Effective Removal of Iron (II) from Aqueous Solution by Adsorption using Zn/Cr Layered Double Hydroxides Intercalated with Keggin Ion

• Autorzy: Oktriyanti Melantina , Palapa Neza Rahayu , Mohadi Risfidian , Lesbani Aldes

Identyfikatory

DOI

10.12911/22998993/122190

• Języki publikacji: EN

Abstrakty

EN

Zn/Cr and Zn/Cr layered double hydroxides (LDHs) intercalated with Keggin ion [α-SiW₁₂O₄₀]^4-were successfully synthesized at room temperature and pH value of 10. The synthesized materials were characterized by means of the XRD, BET, and FT-IR analyses and used as an adsorbent iron(II). The adsorption process was investigated by studying pH, the kinetics, and thermodynamic properties of the adsorption process. The results showed the interlayer Zn/Cr LDHs was 7.53 Å and increase to 10.26 Å on Zn/Cr LDHs intercalated with Keggin ion [α-SiW₁₂O₄₀]^4-. The BET analysis showed that the pore volume of both materials increased from 0.063 cm³ g^-1 to 0.163 cm³ g^-1. The pH point zero charge measurement for the Zn/Cr LDHs material was 10 while LDHs Zn/Cr intercalated with Keggin ion [α-SiW₁₂O₄₀]^4- was 8. Zn/Cr LDHs intercalated with Keggin ion [α-SiW₁₂O₄₀]^4- has higher adsorption capacity than Zn/Cr LDHs without intercalation. Desorption of iron (III) was successfully conducted using HCl as reagent showing the involvement of ion exchange in the adsorption.

Słowa kluczowe

EN

adsorption; iron(II); desorption; zinc; chromium; layered double hydroxide

• Wydawca: Polskie Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology
• Czasopismo: Journal of Ecological Engineering
• Rocznik: 2020
• Tom: Vol. 21, nr 5
• Strony: 63--71
• Opis fizyczny: Bibliogr. 21 poz., rys., tab.

Twórcy

autor

Oktriyanti Melantina

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Padang Selasa Bukit Besar Palembang 30139, Indonesia

autor

Palapa Neza Rahayu

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Padang Selasa Bukit Besar Palembang 30139, Indonesia

autor

Mohadi Risfidian

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Padang Selasa Bukit Besar Palembang 30139, Indonesia

autor

Lesbani Aldes

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Padang Selasa Bukit Besar Palembang 30139, Indonesia

Bibliografia

• 1. Abdelrahman, E.A. 2018. Synthesis of zeolite nanostructures from waste aluminum cans for efficient removal of malachite green dye from aqueous media. Journal of Molecular Liquids 253, 72–82.
• 2. Aparicio-Anglès, X., Miró, P., Clotet, A., Bo, C., Poblet, J. M. 2012. Polyoxometalates adsorbed on metallic surfaces: immediate reduction of [SiW 12O 40] 4on Ag(100). Chemical Science 3(6), 2020–27.
• 3. Boulaiche, W., Hamdi, B., Trari, M. 2019. Removal of heavy metals by chitin: equilibrium, kinetic and thermodynamic studies. Applied Water Science 9(2), 1–10.
• 4. Cherfi, A., Abdoun, S., Gaci, O. 2014. Food survey: levels and potential health risks of Chromium, Lead, Zinc and Copper content in fruits and vegetables consumed in Algeria. Food and Chemical Toxicology 70, 48–53.
• 5. Fu, F., Dionysiou, D.D., Liu, H. 2014. The use of zero-valent iron for groundwater remediation and wastewater treatment: A review. Journal of Hazardous Materials 267, 194–205.
• 6. Fu, F., Wang, Q. 2011. Removal of heavy metal ions from wastewaters: A review. Journal of Environmental Management 92(3), 407–18.
• 7. Hirata, N., Tadanaga, K., Tatsumisago, M. 2015. Photocatalytic O2 evolution from water over Zn-Cr layered double hydroxides intercalated with inorganic anion. Materials Research Bulletin 62, 1–4.
• 8. Huang, D., Liu, C., Zhang, C., Deng, R., Wang, R., Xue, W., Luo, H., Zeng, G., Zhang, Q., Guo, X. 2019. Cr(VI) removal from aqueous solution using biochar modified with Mg/Al-layered double hydroxide intercalated with ethylenediaminetetraacetic acid. Bioresource Technology 276, 127–32.
• 9. Lesbani, A., Hensen, H., Taher, T., Hidayati, N., Mohadi, R., Andreas, R. 2018. Intercalation of Zn/ Al layered double hydroxides with keggin ion as adsorbent of Cadmium(II). AIP Conference Proceedings, 2026.
• 10. Lü, Z., Hu, F., Li, H., Zhang, X., Yu, S., Liu, M., & Gao, C. 2019. Composite nanofiltration membrane with asymmetric selective separation layer for enhanced separation efficiency to anionic dye aqueous solution. Journal of Hazardous Materials 19, 436–43.
• 11. Oktriyanti, M., Palapa, N.R., Mohadi, R., Lesbani, A. 2019. Modification of Zn-Cr layered double hydroxide with keggin ion. Indonesian Journal of Environmental Management and Sustainability 3(3), 93–99.
• 12. Oliveira, J.A., Cunha, F.A., Ruotolo, L.A.M. 2019. Synthesis of zeolite from sugarcane bagasse fly ash and its application as a low-cost adsorbent to remove heavy metals. Journal of Cleaner Production 229, 956–63.
• 13. Palapa, N.R., Saria, Y., Taher, T., Mohadi, R., Lesbani, A. 2019. Synthesis and characterization of Zn/Al, Zn/Fe, and Zn/Cr layered double hydroxides: Effect of M3+ ions toward layer formation. Science and Technology Indonesia 4(2), 36–39.
• 14. Peligro, F.R., Pavlovic, I., Rojas, R., Barriga, C. 2016. Removal of heavy metals from simulated wastewater by in situ formation of layered double hydroxides. Chemical Engineering Journal. 306, 1035–1040
• 15. Rahman, M.T., Kameda, T., Kumagai, S., Yoshioka, T. 2018. A novel method to delaminate nitrate-intercalated Mg–Al layered double hydroxides in water and application in heavy metals removal from waste water. Chemosphere 203, 281–90.
• 16. Taher, T., Christina, M.M., Said, M., Hidayati, N., Ferlinahayati, F., Lesbani, A. 2019. Removal of iron(II) using intercalated Ca/Al layered double hydroxides with [-SiW12 O40]4-. Bulletin of Chemical Reaction Engineering & Catalysis 14(2), 260–67.
• 17. Taher, T., Mohadi, R., Rohendi, D., Lesbani, A. 2017. Kinetic and Thermodynamic adsorption studies of congo red on bentonite. AIP Conference Proceedings, 1823.
• 18. Tran, H.N., Lin, C.C., Woo, S. H., Chao, H.P. 2018. Efficient removal of Copper and Lead by Mg/Al layered double hydroxides intercalated with organic acid anions: Adsorption kinetics, isotherms, and thermodynamics. Applied Clay Science 154, 17–27.
• 19. Wang, F., Pan, Y., Cai, P., Guo, T., Xiao, H. 2017. Single and binary adsorption of heavy metal ions from aqueous solutions using sugarcane cellulose-based adsorbent. Bioresource Technology 241, 482–90.
• 20. Zhou, H., Jiang, Z., Wei, S. 2018. A New Hydrotalcite-Like Absorbent FeMnMg-LDH and its adsorption capacity for Pb2+ ions in water. Applied Clay Science 153, 29–37.
• 21. Zubieta, C., Sierra, M.B., Morini, M.A., Schulz, P. C., Albertengo, L., Rodŕguez, M.S. 2008. The adsorption of dyes used in the textile industry on mesoporous materials. Colloid and Polymer Science 286(4), 377–84.

Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).