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Dynamic mechanical characterization of epoxy composite reinforced with areca nut husk fiber

100%

Muralidhar N. , Vadivuchezhian K. , Arumugam V. , Reddy, I. Srinivasula , Muralidhar N. , Vadivuchezhian K. , Arumugam V. , Reddy, I. Srinivasula

nr 1

DMA analysis of the structure of crosslinked poly(methyl methacrylate)s

89%

Barszczewska-Rybarek I. M. , Korytkowska-Wałach A. , Kurcok M. , Chladek G. , Kasperski J.

tom Vol. 19, no. 1

47--53

Purpose: This paper presents the study aimed at the development of crosslinked poly(methyl methacrylate)s (X-PMMA) of varied crosslink density and the investigation of the relationships between the polymer network structure and dynamic mechanical properties. Methods: A series of model X-PMMA networks were crosslinked by the introduction of: 1, 2, 5, 10 and 20% of triethylene glycol dimethacrylate (TEGDMA). The copolymerizations led to various glass-rubber relaxation properties of the polymer networks, as revealed by dynamic-mechanical analysis (DMA). Glass temperature (Tg) and storage modulus above the Tg ( ) Erubbery  were a sensitive function of network architecture. DMA data were used for calculating the network parameter (Mc), crosslink density (q) and its alternative measure – the degree of crosslinking (DX). Results: The viscoelastic properties as well as structural parameters calculated from those showed correlation with the amount of the crosslinker. The increase in TEGDMA content resulted in the Tg, q and DX increases, whereas Mc decrease. The possible incomplete conversion of double bonds was detected in the DMA analysis, which was confirmed by the degree of conversion (DC), measured by FTIR spectroscopy. Additionally, some amount of sol fraction was found by 1H NMR experiments. Conclusions: The structure-property relationships developed for the system presented in this work could be useful in tissue engineering, where X-PMMA is applied. The direct measure of storage modulus values before and above glass transition may serve as a simple and fast indicator of the X-PMMA crosslink density.

Evaluation of physical and dynamic mechanical properties of coconut husk ash (CHA) reinforced polyester composites

89%

Ipilakyaa T. , Tuleun L. , Sule T.

tom Vol. 4, No 4

315--324

The evaluation of physical and dynamic mechanical analysis (DMA) properties was carried out on a developed Coconut Husk Ash Reinforced Polymer Composite. Sieve analysis of pretreated coconut husk ash was done to obtain 75 μm, 150 μm and 300 μm particles sizes. These particles were used at varying compositions of 5%, 10%, 15%, 20% and 25% as reinforcements for polyester composites. The catalyst and accelerator used were Methyl Ethyl Ketone Peroxide and Cobalt Naphthenate respectively. The densities of the evaluated composites made with 150 μm particles were found to be less dense with values ranging from 0.9792 g/cm3 to 1.2561 g/cm3 than those made with 75 μm and 300 μm. The results also show that the percentage water absorbed by samples increased, ranging from 0 to over 2000 E’/MPa for all percentage reinforcements of coconut husk ash, with an increase in the duration of immersion of the samples in distilled water. However, 25% reinforcement had better results for all particle sizes. There were obvious variations of storage modulus, loss modulus and mechanical loss factor with percentage weight of reinforcement, temperature and frequency. The composite with 15%reinforcement displayed better results. The composite shows promising results as a material for interior components in aerospace and automobile industries.

Dynamic Mechanical Properties of Artifcially Aged Double Base Rocket Propellant and the Possibilities for the Prediction of Their Service Lifetime

89%

Matečić-Mušanić S. , Sućeska M.

tom Vol. 10, no. 2

225--244

The ageing of double base (DB) rocket propellants, as a consequence of the chemical reactions and physical processes that take place over time, has a signifcant effect on their relevant properties, such as chemical composition and mechanical and ballistic properties. The changes to relevant properties limit the safe and reliable service life of DB rocket propellants. Accordingly, numerous research efforts have been undertaken to fnd reliable methods to measure the changes caused by ageing in order to assess the quality of DB rocket propellants at a given moment of their lifetime, and to predict their remaining service lifetime. In this work we studied the dynamic mechanical properties of DB rocket propellant artifcially aged at temperatures of 80, 85 and 90 °C, in order to detect and quantify changes in the dynamic mechanical properties caused by ageing, and to investigate the possibilities for the prediction of service lifetime. Dynamic mechanical properties were studied using a dynamic mechanical analyser (DMA). The results obtained have shown that ageing causes signifcant changes in the storage modulus (E´), the loss modulus (E˝) and the tan δ curves’ shape and position. These changes are quantifed by following some characteristic points on the E´-T, E˝-T, and tan δ-T curves (e.g. glass transition temperatures; storage modulus, loss modulus and tan δ at characteristic temperatures, etc.). It has been found that the monitored parameters are temperature and time dependent, and that they can be shown to be functions of the so called ‘reduced time of artifcial ageing’. In addition, it has been found that, on the basis of known changes in viscoelastic properties as a function of time and ageing temperature, and the known kinetic parameters of the ageing process, it is possible to calculate (determine) the change in the properties at any ageing temperature provided that the mechanism of the ageing process does not change. Unfortunately, the use of kinetic parameters obtained by artifcial ageing at high temperatures (above 60 °C) for the prediction of the propellant lifetime will not give reliable results, because the mechanisms of ageing at 85 °C and 25 °C are not the same.