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3 2018

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Application of the central composite design to optimization of petroleum hydrocarbons removal from oilfield water using advanced oxidation process

100%

Farzadkia M. , Ghorbanian M. , Biglari H. , Gholami M. , Mehrizi E. A.

Archives of Environmental Protection

2018

tom Vol. 44, no. 4

22--30

In the last few years, RSM method has been used widely to analyze, optimize and evaluate the interaction of independent factors for chemical, biochemical, and environmental processes. This study examined and evaluated the applicability of this method to manage Oilfield Produced Water to prevent marine environment due to the presence of hard degradable compounds by ozonation process. In this study simulated oil-water sample and a homogenizer reactor was used. The main reactor used in this study was impeinger equipped with sintered glass filter through which the treated oil-water was entered to reactor in the form of discontinuous flow. After ozonation and at the end of the reaction time (60 min), the concentration of oil hydrocarbons was determined by a gas chromatography device equipped with a flame ionization detector. The performance of the central composite design (CCD) approach was evaluated by the F-Value, P-Value, R2, lack of fit test and Adequate Precision parameters to determine the influence of effective factors, including ozonation time, pH, ozone dose, and TPH concentration on the TPH removal efficiency. The mean TPH efficiency obtained from the design of the 30-step experiment resulting from surface-response method was 49.903%, with a standard deviation of 12.47. This study showed the high power of model adopted from the central composite design to predict the hydrocarbons removal from oilfield water using advanced oxidation process, and it was proved that this model can be used alone to determine the design space nature.

Disinfecting poultry slaughterhouse wastewater using copper electrodes in the electrocoagulation process

58%

Zarei A. , Biglari H. , Mobini M. , Dargahi A. , Ebrahimzadeh G. , Narooie M. R. , Mehrizi E. A. , Yari A. R. , Mohammadi M. J. , Baneshi M. M. , Khosravi R. , Poursadeghiyan M.

Polish Journal of Environmental Studies

2018

tom 27

nr 4

Insufficiencies and deficiencies in slaughterhouses could adversely affect public health. Wastewater from slaughtering, along with high microbial pollution, results in serious pollution to the surrounding environment if not treated. This study sought to investigate the efficiency of the electrocoagulation process using copper electrodes in the disinfection of poultry slaughterhouse wastewater without any initial controlling. The physical and chemical properties of samples of wastewater taken from a poultry slaughterhouse were first analyzed. Then the samples were subjected to the electrocoagulation process using copper electrodes in potential differences of 10, 20, and 30 V over a period of 60 min. Then the removal efficiency of total coliforms was examined in accordance with standard methods found in textbooks. The results obtained from this study indicated that the efficiency of the electrocoagulation process increased by an increase in process time as well as in electric potential difference. The maximum removal efficiency of total coliforms was 100% in potential difference, equal to 30 V in the reaction time of 10 min. Moreover, the results of this study revealed that the electrocoagulation process using a copper electrode was fully able to remove total coliform from poultry slaughterhouse wastewater.

Enhancing electrocoagulation process efficiency using Astraglus gossypinus Tragacanth in turbidity removal from brackish water samples

58%

Zarei A. , Biglari H. , Mobini M. , Ebrahimzadeh G. , Yari A. R. , Narooie M. R. , Mehrizi E. A. , Dargahi A. , Baneshi M. M. , Mohammadi M. J. , Mazloomi S.

Polish Journal of Environmental Studies

2018

tom 27

nr 4

Colloidal particles are the main cause of turbidity in an aquatic environment. Water turbidity maintains pathogenic microorganisms against disinfection. In addition to increasing the consumption of antiseptic substances, mainly it causes a lot of aesthetic and non-sanitary problems such as the formation of toxic and carcinogenic side constituents in the treatment of water. In this study we investigated the efficiency of the use of tragacanth of Astraglus gossypinus (Catira) on the effectiveness of the electrocoagulation process in the removal of turbidity from brackish water. In this descriptive-analytic study, direct bentonite injections of 2 to 8 g/L were used to provide opacity. In the following, the effect of applying coagulant aid of Tragacanth of Astraglus gossypinus plant with values of 0.25 to 1.5 g/L on the efficiency of the electro-coagulation process equipped with iron electrodes in the removal of opacity from brackish water samples were examined in potential difference from 5 to 30 volts, and pH from 2 to 9 over a period of 60 min. Variation of turbidity was determined using the turbidity sensor in accordance with standard reference methods. The results showed that the highest opacity removal efficiency is about 99% for each 1 kg of opacity due to the addition of 7 g/L bentonite under neutral pH conditions, Tragacanth dose of 1.5 g/L, 8 g/L dose of NaCl, and voltage of 30 V for 30 min, along with the average consumption of iron and electrical energy of 0.18 kg and 0.53 Kwh, respectively. Thus, the use of Astraglus gossypinus tragacanth for removing turbidity as a natural coagulant aid dramatically improves the electrocoagulation process efficiency in the removal of turbidity from brackish water samples and reduces current costs of the electro-coagulation process.