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Materiały ceramiczne z grupy perowskitów podwójnych na bazie BaYMn2O5+δ dla technologii magazynowania tlenu

100%

Klimkowicz A. , Zheng K. , Fiołka G. , Świerczek K.

Materiały Ceramiczne

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2013

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tom T. 65, nr 1

92--96

PL

W niniejszej pracy przedstawiono charakterystykę właściwości strukturalnych, oraz wyniki badań pojemności magazynowania tlenu, materiałów ceramicznych z grupy perowskitów podwójnych BaY1-xSmxMn2O5+δ (x = 0, 0,25, 0,5, 0,75 i 1). Podobnie jak materiał wyjściowy BaYMn2O5+δ, związki podstawiane Sm wykazują strukturę z warstwowym uporządkowaniem podsieci Ba-Y1-xSmx. Materiały zredukowane (δ ≈ 0) krystalizują w układzie tetragonalnym z grupą przestrzenną P4/nmm. W przypadku materiałów utlenionych (δ ≈ 1) zaobserwowano strukturę trójskośną P-1 dla składów o zawartości samaru x ≤ 0,5. Dla związków o zawartości x > 0,5 proces utleniania nie powoduje zmian symetrii, a materiały te różnią się od zredukowanych jedynie stopniem obsadzenia przez tlen pozycji strukturalnych oraz objętością komórki elementarnej. W przypadku całej serii materiałów zmierzono odwracalną pojemność magazynowania tlenu przekraczającą 99% wartości teoretycznej, sięgającą od 3,35% wag. dla BaSmMn2O5+δ do 3,82% wag. dla BaYMn2O5+δ. Niższa pojemność związków zawierających samar wynika z ich wyższej masy molowej. Podstawienie itru samarem istotnie wpływa na temperaturę i kinetykę procesów redukcji i utleniania, co umożliwia zaprojektowanie materiału wykazującego żądane właściwości dla zastosowań technologicznych.

EN

Characterization of structural properties and results of measurements of oxygen storage capacity of ceramic materials from the BaY1-xSmxMn2O5+δ (x = 0, 0.25, 0.5, 0.75 and 1) group of double perovskites are presented in this work. Similarly to initial BaYMn2O5+δ, Sm-substituted compounds exhibit the structure with layered arrangement of the Ba-Y1-xSmx sublattice. Reduced materials (δ ≈ 0) crystallize in tetragonal symmetry with P4/nmm space group. In the case of oxidized materials (δ ≈ 1), the triclinic P-1 structure was observed for compositions with samarium content x ≤ 0.5. For compounds with x > 0.5 the oxidation process does not cause a change of the symmetry, and these materials differ from the reduced one only by occupation of crystal positions by oxygen and by unit cell volume. In case of whole series of the materials, the measured reversible oxygen storage capacity exceeded 99% of theoretical one, which was from 3.35 wt.% for BaSmMn2O5+δ up to 3.82 wt.% for BaYMn2O5+δ. Lower capacity of Sm-containing materials was due to their higher molar mass. The substitution of yttrium by samarium significantly influenced the temperature and kinetics of reduction and oxidation, which allows for designing of material exhibiting required properties for technological applications.

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Modyfikacja BaYMn2O5+δ w aspekcie rozwoju technologii magazynowania tlenu w tlenkach perowskitowych

100%

Klimowicz A. , Zheng K. , Fiołka G. , Świerczek K.

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tom Vol. 67, nr 12

1199--1206

PL

Niniejsza praca prezentuje metodę modyfikacji właściwości związanych z magazynowaniem tlenu w układzie BaYMn2O5- BaYMn2O6 poprzez chemiczne podstawienie itru gadolinem. Praca zawiera charakterystykę właściwości strukturalnych oraz wyniki pomiarów odwracalnej pojemności magazynowania tlenu dla perowskitów z uporządkowaną podsiecią kationową A, należących do grupy BaY1-xGdxMn2O5+δ (x = 0; 0,25; 0,5; 0,75 oraz 1.0). Pomiary rentgenowskie potwierdziły tworzenie roztworów stałych, a materiały zawierające gadolin wykazują strukturę z warstwowym uporządkowaniem podsieci Ba-Y1-xGdx. Większe kationy Gd3+ powodują wzrost objętości komórki elementarnej zarówno dla materiałów zredukowanych BaY1-xGdxMn2O5, jak i dla utlenionych BaY1-xGdxMn2O6. Oprócz zmian strukturalnych, gadolin powoduje też zmianę właściwości związanych z magazynowaniem tlenu. Ich poprawa polega głównie na znaczącym przyspieszeniu szybkości redukcji oraz na obniżeniu temperatury charakterystycznej utleniania, jednakże, ze względu na większą masę molową, materiały zawierające gadolin wykazują obniżoną odwracalną pojemność magazynowania tlenu. Przedstawione w pracy wyniki wskazują, że chemiczna modyfikacja BaYMn2O5+˂ umożliwia otrzymanie materiałów o polepszonych właściwościach, co może w przyszłości doprowadzić do zasadniczego postępu w rozwoju technologii magazynowania tlenu w tlenkach o strukturze perowskitu.

EN

This work presents an approach to modification of oxygen storage properties of BaYMn2O5- BaYMn2O6 system by a chemical substitution of yttrium by gadolinium. Characterization of structural properties and results of measurements of reversible oxygen storage capacity of A-site cation ordered perovskites, belonging to BaY1-xGdxMn2O5+δ (x = 0, 0.25, 0.5, 0.75 and 1.0) family are presented. Formation of solid solutions was confirmed by x-ray measurements, with Gd-containing compounds exhibiting structure with layered arrangement of Ba-Y1-xGdx sub-lattice. Larger Gd3+ cations cause an increase of unit cell volume of reduced BaY1-xGdxMn2O5, as well as oxidized BaY1-xGdxMn2O6. Apart from structural modification, gadolinium significantly changes oxygen storage properties of the compounds. The major improvement is related to a significantly faster reduction rate, as well as to a lower characteristic temperature of oxidation, however, due to a higher molar mass, Gd-containing materials exhibit reduced reversible oxygen storage capacity. The presented results indicate that chemical modification of BaYMn2O55+δ allows to obtain materials with enhanced properties, which may lead to a significant progress of oxygen storage technology in perovskite oxides in the future.

3

Mass–density relationship changes along salinity gradient in Suaeda salsa L.

100%

Zhang H. , Wang G. , Zheng K. , Zhang W.

Acta Physiologiae Plantarum

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2010

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tom 32

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nr 6

EN

Whether and why the biomass–density (M–N) scaling relationship varies along environmental gradients were continuously debated in theoretical ecology. In this study, how soil salinity stress affects on the M–N scaling relationship was investigated by using Suaeda salsa L. in beach of Dongtai, Jiangsu Province, China. The results showed that the exponent of the scaling relationship (b) of low salinity level (-1.259) was smaller than that of middle salinity level (-1.025), which in turn was smaller than that high salinity level (-0.698). The plant height–crown radius (H–r) scaling exponents (ϭ) decreased with increasing salinity stress, while the canopy coverage–density (C–N) scaling exponents (β) showed an inverse trend. The predict data (b) based on ϭ and β by using the geometric model were statistically indistinguishable from their observed values for the three salinity levels. Moreover, two resources utilization parameters (l mean from root to leaf, a total area of leaves) of metabolic theory, photosynthetic rate, and water-use efficiency were more advantageous to Suaeda salsa L. of high stress than to those of low salinity. Therefore, it was implied that the changes of M–N relationship along salinity gradients may be resulted from their different geometric morphologies and resource utilization in response to salinity stress.

4

Experimental investigation and modelling of hot forming B₄C/AA6061 low volume fraction reinforcement composites

88%

Zheng K. , Lin J. , Wu G. , Hall R. W. , Dean T. A.

Journal of Theoretical and Applied Mechanics

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2018

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tom Vol. 56 nr 2

457--469

EN

This paper presents an experimental investigation of the hot deformation behaviour of 15% B₄C particle reinforced AA6061 matrix composites and the establishment of a novel corresponding unified and physically-based visco-plastic material model. The feasibility of hot forming of a metal matrix composite (MMC) with a low volume fraction reinforcement has been assessed by performing hot compression tests at different temperatures and strain rates. Examination of the obtained stress-strain relationships revealed the correlation between temperature and strain hardening extent. Forming at elevated temperatures enables obvious strain rate hardening and reasonably high ductility of the MMC. The developed unified material model includes evolution of dislocations resulting from plastic deformation, recovery and punching effect due to differential thermal expansion between matrix and reinforcement particles during non-steady state heating and plastic straining. Good agreement has been obtained between experimental and computed results. The proposed material model contributes greatly to a more thorough understanding of flow stress behaviour and microstructural evolution during the hot forming of MMCs.

5

Dynamic electric vehicles charging load allocation strategy for residential area

75%

Wang Y. , Ma X. , Wang F. , Hou X. , Sun H. , Zheng K.

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2018

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tom Vol. 67, nr 3

641–-654

EN

A large amount of electric vehicles (EVs) charging load will bring significant impact to the power system. An appropriate resource allocation strategy is required for securing the power system safety and satisfying EVs charging demand. This paper proposed a power coordination allocation strategy of EVs’ in distribution systems. The strategy divides the allocation into two stages. The first stage is based on scores assigned to EVs through an entropy method, whereas the second stage allocates energy according to EV’s state of charge. The charging power is delivered in order to maximize EV users’ satisfaction and fairness without violation of grid constraints. Simulation on a typical power-limited residential distribution network proves the effectiveness of the strategy. The analysis results indicate that compared with traditional methods, EVs, which have higher charging requirement and shorter available time will get more energy delivered than others. The root-mean-square-error (RMSE) and standard-deviation (SD) results prove the effectiveness of the methodology for improving the balance of power delivery.

6

Estimation of rice neck blasta severity using spectral reflectance based on BP-neural Network

75%

Zhang H. , Hu H. , Zhang X. , Zhu L. , Zheng K. , Jin Q. , Zeng F.

Acta Physiologiae Plantarum

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2011

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tom 33

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nr 6

EN

Estimation of rice disease using spectral reflectance is important to non-destructive, rapid, and accurate monitoring of rice health. In this study, the rice reflectance data and disease index (DI) were determined experimentally and analyzed by single wave correlation, regression model and neural network model. The result showed that raw spectral reflectance and first derivative reflectance (FDR) difference of the rice necks under various disease severities is clear and obvious in the different spectral regions. There was also significantly negative or positive correlation between DI and raw spectral reflectance, FDR. The regression model was built with raw and first derivative spectral reflectance, which was correlated highly with the DI. However, due to rather complicated non-linear relations between spectral reflectance data and DI, the results of DI retrieved from the regression model was not so ideal. For this reason, an artificial neural network model (BP model) was constructed and applied in the retrieval of DI. For its superior ability for solving the nonlinear problem, the BP model provided better accuracy in retrieval of DI compared with the results from the statistic model. Therefore, it was implied that the rice neck blasts could be predicted by remote sensing technology.

7

Nitric oxide and thyroid hormone receptor alpha 1 contribute to ovarian follicular development in immature hyper- and hypo-thyroid rats

75%

Zheng K. , Sulieman F. J. , Li J. , Wei Q. , Xu M. , Shi F.

Reproductive Biology

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2015

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tom 15

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nr 1