In this work the identification procedure of intermetallic compounds forming in liquid metallic solutions is presented. Bhatia and Thornton proposal was used; calculations were made on the base of mercury-indium system. Experimental data were described by Pelton polynomials and Krupkowski equations. Executed calculations show the insufficient tenderness of used functions, the course of examined parameters Scc(0) and delta Scc(0) indicates no intermetallic compounds in this system. It is suggested to describe experimental data more subtle methods such spline line functions in the case of this type of systems, with greater number of intermetallic compounds.
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