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Abstrakty
Biosorption of Zn(II) and Cd(II) ions from aqueous solutions onto organic waste – orange peel, hazelnut shell, and walnut shell was studied using batch adsorption experiments. In the biosorption studies, equilibrium metal ion concentration was determined. Experimental data obtained were analysed in terms of Freundlich, Langmuir, Temkin, Dubinin–Radushkevich, Redlich–Peterson, Sips, Toth, and Khan isotherms. The results of the study showed that orange peel, hazelnut shell, and walnut shell can be adequately used as low-cost alternatives for the removal of Zn(II) and Cd(II) ions from aqueous solutions with maximum sorption capacities of 15.51 and 19.8 mg/g, 11.55 and 16.65 mg/g, and 26.60 and 21.10 mg/g, respectively. The highest removal efficiency of Zn(II) and Cd(II) ions was obtained for hazelnut shells. The process was fast and about 90% of metal ions were removed by all the studied biosorbents. The sorption process was possibly chemisorption occurring on a heterogeneous surface.
Czasopismo
Rocznik
Tom
Strony
35--54
Opis fizyczny
Bibliogr. 26 poz., tab., rys.
Twórcy
autor
- Technical University of Košice, Faculty of Mining, Ecology, Process Control and Geotechnologies, Institute of Earth Resources, Letná 9, 042 00 Košice, Slovakia
autor
- Technical University of Košice, Faculty of Mining, Ecology, Process Control and Geotechnologies, Institute of Earth Resources, Letná 9, 042 00 Košice, Slovakia
Bibliografia
- [1] FENG N., GUO X., LIANG S., Adsorption study of copper(II) by chemically modified orange peel, J. Hazard. Mater., 2009, 164 (2–3), 1286.
- [2] LI X., TANG Y., CAO X., LU D., LUO F., SHAO W., Preparation and evaluation of orange peel cellulose adsorbents for effective removal of Cd(II), Zn(II), Colloids Surf. A, 2008, 317 (1–3), 512.
- [3] PÉREZ-MARÍN A.B., MESEGUER ZAPATA V., ORTUÑO J.F., AGUILAR M., SÁEZ J., LLORÉNS M., Removal of cadmium from aqueous solutions by adsorption onto orange waste, J. Hazard. Mater., 2007, 139 (1), 122.
- [4] ANNADURAI G., JUANG R.S., LEE D.J., Adsorption of heavy metals from water using banana and orange peels, Water Sci. Technol., 2003, 47, 185.
- [5] DEMIRBAS A., Heavy metal adsorption onto agro-based waste materials. A review, J. Hazard. Mater., 2008, 157 (2–3), 220.
- [6] CIMINO G., PASSERINI A., TOSCANO G., Removal of toxic cations and Cr(VI) from aqueous solutions by hazelnut shell, Water Res., 2000, 34 (11), 2955.
- [7] BULUT Y., TEZ Z., Removal of heavy metals from aqueous solution by sawdust adsorption, J. Environ. Sci., 2007, 19 (2), 160.
- [8] TURAN N.G., MESCI B., Adsorption of copper(II) and zinc(II) ions by various agricultural by-products. Experimental studies and modelling, Environ. Prot. Eng., 2011, 37 (4), 143.
- [9] BULUT Y., TEZ Z., Adsorption studies on ground shells of hazelnut and almond, J. Hazard. Mater., 2007, 149 (1), 35.
- [10] BULUT E., ÖZACAR M., ŞENGIL I.A., Adsorption of malachite green onto bentonite: Equilibrium and kinetic studies and process design, Micr. Mes. Mater., 2008, 115 (3), 234.
- [11] ALBADARIN A.B., AL-MUHTASEB A.H., AL-LAQTAH N.A., WALKER G.M., ALLEN S.J., AHMAD M.N.M., Biosorption of toxic chromium from aqueous phase by lignin: mechanism, effect of other metal ions and salts, Chem. Eng. J., 2011, 169 (1–3), 20.
- [12] GÜNAY A., ARSLANKAYA E., TOSUN I., Lead removal from aqueous solution by natural and pretreated clinoptilolite. Adsorption equilibrium and kinetics, J. Hazard. Mater., 2007, 146 (1–2), 362.
- [13] LEVENSON R., More Modern Chemical Techniques, Royal Society of Chemistry, Cambridge 2001.
- [14] GARDEA-TORRESDEY J.L., DE LA ROSA G., PERALTA-VIDEA J.R., Use of phytofiltration technologies in the removal of heavy metals. A review, Pure Appl. Chem., 2004, 76 (4), 801.
- [15] VOLESKY B., Detoxification of metal-bearing effluents. Biosorption for the next century, Hydrometallurgy, 59 (2–3), 203.
- [16] AL-ASHEH S., DUVNJAK Z., Sorption of cadmium and other heavy metals by pine bark, J. Hazard. Mater., 1997, 56 (1–2), 35.
- [17] LEE S.B., KIM I.H., RYU D.D.Y., Structural properties of cellulose and cellulase reaction mechanism, Biotechn. Bioeng., 1983, 25 (1), 33.
- [18] ACEMIOGLU B., ALMA M.H., Equilibrium studies on adsorption of Cu(II) from aqueous solution onto cellulose, J. Coll. Int. Sci., 2001, 243 (1), 81.
- [19] MÜLLER G., JANOŠKOVÁ K., BAKALÁR T., CAKL J., JIRÁNKOVÁ H., Removal of Zn(II) from aqueous solutions using Lewatit S1468, Des. Water Treat., 2012, 37 (1–3), 146.
- [20] JIAO J., ZHAO J., PEI Y., Adsorption of Co(II) from aqueous solutions by water treatment residuals, J. Environ. Sci., 2017, 52, 232.
- [21] SIMONIN J.-P., On the comparison of pseudo-first order and pseudo-second order rate laws in the modeling of adsorption kinetics, Chem. Eng. J., 2016, 300, 254.
- [22] CARDOSO S.L., COSTA C.S.D., NISHIKAWA E., DA SILVA M.G.C., GURGEL ADEODATO VIEIRA M., Biosorption of toxic metals using the alginate extraction residue from the brown algae Sargassum filipendula as a natural ion-exchanger, J. Cleaner Prod., 2017, 165, 491.
- [23] EL-KAMASH A.M., ZAKI A.A., ABED EL GELEEL M., Modeling batch kinetics and thermodynamics of zinc and cadmium ions removal from waste solutions using synthetic zeolite A, J. Hazard. Mater., 2005, 127 (1–3), 211.
- [24] AZIZIAN S., Kinetic models of sorption. A theoretical analysis, J. Coll. Int. Sci., 2004, 276 (1), 47.
- [25] LIANG S., GUO X., FENG N., TIAN Q., Effective removal of heavy metals from aqueous solutions by orange peel xanthate, Trans. Nonfer. Met. Soc. China, 2010, 20, 187.
- [26] ZHANG Y., LI Y., YANG L., MA X., WANG L., YE Z., Characterization and adsorption mechanism of Zn2+ removal by PVA/EDTA resin in polluted water, J. Hazard. Mater., 2010, 178 (1–3), 1046.
Uwagi
PL
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-2519504c-605c-48f8-93a7-efed0efb6851