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Minimization of phenol by natural occurrence adsorbent

100%

Joshi J. , Sahu O.

International Letters of Natural Sciences

2014

tom 11

nr 1

Phenol and chlorophenols are long-lived pollutants frequently found in industrial effluents. Phenols are widely used for the commercial production of a wide variety of resins including phenolic resins, epoxy resins and adhesives, and polyamide for various applications. Adsorption process has been proven one of the best water treatment technologies around the world and the removal of diverse types of pollutants from water. However, widespread use of commercial adsorbent is sometimes restricted due to its higher costs. Attempts have been made to develop inexpensive adsorbents utilizing for the reduction of phenol from water. Four types of adsorbent clay, algae, moringa oleifera and rice husk has been used. Among all rice husk shown 97 % of phenol adsorption at 1mm particle size, pH 4, 3 g/l dosing and 150min contact time.

Removal of Dyes by Adsorption Process Using Date Pits as Material Environmentally Friendly

84%

Adachi A. , El Ouadrhiri F. , El Manssouri I. , Moussaoui F. , El Bourachdi S. , Lahkimi A.

Ecological Engineering & Environmental Technology

2023

tom Vol. 24, iss. 8

181--193

This study is based on the use of a natural material in the adsorption process to remove organic pollutants. The objective is to assess its effectiveness in adsorbing the organic pollutant MB from an aqueous solution, while operating in an open system. The DP bioadsorbent was characterized using FTIR and SEM. To determine their effect on adsorption efficiency, a number of variables were examined, including contact time, concentration of pollutant MB, adsorbent mass, pH, temperature, and adsorbent particle size. The effect of these variables on adsorption efficiency shows that a removal rate of 92.66% is achieved under optimum conditions, including a contact time of 35 minutes, a concentration of pollutant MB of 22.5 mg·l-1, an adsorbent mass (mDP) of 1.1 g·l-1 and a solution pH of 5.6. In addition, a progressive decrease in adsorption efficiency is observed with increasing temperature and adsorbent mass. On the other hand, this efficiency increases with increasing a concentration of pollutant MB. Three popular models, the Freundlich, Langmuir, and Dubin-Radushkevich models, have been used to examine the adsorption isotherms of the MB dye on DP. With a correlation factor of 0.98, it was discovered that MB adsorption monitored by the Freundlich isotherm. The Langmuir and Dubinin-Radushkevich models, however, do not adequately describe the data. The kinetic results were studied using the pseudo-first-order and pseudo-second-order equations, and show that MB dye adsorption on DP (adsorbent) follows the pseudo-second-order model. Also estimated were thermodynamic parameters such as (ΔH°), (ΔS°), (ΔG°), enthalpy, entropy, Gibbs free energy respectively to anticipate the character of adsorption. The results indicate that the adsorption process of MB on the bioadsorbent is exothermic. The results derived from the ΔG° values lead to the conclusion that the adsorption of MB occurs spontaneously.