the formation of reverse osmosis, low-pressure membranes were used, and in ion-exchange processes, highly alkaline anionite AB–17–8 was applied in salt form. The dynamics of changes in the concentration of nitrates in the permeate and the concentration with an increase in the degree of permeate selection from 9 to 90% at initial nitrate concentrations of 18, 50 and 100 mg/dm3 were determined. The indicators of selectivity and productivity of membranes were calculated depending on the degree of permeate selection. It was shown that the low-pressure reverse osmosis membrane is characterized by low selectivity values at high productivity values in the selected part of the nitrate concentration. It was established that the ion exchange method is significantly more effective than reverse osmosis in removing nitrates from water. It ensures the reduction of nitrate content in purified water to a value of less than 1 mg/dm3 when the degree of their extraction is reached at the level of 99%. As the ionite is saturated with nitrates, the efficiency of their extraction decreases. Anionite sorbs nitrates effectively enough, being both in the chloride mixture and in the sulfate form. Nitrates are effectively desorbed by 2H solutions of sodium chloride and sodium or ammonium sulfate.
Rocznik
Strony
172--180
Opis fizyczny
Bibliogr. 24 poz., rys., tab.
Twórcy
  • Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, Igor Sikorsky Kyiv Polytechnic Institute, Peremogy Avenu 37/4, 03056 Kyiv, Ukraine
  • Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, Igor Sikorsky Kyiv Polytechnic Institute, Peremogy Avenu 37/4, 03056 Kyiv, Ukraine
  • Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, Igor Sikorsky Kyiv Polytechnic Institute, Peremogy Avenu 37/4, 03056 Kyiv, Ukraine
  • Department of Ecology and Technology of Plant Polymers, Faculty of Chemical Engineering, Igor Sikorsky Kyiv Polytechnic Institute, Peremogy Avenu 37/4, 03056 Kyiv, Ukraine
Bibliografia
  • 1. Ayyasamy P.M., Rajakumar S., Sathishkumar M., Swaminathan K., Shanthi K., Lakshmanaperumalsamy P., Lee S. 2009. Nitrate removal from synthetic medium and groundwater with aquatic macrophytes. Desalination, 242(1–3), 286–296.
  • 2. Balakina M.N., Kucheruk D.D., Bilyk Yu. S., Osipenko V.O., Shkavro Z.N. 2013. Wastewater treatment from biogenic elements. Journal of Water Chemistry and Technology, 35, 5, 386–397. (in Russian)
  • 3. COUNCIL DIRECTIVE 98/83/EC of 3 November 1998 on the quality of water intended for human consumption.
  • 4. Dehghani M., Hoseini M., Fath-Aabaadi M.-K. F., Elhamiyan Z., Shamsedini N., Ghanbarian M., Shahsavani S., Baghani A. N. 2016. Optimizing Electrocoagulation Process for the Removal of Nitrate from Aqueous Solution. Jundishapur Journal of Health Sciences, 8, 1, 2–5.
  • 5. Dong-Wan C., Chul-Min C., Byong-Hun J., Yongje K., Ali K. M., Hocheol S. 2010. The role of clay minerals in the reduction of nitrate in groundwater by zero-valent iron. Chemosphere, 2, 611–616.
  • 6. Dsan Pin 2.2.4.-400–10. Hygienic requirements for drinking water intended for human consumption. Approved by the Order of the Ministry of Health of Ukraine dated 12.05.2010. (in Ukrainian)
  • 7. Epsztein R., Nir O., Lahav O., Green M. 2015. Selective nitrate removal from groundwater using a hybrid nanofiltration-reverse osmosis filtration scheme. Chemical Engineering Journal, 279, 372–378.
  • 8. Ghanbari F., Moradi М., Mohseni-Bandpei А., Gohari F., Mirtaleb Abkenar Т., Aghayani Е. 2014. Simultaneous application of iron and aluminum anodes for nitrate removal: a comprehensive parametric study. International Journal of Environmental Science and Technology, 11, 1653–1660.
  • 9. Giammarino M., Quatto P. 2015. Nitrates in drinking water: relation with intensive livestock production. Journal of Preventive Medicine and Hygiene, 56, 4, 187–189.
  • 10. Gomelya M., Grabitchenko V.M., Trus I.M. 2015. Estimation of the influence of chlorides on ion exchange purification of water from nitrates. Ecology and Industry, 1, 61–65. (in Ukrainian)
  • 11. Gomelya M.D., Hrabitchenko V.M., Trokhymenko G.G. 2016. Nitrates Removal from Water by Ion-Exchange Purification in the Presence of Chlorides and Sulfates. Energy Technologies and Resource Saving, 1, 57–65.
  • 12. Gomelya M., Trokhymenko А., Shabliy T. 2016. Low-waste ion exchange technology of extraction of nitrogen compounds from water. Easten-Europen Journal of Enterprise Technologies, 4/10 (82), 4–9.
  • 13. Goncharuk V.V., Osipenko V.O., Kucheruk D.D., Balakina M.N. 2013. Water purification of nitrates by reverse osmosis low-pressure. Journal of Water Chemistry and Technology, 35(2), 125–131. (in Russian)
  • 14. Hayrynen K., Pongracz E., Vaisanen V., Pap N., Manttari M., Langwaldt J., Riitta L. K. 2009. Concentration of ammonium and nitrate from mine water by reverse osmosis and nanofiltration. Desalination, 240(1–3), 280–289.
  • 15. Ievleva O.S., Goncharuk V.V. 2015. Calculation of the material balance of the technological scheme for the extraction of nitrate ions from solutions by baromembrane methods. Scientific News of NTUU “KPI”, 5, 113–118. (in Ukrainian)
  • 16. Kombo Mpindou G.O.M. 2015. Experimental study of the removal of nitrates by nanofiltration: application to the determination of transport models. Valencia, 319. (in Spanish)
  • 17. Lurie Y.Y. Analytical chemistry of industrial wastewater. 1984. M.: Chemistry, 448. (in Russian)
  • 18. MultiLab User Guide. Fourier Systems Ltd. 2009. http://www.mokslotechnologijos.lt/images/Userfiles/MultiLab_vartotojo_gidas_EN.pdf
  • 19. Nabivanets B.I., Sukhan V.V., Kalabina L.V. 1996. Analytical chemistry of the natural environment. K.: Lybid, 201. (in Ukrainian)
  • 20. Osipenko V.O., Balakina M.N., Kucheruk D.D. 2015. Purification of nitrate containing brackish waters with obtaining of ammonium fertilizers by electrodialysis. Journal of Water Chemistry and Technology, 37(2), 75–84. (in Russian)
  • 21. Pradhan S., Fana L., Roddicka F.A., Shahsavarib E., Ballb A.S. 2016. Impact of salinity on organic matter and nitrogen removal from a municipal wastewater RO concentrate using biologically activated carbon coupled with UV/H2O2. Water Research, 94, 103–110.
  • 22. Primo O., Rivero M.J., Urtiaga A.M., Ortiz I. 2009. Nitrate removal from electro-oxidized landfill leachate by ion exchange. Journal of Hazardous Materials, 164(1), 389–393.
  • 23. Xu X., Bao-Yu G., Qian-Qian Z., Qin-Yan Y., Qian L. 2011. Sorption of nitrate onto amine-crosslinked wheat straw: Characteristics, column sorption and desorption properties. Journal of Hazardous Materials, 186(2), 206–211.
  • 24. Yanhao Z., Fohua Z., Siqing X., Xuejiang W., Jixiang L. 2009. Autohydrogenotrophic denitrification of drinking water using a polyvinyl chloride hollow fiber membrane biofilm reactor. Journal of Hazardous Materials, 1, 203–209.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-295bae1c-9b74-4b7a-a14a-cffcafa336ee
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