Comparison of Sequential Extraction Procedures for As Partitioning in Contaminated Soils

• Autorzy: Gusiatin Z. M. , Marzec M. M.

Warianty tytułu

PL

Porównanie metod ekstrakcji sekwencyjnej do określenia form chemicznych arsenu w zanieczyszczonych glebach

• Języki publikacji: EN

Abstrakty

EN

The aim of present study was to review and characterize selected procedures for determination of As chemical forms in soil. The methodology, wherein conditions and the way of extraction for five procedures of sequential analysis (Tessier et al, Chao and Sanzolone, BCR, Wenzel et al, Matera et al) in industrial soils with different contamination degree of As were presented. Application of individual sequential extraction procedures (SEPs) enables to analyze between 4 and 7 chemical forms of arsenic. The methods differ in the type and volume of used reagents, duration of extraction and total cost. From economical point of view the most suitable seems to be 5-step procedure by Chao and Sanzolone. Determination of detailed arsenic distribution in soil provides procedure by Matera et al.

PL

Celem pracy był przegląd oraz szczegółowa charakterystyka wybranych metod oznaczania form chemicznych arsenu w glebie. Zaprezentowano warunki oraz sposób ekstrakcji pięciu stosowanych procedur analizy sekwencyjnej arsenu w glebach z terenów przemysłowych, w których stopień zanieczyszczenia arsenem jest zróżnicowany. Należą do nich metoda Tessiera i in., Chao i Sanzolone, BCR, Wenzla i in. oraz Matery i in. Zastosowanie poszczególnych metod umożliwia analizę od 4 do 7 form chemicznych arsenu. Różnią się one rodzajem i objętością zużywanych odczynników chemicznych, czasem trwania ekstrakcji oraz całkowitym kosztem. Z ekonomicznego punktu widzenia najbardziej odpowiednią wydaje się być 5-stopniowa procedura według Chao i Sanzolone. Określenie szczegółowej dystrybucji arsenu zapewnia natomiast metoda według Matery i in.

Słowa kluczowe

EN

arsenic; soil; sequential extraction procedure

PL

arsen; gleba; ekstrakcja sekwencyjna

• Wydawca: Towarzystwo Chemii i Inżynierii Ekologicznej
• Czasopismo: Ecological Chemistry and Engineering. A
• Rocznik: 2013
• Tom: Vol. 20, nr 3
• Strony: 351--361
• Opis fizyczny: Bibliogr. 32 poz., tab., wykr.

Twórcy

autor

Gusiatin Z. M.

• Department of Environmental Biotechnology, University of Warmia and Mazury in Olsztyn, ul. S³oneczna 45G, 10-719 Olsztyn, Poland, phone: [phone]

autor

Marzec M. M.

• Department of Environmental Biotechnology, University of Warmia and Mazury in Olsztyn, ul. S³oneczna 45G, 10-719 Olsztyn, Poland, phone: [phone]

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