The effects of Si, O, C and N ion implantation with different implantation doses on yellow luminescence (YL) of GaN have been investigated. The as-grown GaN samples used in the work were of unintentional doped n-type, and the photoluminescence (PL) spectra of samples had strong YL. The experimental results showed that YL of ion implanted samples exhibited marked reductions compared to samples with no implantation, while the near band edge (NBE) emissions were reduced to a lesser extent. The deep-level centers associated with YL may be produced in GaN films by O and C ion implantation, and identities of these deep-level centers were analyzed. It was also found that the dose dependence of YL was analogous with the one of the intensity ratios of YL to the near band edge (NBE) emission (I YL/I NBE) for ion implanted samples. The possible reason for this comparability has been proposed.
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Otrzymano cztery metakrylany w-(9-karbazolio)alkilowe wychodząc z w-(9-bromoalkilo)karbazoli oraz z soli metalu alkalicznego z kwasem metakrylowym. Metakrylany te poddano polimeryzacji w toluenie, stosując AIBN jako inicjator. Ciężary cząsteczkowe otrzymanych polimerów oznaczono metodą GPC. Stwierdzono, że źródła fotoluminescencyjne w fazie stałej uzyskanych polimerów i użytego do porównania poliwinylokarbazolu są podobne. Natężenie emisji zależy od długości łańcucha alkilowego (C2-C6) i wzrasta wraz ze zwiększeniem jego długości.
EN
Four monomers, viz., w-(9-carbazolyl)alkyl methacrylates, were prepared from 9-(w-bromoalkyl)carbazoles and alkali metal salts of metha-crylic acid. The methacrylates were polymerized in toluene by using azobisisobutyronitrile (AIBN) as initiator. Molecular weights of the resulting polymers were established by gel permeation chromatography (GPC). Photoluminescence spectra were recorded for the four synthesized polymers in the solid state and for poly(vinyl carbazole). The spectra were found to be comparable, the intensity of emission was found to be related to the number of carbon atoms in the alkyl chain (C2-C6) and to increase as the length of the chain was increased.
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