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Discrete-continuum transition at interfaces of nanocomposites

100%

Pyrz R. , Bochenek B.

tom Vol. 55, nr 2

251-260

A number of micromechanical investigations have been performed to predict behaviour of composite interfaces, showing that the detailed behaviour of the material at these interfaces frequently dominates the behaviour of the composite as a whole. The interfacial interaction is an extremely complex process due to continuous evolution of interfacial zones during deformation and this is particularly true for carbon nanotubes since the interfacial interaction is confined to the discrete molecular level. The atomic strain concept based upon Voronoi tessellation allows analyzing the molecular structure atom by atom, which may give a unique insight into deformation phenomena operative at molecular level such as interface behaviour in nanocomposites.

Wetting behavior of Si-13.5B alloy on polycrystalline h-BN-based substrates

88%

Polkowski W. , Sobczak N. , Nowak R. , Kudyba A. , Bruzda G. , Polkowska A. , Homa M. , Turalska P. , Shuleshova O. , Kaban I.

tom Vol. 57, no. 4

321--326

In this work, for the first time the results of an experimental evaluation of the high temperature behavior of molten Si-B alloy in contact with refractory materials at temperatures up to 1750°C, under static argon atmosphere (p = 850– 900 mbar), is shown. The material investigated, having a nominal chemical composition of Si-13.5B (at. %), was fabricated by using the crucible-less electric arc-melting process assisted by the levitation drop method. The wettability of the molten alloy in contact with commercial hexagonal boron nitride (h-BN) substrates was evaluated by means of especially developed sessile drop technique combined with a contact heating procedure. It was found that both couples show a lack of wettability in the whole tested temperature range (the measured contact angle was θ > 130°). The more stable behavior in contact with molten Si-13.B alloy, evidenced by higher θ values and a lack of drop vibration during the high temperature exposition, was observed for the h-BN based composite substrate.

Elastic Wave Behaviour in 2-D Acoustic Interface Superlattices of an Altered Phase

75%

Kapelewski J. , Lila B.

nr 3

Modeling of surface properties of metallurgical solutions: steels, slags and steel-slag systems

51%

Iwanciw J. , Pytel K. , Kawecka-Cebula E. , Kostołowska M.

tom Vol. 53, iss. 2

575-581

The aim of the study was elaboration of a model for prediction of the surface properties of such metallurgical solutions like steels, slags and for steel/slag interfaces for broad range of chemical compositions of the phases and temperatures. There have been carried out the following steps: (i) constructing of the data base for the systems in question, (ii) working out the program for establishing of the equilibrium conditions (chemical compositions) for metal/slag systems, (iii) elaboration of the computer programs for prediction of surface tensions for the systems as follows: metal/gas, slag/gas and metal/slag. The models, constructed by the authors, allow to present results in form of either model equations, Excel sheets or graphic plots.

Celem artykułu było opracowanie modelu dla prognozowania właściwości powierzchniowych roztworów metalurgicznych takich jak stale, żużle oraz układu metal/żużel dla szerokiego zakresu składów chemicznych faz oraz temperatur. Przepro- wadzono następujące kroki: – opracowano bazę danych w układzie pytań, – opracowano program do ustalania warunków równowagowych (skład chemiczny) dla układu metal/żużel, – opracowano program do prognozowania napięcia powierzch- niowego dla układów takich jak: metal/gaz, żużel/gaz, metal/żużel. Zaproponowany model pozwolił na oszacowanie napięcia powierzchniowego w zakresie od 30 do 85 mN/m, przy standardowym zakresie odchylenia. Model opracowany przez autorów pozwala na zaprezentowanie uzyskanych wyników w postaci innych równań modelowych, arkuszy Excela oraz wykresów graficznych.