Electronic and vibrational spectroscopies were applied to the study of the strength of the donor-acceptor interaction and optical properties of the complexes of C-60 with two TTF-derived donors, i.e. bis(methylthio)ethylenedithio-tetrathiafulvalene (C-1TET- TTF) and tetramethyltetraselenafulvalene (TMTSF). The investigations of the single crystalline samples, for various light polarizations and temperatures, were performed. The analysis of all the spectral data shows that the investigated compounds are weak complexes with a neutral ground state.
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