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Open Physics
|
2011
|
tom 9
|
nr 6
1440-1445
EN
The 3D profile surface parameter H q and fractal dimension D were tested as indicators of mechanical properties inferred from fracture surfaces of porous solids. High porous hydrated cement pastes were used as prototypes of porous materials. Both the profile parameter H q and the fractal dimension D showed capability to assess compressive strength from the fracture surfaces of hydrated pastes. From a practical point of view the 3D profile parameter H q seems to be more convenient as an indicator of mechanical properties, as its values suffer much less from statistical scatter than those of fractal dimensions.
2
Content available remote A remark on nano-particle stability of cement C-S-H gel
80%
EN
Hydrated pastes of ordinary Portland cement prepared with different water-to-cement ratios were investigated by using the small-angle neutron scattering technique in the region of Q ∈ (0.0045, 0.11) Å−1. Samples of cement pastes were subjected to non-standard hydration conditions using a mix with D2O, low RH, and water-to-cement ratios spread over a very wide interval (0.4; 1.4). The investigation was focused on testing the structural stability of nano-metric particles in the cement C-S-H gel. Owing to the high structural stability of these nano-particles, their average diameter might be used as a microscopic parameter characterizing the nano-metric structure of C-S-H gels. The average diameter of the nano-particles of the studied ordinary Portland cement CEMI 42.5 R-SC was found to be close to the value of 4.2 nm and independent of the water-to-cement ratios.
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