Soft Ion Divalent Metals toward Adsorption on Zn/Al-POM Layered Double Hydroxide

• Autorzy: Silaen Luna , Elfita , Mohadi Risfidian , Normah , Juleanti Novie , Palapa Neza Rahayu , Lesbani Aldes

Identyfikatory

DOI

10.12911/22998993/142122

• Języki publikacji: EN

Abstrakty

EN

Development of Zn/Al layered double hydroxide by intercalation using polyoxometalate (POM) K₄ [α-SiW₁₂O₄₀] to Zn/Al-POM was investigated. The success of the modification is evidenced by the XRD, FT-IR, and BET characterization data. XRD characterization showed an increase in the interlayer distance from 8.59 Å in Zn/Al LDHs to 10.26 Å in Zn/Al-POM. This success is also supported by the FT-IR data with the appearance of vibrations around 779–979 cm^-1 which indicates the vibration of the polyoxometalate compound in Zn/Al-POM. Other supporting data in the form of BET also prove an increase in surface area from 1.968 m²/g in Zn/Al LDHs to 14.042 m²/g Zn/Al-POM. The ability of Zn/Al-POM as an adsorbent is proven through several parameters such as kinetics, isotherm, thermodynamics, and regeneration for Cd²⁺, Pb²⁺, Ni²⁺, and Co²⁺. Adsorption kinetics showed that Zn/Al-POM was more likely to follow the pseudo-second-order adsorption kinetics model for Cd²⁺, Pb²⁺, Ni²⁺, and Co²⁺. The results of determining the adsorption isotherm parameters of Zn/Al-POM tend to follow the Freundlich isotherm model with a maximum adsorption capacity of 74.13 mg/g on Pb²⁺. The regeneration process showed that Zn/Al-POM was more resistant than Zn/Al LDHs up to 3 cycles. It was proven that Zn/Al-POM was able to survive in the last cycle up to 69.19% on Ni²⁺.

Słowa kluczowe

EN

soft divalent metal ions; adsorption; polyoxometalate; regeneration

• Wydawca: Polskie Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology
• Czasopismo: Journal of Ecological Engineering
• Rocznik: 2021
• Tom: Vol. 22, nr 10
• Strony: 109--120
• Opis fizyczny: Bibliogr. 41 poz., rys., tab.

Twórcy

autor

Silaen Luna

• Graduate School, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Padang Selasa No. 524 Ilir Barat 1, Palembang-South Sumatra, Indonesia

autor

Elfita

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Palembang-Prabumulih, Km. 32, Ogan Ilir, South Sumatra, Indonesia

autor

Mohadi Risfidian

• Department of Environmental Science, Graduate School, Sriwijaya University, Jl. Padang Selasa No. 524 Ilir Barat 1, Palembang-South Sumatra, Indonesia

autor

Normah

• Research Center of Inorganic Materials and Coordination Complexes, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Palembang Prabumulih Km.32 Ogan Ilir 30662, Indonesia

autor

Juleanti Novie

• Research Center of Inorganic Materials and Coordination Complexes, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Palembang Prabumulih Km.32 Ogan Ilir 30662, Indonesia

autor

Palapa Neza Rahayu

• Research Center of Inorganic Materials and Coordination Complexes, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Palembang Prabumulih Km.32 Ogan Ilir 30662, Indonesia

autor

Lesbani Aldes

• Graduate School, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Padang Selasa No. 524 Ilir Barat 1, Palembang-South Sumatra, Indonesia
• Research Center of Inorganic Materials and Coordination Complexes, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Jl. Palembang Prabumulih Km.32 Ogan Ilir 30662, Indonesia

• https://orcid.org/0000-0001-5054-2324

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