The speed of ustrasound is and densities of ethanol + syclohexane mixtures were measured in the whole concentration range at 293.15K. The adiabatic compressibility coefficients and excess molar volumes, as well as the mean molecular radii, free intermolecular lenght and internal pressures were determined for the binaries. The dependance of the exess molar volumes and exess internal pressures on the mixture composition were compared and discussed in terms of the free intermolecular lenght and other factors affecting the self-association of the athanol and structural changes of the solvent.
The speeds of ultrasound in and densities of 3-methylopyrazole with cyclohexane mixtures were measured in the whole concetration range at 293.15 and 313.15 K. The Excess molar volumes, free volumes excess volumes and diabatic copressibilty coefficients, as well as the free intermolecular lenghts were determinated for the binaries. The dependance of the excess molar volumes and excess free volumes on the mixture composition were compared and discussed in terms of the free intermolecular lenght and other factors affecting the self-association of 3-methylopyrazole and structural changes of the non-polar solvent. Search Site
The speed of ulrtasound in and densities of binary solutions of ethanol, propan-2-ol and 2-methylopropan-2-ol in cyclohexane were measured on the whole concentration range at 293.15K. The excess molar volumes, free volumies, excess free volumes and adiabatic cmpressibility coeffcients, as well as the free intermolecular lenghts were determined for binaries. The dependance of the excess molar volumes and excess free volumes on the mixture composition were compared and discussed in terms of the intermolecular lenght and other factors afecting the self-association of alcohols and structural changes od the solvent.
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