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Hydrothermal veins linked with the Variscan structure of the Prague Synform (Barrandien, Czech Republic): resolving fluid-wall rock interaction

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Halavínová M. , Melichar R. , Slobodník M.

Geological Quarterly

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2008

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tom Vol. 52, No 4

309-309

EN

Variscan syntectonic hy dro ther mal veins of the Prague Synform are important traces of small-scale fluid migration in Lower Palaeozoic sedimentary rocks — a process induced by late Variscan tectogenesis. Two main structural types of Variscan syntectonic calcite veins were recognised during fieldwork. Veins of Type I have an irregular or sigmoidal shape and are often arranged in en echelon arrays. A shearing regime during the formation of this type is deduced. Veins of a second structural type (Type II) have a more regular and straight shape relative to those of Type I and in some places form a dense network. The structural position of the Type II veins is related to structural elements of Variscan folds. Veins were formed due to interlayer-slip combined with fold- related fracturing that gave rise to the infilling of dilational structures. A tensional regime also permits growth of the fibrous veins. Two princpal directions were distinguished within the Type II veins. The first one is NNW–SSE and the second one shows a perpendicular ENE–WSW orientation. These directions seem to be parallel and/or perpendicular to the nappearchitec ture of the Prague Synform. Variscan syntectonic veins crystallised in a relatively closed, rock-buf fered system. Extraction of chemical components from surrounding rocks is indicated by a combined microprobe/cathodoluminescent study and by isotope geochemistry. The carbon isotope values of hydrothermal calcites reflect the carbon isotope composition of the host rocks. The delta exp.13C values of vein calcites and their host Silurian rocks are between –0.29 and –1.98‰ PDB. The same relationships were found between the veins and the host Devonian limestones (from 1.72 to 2.52‰ PDB). Samples close to the Silurian/Devonian boundary show transition values between 0.25 and + 1.16‰ PDB. The Sr-isotopic signature supports a genetic link between the calcite veins and the host rocks. The 87Sr/86Sr ra tio in calcites ranges between 0.708619 and 0.708738 and in wall rocks be tween 0.708755 and 0.709355. Aqueous and hydrocarbon-rich fluid systems have been found in fluid inclusions. Liquid hydrocarbons show mostly a light blue fluorescence suggesting the presence of higher hydrocarbons. They are more abundant in dark Silurian rocks, which are rich in organic matter. Lower salinities (0.5–8.9 eq. wt.% NaCl) and homogenization temperatures with a maximum around 140gradeC are typ i cal for the aqueous (H2O–NaCl) system. The oxygen isotopic composition of fluids ranges between –2.80 and +3.33‰ SMOW. This indicates that transformed formation waters in teracted with the host rocks and/or deeply circulating isotopically depleted meteoric waters. Intersections with the isochore specify border trapping temperatures between 127 and 160grade C and pressures from 300 to 1070 bars.

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Source rock geochemistry, petrography of reservoir horizons and origin of natural gas in the Devonian of the Lublin and Lviv basins (SE Poland and western Ukraine)

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Radkovets N. Y. , Kotarba M. J. , Wójcik K.

Geological Quarterly

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2017

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tom Vol. 61, No. 3

569--589

EN

The Rock-Eval source rock characteristics, mineral composition and type-porosity of reservoir horizons, and origin of natural gas in the Devonian of the Lublin and Lviv basins are described. In the Lower Devonian, the TOC content ranges from 0.01 to 1.82 wt.% in the Lublin Basin, and from 0.01 to 0.45 wt.% in the Lviv Basin. Transformation of organic matter varies from immature in the Lochkovian (Lviv Basin) to mature and overmature in the Emsian (Lublin Basin). The organic matter contains mainly Type-II kerogen, and underwent primary and/or secondary oxidation processes. In the Middle Devonian, the TOC content varies from 0.00 to 1.63 wt.% in the Lublin Basin, and from 0.02 to 0.64 to 2.35 wt.% in the Lviv Basin. The organic matter contains mainly Type-II kerogen and is immature in the Givetian of the Lviv Basin and mature in the Eifelian of the Lviv Basin and in the Eifelian and Givetian in the Lublin Basin. In the Upper Devonian, the TOC content is from 0.02 to 2.62 wt.% in the Lublin Basin, and from 0.04 to 1.43 wt.% in the Lviv Basin. Type-II kerogen dominates in both basins. Organic matter is mature in the Upper Devonian in the Lublin Basin and in the Famennian of the Lviv Basin and overmature in the Frasnian of the Lviv Basin. The reservoir horizons in the Devonian of the Lublin and Lviv basins are developed in clastic, carbonate and sulphate rocks. Terrigenous rocks form several separate horizons in the Lower and Middle Devonian of the Lviv Basin, and in the Upper Devonian (Famennian) of the Lublin Basin. Their filtration properties relate to intergranular porosity, while the fracture space has subordinate significance. Carbonate rocks form thick saturated horizons in the Givetian in the Lviv Basin, and in the Eifelian, Givetian and Frasnian in the Lublin Basin. Their filtration properties are produced by fracture porosity. Sulphates and carbonate-sulphate rocks with fracture and cavern porosity play a role as reservoir horizons in the Middle Devonian of the Lublin Basin. The natural gas collected from the Upper Devonian of the Lublin Basin was generated mainly during low-temperature thermogenic processes, from Ordovician–Silurian Type-II kerogen. The gas from the Middle Devonian reservoirs of the Lviv Basin was produced from Ordovician–Silurian Type-II kerogen and partly from the Middle and Upper Devonian mixed Type-III/II kerogen with maturity from about 0.9 to 1.4%. Carbon dioxide was formed by both thermogenic and microbial processes. Molecular nitrogen was generated mainly through thermal transformation of organic matter and also from destruction of NH4-rich illite of the clayey facies of the Ordovician–Silurian strata.

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Marine vs. terrestrial environments during Early Triassic deposition on the northeastern margin of the Central European Basin : a multidisciplinary study on the Middle Buntsandstein of the Bartoszyce IG 1 borehole, NE Poland

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Becker A. , Fijałkowska-Mader A. , Jasionowski M.

Geological Quarterly

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2020

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tom Vol. 64, No. 4

1023--1047

EN

The Middle Buntsandstein Subgroup of the Lower Triassic of north-eastern Poland has been investigated in the context of possible marine ingressions into the Central European Basin. To better constrain these, palynofacies analysis and mineralogical analysis of mudstones were undertaken on samples taken from the Lidzbark and Malbork formations penetrated by the Bartoszyce IG 1 borehole, serving as stratotype section of both lithostratigraphic units. Microfacies and geochemical analyses, including C and O isotope analysis, were conducted additionally on oolitic limestones of the basal Lidzbark Formation (the lowermost Middle Buntsandstein), and the boron content was measured on all mudstone samples. Seven palynofacies types are distinguished: types 1 to 3 within the Malbork Formation and types 4 to 7 within the Lidzbark Formation. Types 1 and 2 originated on a floodplain, type 3 probably in a deltaic or barrier setting, and types 4 and 5 in a brackish lagoon or a more open basin, possibly of marine origin. Palynofacies type 6 reflects long transport and reworking, whereas palynofacies type 7 is interpreted as formed due to pedogenic processes. Clay minerals and quartz, accompanied by feldspars, calcite and dolomite are the main components of the mudstones investigated. The clay mineral association consists of illite or a mixture of illite and smectite, and chlorite. The Lidzbark Formation and the lowermost part of the Malbork Formation show less variability in mineralogical composition than the upper part of the Malbork Formation. Smectite admixtures were detected only in the upper part of the Malbork Formation (the uppermost Middle Buntsandstein). The boron content, achieved after aqua regia digestion, ranges from 70 to 121 mg/kg (96 mg/kg at average), oscillating generally around 90 mg/kg. A higher boron content, bound in silicate structure, is associated with the upper part of the Malbork Formation. All major mineralogical and geochemical changes coincide more or less with the transition from the supposed marine to the terrestrial environmental realm, interpreted from lithological and sedimentological observations within the lowermost part of the Malbork Formation. However, diagenetic alteration of the clay minerals, and of the boron content, could not be ruled out. The oolitic limestones, mainly grainstones, contain admixtures of quartz grains and rare bioclasts, the ooids nuclei being peloids or unrecognizable. The carbonates are almost exclusively composed of low-Mg calcite. A high content of Mg and the presence of small amounts of dolomite suggest that the ooids were primarily composed of high-Mg calcite and are comparable with similar Early Triassic deposits in Tethyan settings. The δ13C values range from -2 to +1‰ VPDB, fitting well with the known ranges of Lower Triassic marine carbonates. An observed δ13C depletion towards the top of the oolite-bearing part of the section may reflect a local shallowing trend that led to overall salinity decrease. A possible connection with the one of the global oceanic geochemical episodes has to be tested further. The results obtained suggest a marine origin of the lower Middle Buntsandstein deposits studied and document a terrestrial origin for the upper Malbork Formation.

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K-Ar dating of biotite from the Kudowa Zdroj granitoids [Central Sudetes, SW Poland]

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Bachlinski R. , Halas S.

Bulletin of the Polish Academy of Sciences. Earth Sciences

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2002

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tom 50

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nr 2

5

Calibrated geochemical ages of the Baltic Artesian Basin groundwater

84%

Samalavičius V. , Arustienė J.

Geologos

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2022

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tom Vol. 28, No. 3

179--189

EN

For the present study, geochemical ages were derived from radiocarbon and radiokrypton age calibration with ground-water chemical contents (Na+, K+, Mg2+, Ca2+, Cl−, SO42−, HCO3−). Geochemical ages may fill the dating gap (40–150 ka) between the isotope techniques mentioned. A case study of groundwater in the Baltic Artesian Basin has involved geochemical age calibration, data filtering (such as regional subdivision of the basin for more accurate results) and geochemical dating of groundwater of unknown age. Various approaches to interpretations of geochemical age results could be used. Bicarbonate and sulphate are sensitive to the hydrochemical environment and should be omitted from geochemical age calculations. Modern fresh groundwater samples should also be excluded from calibration in order to obtain more reliable trend lines. Calcium-sodium cation exchange occurs in deep aquifers and may be used for geo- chemical age determination of fossil groundwater.

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Early diagenetic processes in the formation of carbonate-hosted Mn ore deposit [Lower Jurassic, Tatra Mountains] as indicated from its carbon isotopic record

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Krajewski K. P. , Lefeld J. , Lacka B.

Bulletin of the Polish Academy of Sciences. Earth Sciences

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2001

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tom 49

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nr 1

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Badenian [Middle Miocene] Ratyn Limestone in Western Ukraine and Northern Moldavia: microfacies, calcareous nannoplankton and isotope geochemistry

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Peryt T. M. , Peryt D.

Bulletin of the Polish Academy of Sciences. Earth Sciences

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1994

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tom 42

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nr 2

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Oxygen and carbon isotopic changes in the Middle Miocene [Badenian] foraminifera of the Gliwice Area [SW Poland]

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Durakiewicz T. , Gonera M. , Peryt T. M.

Bulletin of the Polish Academy of Sciences. Earth Sciences

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1997

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tom 45

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nr 2-4

9

O poziomie anhydrytowym badenu w utworze wiertniczym Ryszkowa Wola 7 k. Jarosławia (SE Polska)

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Peryt T. M. , Peryt D. , Szaran J. , Hałas S. , Jasionowski M.

Biuletyn Państwowego Instytutu Geologicznego

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1998

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tom nr 379

61-78

PL

Badeńska sukcesja ewaporatowa w otworze Ryszkowa Wola 7 składa się z anhydrytów wykształconych w facji laminowanej oraz brekcjowej. Wartości delta 18O i delta 34S anhydrytów wskazują na morskie pochodzenie jonu siarczanowego. Zespoły otwornicowe w utworach bezpośrednio poniżej poziomu anhydrytowego, a także w obrębie najniższej części anhydrytu, świadczą o redepozycji mikrofauny.

EN

Middle Badenian evaporites of the Carpathian Foredeep basin show a regular spacial pattern of evaporite facies: primary gypsum forming wide sulphate platform (with gypsum sections a few tens of metres thick) occurs in the most marginal, northern part of the Carpathian Foredeep. In more buried, basinward part of the Badenian evaporite basin, the place of primary gypsum is taken by anhydrite (e.g. B. Kubica, 1992) usually 10-30 m thick, and in the narrow axial part of the basin, in local salt basins, halite deposits occur. The depth in halite basins was a few hundred metres (A. Garlicki, 1979), and a part of the salt was deposited through the action of gravity currents (e.g. A. Ślączka, K. Kolasa, 1997). Siliciclastic rocks forming intercalations in halite show the facies variability and sedimentary structures characteristic of turbidites (K. Bukowski,1997). Between the marginal sulphate platform and the axial part a zone occurs where laminated sulphates with sulphate breccia and claystone intercalations occur. The Ryszkowa 7 borehole has been located in the eastern part of the Polish Carpathian Foredeep (Fig. 1). In this part of the foredeep, at the base of the Miocene sequence, thin (20-30 m) transgressive conglomerates, sandstones and claystones occur; they belong to Lower Badenian. Middle Badenian anhydrites that follow are covered by very thick (up to 2,500 m) Upper Badenian and Sarmatian claystones and sandstones (R. Ney et al., 1974). The anhydrite section consists of interbedded laminated and breccia anhydrite (Fig. 2). The anhydrite facies display features characteristic of redeposited sediments. Resedimentation is a relatively common phenomenon observed in modern evaporitic environments and the ancient evaporite sequences. The sulphate originated by precipitation at the air-water interface, with the sulphate particles settling to the bottom as a fine crystal "rain", or by precipitation from the brine body. Subsequently, it could be redeposited in relation to debris flows initiated by the earthquakes. The delta values (delta 18O: 11.26-15.15 promile, delta34S: 20.92-24.18 promile) of anhydrite are shown in Figs. 2-4. They indicate a marine origin of sulphate ion (cf. G. E. Claypool et al., 1980). It is characteristic that the general patterns of changes of delta values of Ryszkowa Wola (the central partof the Carpathian Foredeep) and Borków (the peripheral part) are very similar. Foraminiferal assemblages recorded below anhydrite and in the siliciclastic intercalation in the lowermost part of anhydrite (Pl. I-II) derive from older deposits as well as penecontemporaneous with the deposition of the oldest part of the anhydrite section. Redeposited foraminiferal assemblages related to the Wieliczka salt deposits were earlier found by E. Łuczkowska and J. Rolewicz (1990).

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Warsaw ING PAN Isotope Laboratory research reports. 3. Recrystallization of belemnite rostra and its bearing on Sr isotopic ratios

67%

Zielinski G.

Bulletin of the Polish Academy of Sciences. Earth Sciences

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1998

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tom 46

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nr 2

11

Warsaw ING PAN Isotope Laboratory research reports. 1. Introductory information, facilities, projects

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Burchart J. , Bachlinski R. , Pienkowski A. , Zielinski G.

Bulletin of the Polish Academy of Sciences. Earth Sciences

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1997

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tom 45

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nr 2-4

12

Warsaw ING PAN Isotope Laboratory research reports. 2. Rb-Sr data on the rocks associated with the Suwalki Massif anorthosites

67%

Bachlinski R.

Bulletin of the Polish Academy of Sciences. Earth Sciences

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1997

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tom 45

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nr 2-4