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EN
We present the characterisation and distribution of organic matter (OM) within the sea surface microlayer (SML) and underlying water (ULW) collected in October 2015 at nine stations in the Baltic Sea, Gulf of Gdańsk, encompassing the Vistula River plume. The salinity of >7 throughout the transect indicated Vistula plume was possibly displaced westward by the preceding northerly and easterly winds between 5.7 and 10.7 ms–1 during the sampling campaign. Spectral analysis pointed to the highest contribution of aromatic and high molecular weight molecules (lowest spectral slope (SR) ratios and highest absorption coefficient at 254 nm (aCDOM(254)) at the first two stations near the river mouth, demonstrating a very limited influence of the river plume. Concentrations of surface-active organic substances (SAS) ranged from 0.28 to 0.60 mg L−1 in eq. Triton-X-100 in SML, and from 0.22 to 0.47 mg L−1 in eq. Triton-X-100 in the ULW, while POC concentrations ranged from 0.27 to 0.84 mg L−1 in SML and from 0.20 to 0.37 mg L−1 in ULW. Enrichment of SAS and POC detected at the highest wind speeds indicates rapid SML recovery by OM transported from the ULW. Low lipids to POC contribution, on average 5% and 7% in SML and ULW respectively, points to eutrophic conditions. Statistically significant negative correlation between SR and the Lipid:PIG ratio in SML and ULW suggests the production of lower molecular weight OM by phytoplankton living under favourable environmental conditions. Accumulation of lipid reserves triacylglycerols (TG) in the SML indicates more stressful plankton growth conditions compared to ULW.
EN
The present paper dealt with the annual dynamics of the absorption coefficient of chromophoric dissolved organic matter at 440 nm {aCDOM(440)} during February 2015 to January 2016 in the continental shelf of northern Bay of Bengal (nBoB) for the first time. Sea surface salinity (SSS), chlorophyll-a (Chl-a), total suspended matter (TSM) were also analyzed. It was hypothesized that CDOM should exhibit significant spatial and temporal variability in this region. aCDOM(440) and spectral slope ranged between 0.1002 m1—0.6631 m1 and 0.0071 nm1— 0.0229 nm1 respectively during the entire study period. Higher values of aCDOM(440) were observed in the near shore stations and gradually decreased towards the offshore. Significant seasonal variability of aCDOM(440) was observed between the monsoon and non-monsoon seasons ( p < 0.05). Thus the framed hypothesis was successfully accepted by means of the present study. The CDOM was mainly found to be of allochthonous character in this region. aCDOM(440) portrayed a significant negative linear relationship with SSS (R2 = 0.80; p < 0.05) implying conservative mixing of marine and terrestrial end members. However, examining the spatial variability of the relationship, it was observed that this relationship was significant only in the nearshore stations. While examining the seasonal variability of this relationship, it was found to be most significant during the monsoon (R2 = 0.81; p < 0.05). Thus it was inferred that whenever the SSS gradient was higher, the relationship between aCDOM(440) and SSS was found to be most significant.
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