Mechanical properties at elevated temperature, in modern alloys based on intermetallic phase Ni3Al are connected with phase composition, especially with proportion of ordered phase γ′ (L12) and disordered phase γ (A1). In this paper, analysis of one key systems for mentioned alloys - Ni-Al-Cr, is presented. A series of alloys with chemical composition originated from Ni-rich part of Ni-Al-Cr system was prepared. DTA thermal analysis was performed on all samples. Based on shape of obtained curves, characteristic for continuous order-disorder transition, places of course of phase boundaries γ′+γ / γ were determined. Moreover, temperature of melting and freezing of alloys were obtained. Results of DTA analysis concerning phase boundary γ′+γ / γ indicated agreement with results obtained by authors using calorimetric solution method.
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Using the self-consistent field theory (SCFT) in spherical unit cells of various dimensionalities, D, a phase diagram of a diblock, A-b-B, is calculated in 5 dimensional space, d = 5. This is an extension of a previuos work for d = 4. The phase diagram is parameterized by the chain composition, f, and incompatibility between A and B, quantified by the product chi N. We predict 5 stable nanophases: layers, cylinders, 3D spherical cells, 4D spherical cells, and 5D spherical cells. In the strong segregation limit, that is for large chi, the order-order transition compositions are determined by the strong segregation theory (SST) in its simplest form. While the predictions of the SST theory are close to the corresponding SCFT extrapolations for d = 4, the extrapolations for d = 5 significantly differ from them. We find that the S5 nanophase is stable in a narrow strip between the ordered S4 nanophase and the disordered phase. The calculated orderdisorder transition lines depend weakly on d, as expected.
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Purpose: Purpose of this paper was the study of the microstructure of Fe-38Al alloy after hot deformation with the dislocation structure description. Design/methodology/approach: Methodology of the microstructures research included LM (light microscopy) and TEM (transmission electron microscopy) techniques which has characterized the dislocation structure in these materials. The Fe-38Al alloy has been deformed by torsion plastometer within the range of temperatures from 850°C to 1250°C. All samples has been deformed to rupture. Findings: The findings of this study is that the deformation in this alloy is controlled by dislocation motion. The observed dislocations are predominantly of <100> and <111>. At a deformation temperature of 1100°C TEM observations have shown dislocation loops and helices. In this alloy was observed dynamic recrystalization process during the hot deformation. Practical implications: Practical implications of this research is that this alloy may by deformed in long range of strain in temperatures at 800°C to 1000°C Occure 1100°C the plasticity is limited by order - disorder transformation. This transformation could be responsible for dislocations structure behavior what was found. Originality/value: Value of this paper was important in providing a better understanding of technological plasticity of FeAl alloys. The dislocation and reactions between the defects of the structure play a dominant role and are responsible for the variation of technological plasticity.
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