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EN
Studies on combustible matter conversion during oxy-fuel combustion in circulating fluidized bed (CFB) environment are presented. A small pilot-scale CFB facility has been retrofitted to be ready for operation in an oxy-fuel regime, which means elevated partial pressure of oxygen in a gaseous atmosphere of O2/CO2. Maximum thermal load of the unit is estimated at 0.1MW. The unit is fired with polish bituminous coal. The paper is focused on carbon, combustible sulfur and fuel-N behavior in combustion chamber that runs under oxy-fuel CFB conditions. The analysis is based on in-furnace sampling of flue gas and on calculations of carbon, sulfur and nitrogen conversion ratios. The flow rate of the gas in the combustion chamber was the variable parameter of the process. The parameter change influenced distribution of particle concentration in fluidized bed material and the temperature distribution (along) the combustion chamber. Furthermore, it influenced the residence time of fuel particles in the combustion zone, and finally was reflected in the composition of flue gases. Measurement of flue gas composition was carried out on four levels of the combustion chamber, allowing to track the progress of the conversion of elemental carbon, sulfur combustible and fuel-nitrogen along the height of the combustion chamber. The described investigations are a part of the core work scheduled in the project “Advanced Technologies for Energy Generation: Oxy-combustion technology for PC and FBC boilers with CO2 capture” funded by the National Centre for Research & Development in Poland as well as supported by power industry.
EN
This paper presents a study on nitrogen conversion in oxy-fuel coal combustion in a pilot scale CFB 0.1 MWth facility. The paper is focused on fuel-N behaviour in the combustion chamber when the combustion process is accomplished under oxy-fuel CFB conditions. The analysis is based on infurnace sampling of flue gas and calculations of the conversion ratios of fuel-nitrogen (fuel-N) to NO, NO2, N2O, NH3 and HCN. For the tests, O2/CO2 mixtures with the oxygen content of 21 vol.% (primary gas) and with the oxygen content varied from 21 to 35 vol.% (secondary gas), were used as the fluidising gas. Measurements were carried out in 4 control points located along the combustion chamber: 0.43 m, 1.45 m, 2.50 m and 4.88 m. Results presented below indicate that an increased oxygen concentration in the higher part of the combustion chamber has strong influence on the behaviour of fuel based nitrogen compounds.
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