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1 International Journal of Applied Mechanics and Engineering

1 2003

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pH effect on rheological properties of surfactant solutions in hard water

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Broniarz-Press L. , Różański J. , Bednarz J.

International Journal of Applied Mechanics and Engineering

2003

tom Vol. 8, no spec.

201-206

In the paper the results of experiments on the both, salt and pH effect, on the rheological properties of surfactant solutions (in hard and distilled water) are presented. Three surfactants were used: hexadecyltrimethylammonium bromide (cationic), sodium oleate and potassium oleate (anionic). The special additives were sodium salicylate (NaSal), calcium and magnesium chloride, sodium sulphate, sodium phosphate as well as sodium hydroxide, hydrochloric acid of various concentrations. The studies showed the existing for a given solution the optimal pH value connected with both, the maximum of a viscosity and formation of the shear induced structure SIS. The effect of ions and pH depends on the kind of surfactant/solvent system. It has been shown that the effect of the pH of water on the rheological properties of the solutions studied is more evident for sodium oleate than for HTAB/NaSal.