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Tytuł artykułu

Synthesis and characterization of poly(acrylic acid)/organo-modified nanohydroxyapatite nanocomposites: thermal, optical and biocompatibility properties

Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The aim of this study was to investigate the structural, thermal, optical and biocompatibility properties of poly(acrylic acid)(PAA)/organo-modified nanohydroxyapatite (OM-nHAp) nanocomposites synthesized by solvent intercalation method. The characterization of PAA/OM-nHAp nanocomposites was made by different techniques. SEM and TEM results showed that OM-nHAp particles were dispersed in the nanoscale into PAA matrix and that they were uniformly distributed within film. Glass transition temperature of PAA increased with OM-nHAp content. Ultraviolet (UV) absorbance experiments showed that PAA had a higher UV transmission than its nanocomposites. The biocompatibility of nanocomposites was also examined in simulated body fluid.
Rocznik
Strony
54--67
Opis fizyczny
Bibliogr. 30 poz., rys., wykr., tab.
Twórcy
autor
  • Balikesir University, Science and Technology Application and Research Center, Turkey
autor
  • Balikesir University Faculty of Science and Literature Department of Molecular Biology and Genetics, Turkey
autor
  • Balikesir University Faculty of Science and Literature Department of Chemistry, Turkey
autor
  • Balikesir University Faculty of Science and Literature Department of Chemistry, Turkey
Bibliografia
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  • 12. Khan, A.S., Wong, F.S.L., McKay, I.J., Whiley, R.A., Rehman, I.U. Structural, mechanical, and biocompatibility analyses of a novel dental restorative nanocomposite. J. Appl. Polym. Sci. 130 (2013), 439-447.
  • 13. El-Bahy, G.S., Abdelrazek, E.M., Allam, M.A., Hezma, A.M. Characterization of in situ prepared nano-hydroxyapatite/polyacrylic acid (HAp/PAAc) biocomposites. Journal of Applied Polymer Science. 122 (2011), 3270–3276.
  • 14. Darder, M., Colilla, M., Ruiz-Hitzky, E. Biopolymer−Clay Nanocomposites Based on Chitosan Intercalated in Montmorillonite. Chem. Mater. 15(20) (2003), 3774–3780.
  • 15. Wang, S.F., Shen, L., Zhang, W-D., Tong, Y-J. Preparation and mechanical properties of chitosan/carbon nanotubes composites. Biomacromolecules, 6(6) (2005), 3067–3072.
  • 16. Turhan, Y., Turan, P., Doğan, M., Alkan, M., Namli, H. and Demirbaş, Ö. Characterization and adsorption properties of chemically modified sepiolite. Industrial & Engineering Chemistry Research. 47(6) (2008), 1883-1895.
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  • 18. Kızılduman, B.K., Alkan, M., Doğan, M., Turhan, Y. Al-pillared-montmorillonite (AlPMt)/poly(methyl methacrylate)(PMMA) nanocomposıtes: the effects of solvent types and synthesıs methods. Advances in Materials Science, 17(3) (2017), 5-23.
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  • 20. Turhan, Y., Alp, Z.G., Alkan, M., Doğan, M., Preparation and characterization of poly(vinylalcohol)/modified bentonite nanocomposites. Microporous and Mesoporous Materials. 174 (2013), 144-153.
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  • 23. Hojjati, B., Sui, R., Charpentier, P.A. Synthesis of TiO2/PAA nanocomposite by RAFT polymerization. Polymer. 48 (2007), 5850-5858.
  • 24. Dubinsky, S., Grader, G.S., Shter, G.E., Silverstein, M.S. Thermal degradation of poly(acrylic acid) containing copper nitrate. Polymer Degradation and Stability. 86 (2004), 171-178.
  • 25. Turhan, Y., Doğan, M., Alkan, M. Characterization and some properties of poly(vinyl chloride)/sepiolite nanocomposites. Advances in Polymer Technology. 32(1) (2013) E65-E82.
  • 26. Corcione, C.E., Frigione, M. Characterization of nanocomposites by thermal analysis. Materials. 5 (2012), 2960-2980.
  • 27. Fuente, J.L., Wilhelm, M., Spiess, H.W., Madruga, E.L., Fernandez-Garcia, M. Cerrada, M.L. Thermal, morphological and rheological characterization of poly(acrylic acid-g-styrene) amphiphilic graft copolymers. Polymer. 46 (2005), 4544–4553.
  • 28. McGaugh, M.C., Kottle, S. The thermal degradation of poly(acrylic acid). Journal of Polymer Science Part B: Polymer Letters. Journal of Polymer Science Part B: Polymer Letters. 5(9) (1967), 817–820.
  • 29. Beyli, P.T., Doğan, M., Gündüz, Z., Alkan, M., Turhan, Y. Synthesis, characterization and their antimicrobial activities of boron oxide/poly(acrylic acid) nanocomposites: thermal and antimicrobial properties. Advances in Materials Science, 18(1) (2018), 28-36.
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Uwagi
PL
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-15a20883-1a69-4108-8539-256445c51e7a
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