Wyniki wyszukiwania - Biblioteka Nauki

Nowa wersja platformy, zawierająca wyłącznie zasoby pełnotekstowe, jest już dostępna.
Przejdź na https://bibliotekanauki.pl

Ograniczanie wyników

1 Polish Journal of Environmental Studies

1 2003

Znaleziono wyników: 1

Liczba wyników na stronie

Wyniki wyszukiwania

Wyszukiwano:
w słowach kluczowych: hydrodehalogenation

Sortuj według:

Ogranicz wyniki do:

Catalytic conversion CCI3F and CCI2F2 over metal supported catalysts

100%

Kirszensztejn P. , Wachowski L. , Szymkowiak A. , Marciniak P. , Czajka B. , Skupinski W.

Polish Journal of Environmental Studies

2003

tom 12

nr 3

A comparison of the catalytic properties of metals (Pt, Pd and Ru) supported on carbon in the process of catalytic hydrogenolysis of the C-halogen bond in CCl₂F₂ (CFC-12) and CCl₃F (CFC-11) was made. The mechanism of the halogen substitution in the catalytic conversion of CCl₃F was found to differ from that proposed for CCl₂F₂. The catalysts with Ru as the active phase were characterized by much lower activity than those with Pt or Pd, and the main products of conversion in the two reactions were CHClF₂ and CHCl₂F, so the products of substitution of only one chlorine atom in the molecule were obtained, in contrast to the case when Pt or Pd were used.