Bi8V2O17 is commonly observed as an intermediate phase in the synthesis of compounds in ternary systems of the type Bi2O3-V2O5-MexOy. It is also seen as an end product at particular compositions in these systems. A rhombohedral substructure model for this phase is presented along with electrical parameters. Evidence from the Arrhenius plot suggests a phase transition at around 550 °C. The existence of a limited solid solution of Bi8V2O17 with ZrO2 is also discussed.
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