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The Efficiency of Mg-Al/Biochar for Methyl Orange and Methyl Red Removal

Treść / Zawartość
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
MgAl-LDH was directly impregnated with biochar to fabricate MgAl-Biochar (MgAl/BC) and applied to remove methyl orange (MO) and methyl red (MR). The XRD, BET, FTIR, TG-DTA and SEM analyses were conducted to characterize the prepared material. The result of XRD characterization diffraction peaks at 11.47, 22.86, 34.69, and 61.6 shows that the precursor was successfully transformed to MgAl-BC. The FT-IR analysis at vibration 1010, 1381,3447 and 1635 cm-1 illustrated that the composite was well formed. The BET analysis showed that the Surface area of the MgAl-BC composite was 111.404 m2/g which was larger than that of the precursor, equal to 23.15 m2/g. The kinetic model of the adsorption study both MR and MO were fitted to PSO and followed the Langmuir model with adsorption capacities for MR 142.857 mg/g and MO 128.205 mg/g. The regeneration study of composite indicated higher efficiency than the pristine and show good stability of adsorption process in five cycles.
Słowa kluczowe
Twórcy
  • Graduate School of Mathematics and Natural Sciences, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Padang Selasa, Bukit Besar, Palembang 30139, Indonesia
  • Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih, Km. 32, Ogan Ilir 30662, South Sumatra, Indonesia
  • Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih, Km. 32, Ogan Ilir 30662, South Sumatra, Indonesia
autor
  • Department of Pharmacy, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl Palembang Prabumulih, Km. 32, Ogan Ilir 30662, South Sumatra, Indonesia
  • Graduate School of Mathematics and Natural Sciences, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Padang Selasa, Bukit Besar, Palembang 30139, Indonesia
  • Research Center of Inorganic Materials and Complexes FMIPA Universitas Sriwijaya, Jl. Palembang Prabumulih, Km. 32, Ogan Ilir 30662, South Sumatra, Indonesia
Bibliografia
  • 1. Ayawei N., Angaye S.S., Wankasi D., Dikio E.D. 2015. Synthesis, Characterization and Application of Mg/Al Layered Double Hydroxide for the Degradation of Congo Red in Aqueous Solution. Open Journal of Physical Chemistry, 5(3), 56–70.
  • 2. Badri A.F., Siregar P.M.S.B.N., Palapa N.R., Mohadi R., Mardiyanto M., Lesbani A. 2021. Mg-Al/Biochar Composite with Stable Structure for Malachite Green Adsorption from Aqueous Solutions. Bulletin of Chemical Reaction Engineering & Catalysis, 16(1), 149–160.
  • 3. Bharali D., Deka R.C. 2017. Adsorptive removal of congo red from aqueous solution by sonochemically synthesized NiAl layered double hydroxide. Journal of Environmental Chemical Engineering, 5(2), 2056–2067.
  • 4. Cantarella M., Sanz R., Buccheri M.A., Ruffino F., Rappazzo G., Scalese S., Impellizzeri G., Romano L., Privitera V. 2016. Immobilization of nanomaterials in PMMA composites for photocatalytic removal of dyes, phenols and bacteria from water. Journal of Photochemistry and Photobiology A: Chemistry, 321, 1–11.
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  • 6. Duan C., Meng X., Liu C., Lu W., Liu J., Dai L., Wang W., Zhao W., Xiong C., Ni Y. 2019. Carbohydratesrich corncobs supported metal-organic frameworks as versatile biosorbents for dye removal and microbial inactivation. Carbohydrate Polymers, 222, 115042.
  • 7. Gholami P., Dinpazhoh L., Khataee A., Hassani A., Bhatnagar A. 2020. Facile hydrothermal synthesis of novel Fe-Cu layered double hydroxide/biochar nanocomposite with enhanced sonocatalytic activity for degradation of cefazolin sodium. Journal of Hazardous Materials, 381(5), 120742.
  • 8. Juleanti N., Palapa N.R., Taher T., Hidayati N., Putri B.I., Lesbani A. 2021. The Capability of BiocharBased CaAl and MgAl Composite Materials as Adsorbent for Removal Cr ( VI ) in Aqueous Solution. Science and Technology Indonesia, 6(3), 156–165.
  • 9. Lee S.Y., Choi J.W., Song K.G., Choi K., Lee Y.J., Jung K.W. 2019. Adsorption and mechanistic study for phosphate removal by rice husk-derived biochar functionalized with Mg/Al-calcined layered double hydroxides via co-pyrolysis. Composites Part B: Engineering, 176, 107209.
  • 10. Lesbani A., Azmi M.F., Palapa N.R., Taher T., Andreas R., Mohadi R. 2021. Ni/Cr- [α -SiW12O 40] Layered Double Hydroxide as Effective Adsorbent of Iron (II) From Aqueous Solution. Eurasian Chemistry Technology Journal, 23(2021), 103–110.
  • 11. Lesbani A., Palapa N.R., Sayeri R.J., Taher T., Hidayati N. 2021. High Reusability of NiAl LDH/Biochar Composite in the Removal Methylene Blue from Aqueous Solution. Indonesian Journal of Chemistry, 21(2), 421–434.
  • 12. Lu Y., Jiang B., Fang L., Ling F., Gao J., Wu F., Zhang X. 2016. High performance NiFe layered double hydroxide for methyl orange dye and Cr(VI) adsorption. Chemosphere, 152, 415–422.
  • 13. Meili L., Lins P.V., Zanta C.L.P.S., Soletti J.I., Ribeiro L.M.O., Dornelas C.B., Silva T.L., Vieira M.G.A. 2019. MgAl-LDH/Biochar composites for methylene blue removal by adsorption. Applied Clay Science, 168, 11–20.
  • 14. Natarajan S., Anitha V., Gajula G.P., Thiagarajan V. 2020. Synthesis and Characterization of Magnetic Superadsorbent Fe3 O4-PEG-Mg-Al-LDH Nanocomposites for Ultrahigh Removal of Organic Dyes. ACS Omega, 5(7), 3181–3193.
  • 15. Normah N., Juleanti N., Siregar P.M.S.B.N., Wijaya A., Palapa N.R., Taher T., Lesbani A. 2021. Size Selectivity of Anionic and Cationic Dyes Using LDH Modified Adsorbent with Low-Cost Rambutan Peel to Hydrochar. Bulletin of Chemical Reaction Engineering & Catalysis, 16(4), 869–880.
  • 16. Oktriyanti M., Palapa N.R., Mohadi R., Lesbani A. 2019. Indonesian Journal of Environmental Management and Sustainability Modification Of Zn-Cr Layered Double Hydroxide With Keggin Ion. Indonesian Journal of Environmental Management and Sustainability, 3(3), 93–99.
  • 17. Palapa N.R., Mohadi R., Rachmat A., Lesbani A. 2020. Adsorption Study of Malachite Green Removal from Aqueous Solution Using Cu/M3+(M3+=Al,Cr) Layered Double Hydroxide. Mediterranean Journal of Chemistry, 10(1), 33–45.
  • 18. Palapa N.R., Saria Y., Taher T., Mohadi R., Lesbani A. 2019. Synthesis and Characterization of Zn/Al, Zn/Fe, and Zn/Cr Layered Double Hydroxides: Effect of M3+ ions Toward Layer Formation. Science and Technology Indonesia, 4(2), 36–39.
  • 19. Puchana-Rosero M.J., Adebayo M.A., Lima E.C., Machado F.M., Thue P.S., Vaghetti J.C.P., Umpierres C.S., Gutterres M. 2016. Microwave-assisted activated carbon obtained from the sludge of tannery-treatment effluent plant for removal of leather dyes. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 504, 105–115.
  • 20. Santos R.M.M. dos Gonçalves R.G.L., Constantino V.R.L., Santilli C.V., Borges P.D., Tronto J., Pinto F.G. 2017. Adsorption of Acid Yellow 42 dye on calcined layered double hydroxide: Effect of time, concentration, pH and temperature. Applied Clay Science, 140, 132–139.
  • 21. Streit A.F.M., Côrtes L.N., Druzian S.P., Godinho M., Collazzo G.C., Perondi D., Dotto G.L. 2019. Development of high quality activated carbon from biological sludge and its application for dyes removal from aqueous solutions. Science of the Total Environment, 660, 277–287.
  • 22. Tran H.N., Lin C.C., Chao H.P. 2018. Amino acidsintercalated Mg/Al layered double hydroxides as dual-electronic adsorbent for effective removal of cationic and oxyanionic metal ions. Separation and Purification Technology, 192, 36–45.
  • 23. Vinsiah R., Mohadi R., Lesbani A. 2020. Indonesian Journal of Environmental Management and Sustainability Performance of Graphite for Congo Red and Direct Orange Adsorption. Indonesian Journal of Environmental Management and Sustainability, 4(4), 125–132.
  • 24. Wijaya A., Siregar P.N.B.S.M., Priambodo A., Palapa N.R., Taher T., Lesbani A. 2021. Innovative Modified of Cu-Al/C(C=Biochar, Graphite) Composites for Removal of Procion Red from Aqueous Solution. Science and Technology Indonesia, 6(4), 228–234.
  • 25. Yu J., Zhang X., Wang D., Li P. 2018. Adsorption of methyl orange dye onto biochar adsorbent prepared from chicken manure. Water Science and Technology, 77(5–6), 1303–1312.
  • 26. Zhao G., Liu L., Li C., Zhang T., Yan T., Yu J., Jiang X., Jiao F. 2018. Construction of diatomite/ZnFe layered double hydroxides hybrid composites for enhanced photocatalytic degradation of organic pollutants. Journal of Photochemistry and Photobiology A: Chemistry, 367, 302–311.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-1be2bf2d-0eaa-4319-b30b-e1f465f9d52c
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