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1

Crystallization of nodular cast iron with carbides

100%

Pietrowski S. , Gumienny G.

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tom Vol. 8, iss. 4

236-240

EN

In this paper a crystallization process of nodular cast iron with carbides having a different chemical composition have been presented. It have been found, that an increase of molybdenum above 0,30% causes the ledeburutic carbides crystallization after ([alpha]+ graphite) eutectic phase crystallization. When Mo content is lower, these carbides crystallize as a pre-eutectic phase. In this article causes of this effect have been given.

2

The change of NiCrBSi alloys' phase composition after plasma spraying

100%

Dudek A.

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tom Vol. 8, iss. 3s

17-20

EN

Material for investigations was NiCrBSi powder for components' coatings which improve their corrosion resistance as well as resistance to friction wear and erosion. Plasma spraying method was used to produce a coating with thickness of 300 [mikro]m on low-alloy steel which was then remelted with the base material. Using X-ray quality analysis, phase composition was determined for: NiCrBSi powder, obtained coating and the alloyed surface layer. Crystallinity degree was also calculated for NiCrBSi layer sprayed on the base material.

3

Numerical Model for Solidification Zones Selection in the Large Ingots

100%

Wołczyński W. , Kwapisiński P. , Kania B. , Wajda W. , Skuza W. , Bydałek A. W.

Archives of Foundry Engineering

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2015

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tom Vol. 15, iss. 4

87--90

EN

A vertical cut at the mid-depth of the 15-ton forging steel ingot has been performed by curtesy of the CELSA – Huta Ostrowiec plant. Some metallographic studies were able to reveal not only the chilled undersized grains under the ingot surface but columnar grains and large equiaxed grains as well. Additionally, the structural zone within which the competition between columnar and equiaxed structure formation was confirmed by metallography study, was also revealed. Therefore, it seemed justified to reproduce some of the observed structural zones by means of numerical calculation of the temperature field. The formation of the chilled grains zone is the result of unconstrained rapid solidification and was not subject of simulation. Contrary to the equiaxed structure formation, the columnar structure or columnar branched structure formation occurs under steep thermal gradient. Thus, the performed simulation is able to separate both discussed structural zones and indicate their localization along the ingot radius as well as their appearance in term of solidification time.

4

Mechanism of free sulfur influence on the eutectic cell count and transition from graphite to cementite eutectic in cast iron Part I. Theoretical background

84%

Fraś E. , Górny M.

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2010

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tom Vol. 10, iss. 1 spec.

53--56

EN

In this work an analytical solution of general validity is used to explain the mechanism of free sulfur influence on the cell count and on the transition from graphite to cementite eutectic in cast iron. It is found that this transition can be related to the nucleation potential of graphite (represented by eutectic cell count Nv), the growth rate coefficient of graphite eutectic cell, μ the temperature range, ΔTsc and the pre-eutectic austenite volume fraction, fγ.

5

Intermetallic Phases in Alloyed Cast Iron with 18%Si Addition

84%

Stawarz M.

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tom Vol. 20, iss. 2

37--42

EN

The paper presents an analysis of a selected grade of high silicon cast iron intended for work in corrosive and abrasive conditions. The text describes its microstructure taking into account the process of crystallization, TDA analysis, EDS, XRD and the chemical composition analysis. In order to determine the phase composition, X-ray diffraction tests were carried out. The tests were executed on a Panalytical X'Pert PRO X-ray diffractometer with filtration of radiation from a lamp with copper anode and PIXcel 3D detector on the deflected beam axis. Completed tests allowed to describe the microstructure with detailed consideration of intermetallic phases present in the alloy. Results of the analysis of the examined alloy clearly show that we deal with intermetallic phases of Fe3Si, Fe5Si3 types, as well as silicon ferrite and crystals of silicon. In the examined alloy, we observed the phenomenon of segregation of carbon, which, as a result of this process, enriches the surface of silicon crystals, not creating a compound with it. Moreover, the paper demonstrates capability for crystallization of spheroidal graphite in the examined alloy despite lack of elements that contribute to balling in the charge materials.

6

Copper in Ausferritic Compacted Graphite Iron

84%

Gumienny G. , Kacprzyk B.

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tom Vol. 18, iss. 1

162--166

EN

This paper shows how it is possible to obtain an ausferrite in compacted graphite iron (CGI) without heat treatment of castings. Vermicular graphite in cast iron was obtained using Inmold technology. Molybdenum was used as alloying additive at a concentration from 1.6 to 1.7% and copper at a concentration from 1 to 3%. It was shown that ausferrite could be obtained in CGI through the addition of molybdenum and copper in castings with a wall thickness of 3, 6, 12 and 24 mm. Thereby the expensive heat treatment of castings was eliminated. The investigation focuses on the influence of copper on the crystallization temperature of the graphite eutectic mixture in cast iron with the compacted graphite. It has been shown that copper increases the eutectic crystallization temperature in CGI. It presents how this element influences ausferrite microhardness as well as the hardness of the tested iron alloy. It has been shown that above-mentioned properties increases with increasing the copper concentration.

7

Influence of modifier on base Al and Si on structure and elongation Al-7%Si alloy

84%

Lipiński T.

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tom Vol. 8, iss. 3s

55--58

EN

A homogenous modifier with Al and Si obtained by the rapid solidification at a cooling rate equal to v=200 K/s was applied to the modification of the Al-7%Si alloy. The different modifiers were obtained by means of the Al-Si alloys. The components Al, Al-7%Si and Al-12%Si were put into crucible containing the liquid Al-7%Si alloy and kept for one minute to obtain a new homogenous alloy which after break-up was homogenous modifier. Both, effect of cooling rate applied to obtain modifier and weight in weight modifier concentration in the melt on structure and elongations of Al-7%Si alloy are determined. A structural, and elongations resulting from the Al-7%Si alloy treatment by modifiers are studied in details.

8

Effect of Vanadium and Molybdenum on the Crystallization, Microstructure and Properties of Hypoeutectic Silumin

84%

Szymczak T. , Gumienny G. , Pacyniak T.

Archives of Foundry Engineering

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2015

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tom Vol. 15, iss. 4

81--86

EN

The paper presents the results of hypoeutectic silumin 226 grade and silumin produced on its basis through the addition of V and Mo. Vanadium and molybdenum were added as the preliminary alloy AlV10 and AlMo8 in an amount providing the concentration of 0.1; 0.2; 0.3 and 0.4% V and Mo. TDA curves of tested silumins were presented; regardless of the chemical composition there were similar thermal effects. Pressure castings microstructure research revealed the presence in silumins with the addition of V and Mo phases do not occur in silumin without these additives. These phases have a morphology similar to the walled, and their size increases with increasing concentration of V and Mo. The size of the precipitates of these phases silumin containing 0.1% V and Mo does not exceed 10 microns, while 0.4% of the content of these elements increases to about 80 microns. Tests of basic mechanical properties of silumins were carried out. It has been shown that the highest values of tensile strength Rm = 295 MPa and elongation A = 4.2% have silumin containing approximately 0.1% V and Mo. Increasing concentrations of these elements causes a gradual lowering of the Rm and A values.

9

Grain Refinement of AlSi7Mg0,3 Alloy Cast by Rheocasting SEED

67%

Bryksí Stunová B. , Bryksí V. , Vitkova J.

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tom Vol. 18, iss. 3

161--166

EN

The paper concerns experimental work studying chemical composition, structures and selected mechanical properties of castings produced by rheocasting method SEED. After previous experiments, which showed inclusions in the primary phase α(Al) when observing structures, hypothesis of external nuclei was taken. The main goal of the work was to determine the influence of inoculation by various additions of titanium/boron based inoculant on the structure and properties of AlSi7Mg0,3 alloy. The master alloy AlTi5B1 was added in amounts of 0,05, 0,1, 0,15, 0,2 wt %. Metallographic observation by light and SEM microscopy was used for analysing the structures. Measurements of grain size were realised and evaluated. Brinell hardness measurements were performed. Chemical composition was measured by GDS analysis. Undertaken experiments did not prove the effect of inoculation of combined AlTi5B1 master alloy on castings made of AlSi7Mg0,3 alloy made by rheocasting SEED at given amounts and conditions.

10

Effect of the remelting on transformations in Co-Cr-Mo prosthetics alloy

67%

Kacprzyk B. , Szymczak T. , Gumienny G. , Klimek L.

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tom Vol. 13, iss. 3

47--50

EN

In the article we were studing the impact of the remelting on transformations in Co-Cr-Mo prosthetics alloy. The TDA curves were analyzed, the microstructure was examined, the analysis of the chemical composition and hardness using the Brinell method was made. It was found that the obtained microstructure of the alloys that we studied do not differ significantly. In all four samples, microscopic images were similar to each other. The volume, size and distribution of the phases remain similar. Analysis of the chemical composition showed that all the samples fall within the compositions provided for the test alloy. Further to this the hardness of the samples, regardless of the number of remeltings did not show any significant fluctuations and remained within the error limit. After analyzing all the results, it can be concluded that the remeltings of the alloys should not have a significant impact on their properties. Secondarily melted alloys can be used for prosthetics works.