Technological hall where installation for wastewater from fish processing SUPERFISH plant treatment is located is not insulated. Therefore coagulation process during the whole year is carried out in various temperature conditions. This paper presents results of the research on efficiency of coagulation process with application of calcium hydroxide PIX-111 in various temperature conditions. Samples of wastewater ware taken after flotation node form pretreatment installation in SUPERFISH fish processing plant. Then wastewater underwent coagulation process with application of calcium hydroxide (dose 2 g/dm3), as a first variant, and PIX- 111 reagent (dose 0.35 g/dm3 as used in SUPERFISH pretreatment installation), as a second variant. Coagulation process was carried out in three temperatures: T1 = 3.5°C, T2 = 11°C and T3 = 21°C. After coagulation and sedimentation following parameters were determined: pH [-],biochemical oxygen demand BOD [mg O2/dm3], chemical oxygen demand COD [mg O2/dm3], total organic carbon TOC [mg/dm3], total suspension Z [mg/dm3], dissolved substances SR [mg/dm3] and conductivity S [mS/cm]. On the basis of gained research results it may be stated, that PIX-111 showed decidedly smaller variations of determined parameters values, than calcium hydroxide, which is a result of dissolubility of both reagents. Especially bigger dissolubility of calcium hydroxide in lower temperatures. Clear qualitative difference of wastewater after process of coagulation with calcium hydroxide and PIX-111 reagent in low temperatures (3.5°C) was affirmed. Most of wastewater pollution parameters reached smaller values in low temperatures (which prevails during autumn, winter and spring) in process of coagulation with calcium hydroxide, than with PIX-111 reagent, which, most probably, is connected with the inappropriate range of pH of this coagulant application. That is why in order to obtain values of pollution parameters within the range of standards in treated wastewater from SUPERFISH plant in dependence on temperature of coagulation process, PIX-111 reagent should be given up or apply in lower temperatures calcium hydroxide . Also in order to increase effectiveness of PIX-111 it is necessary to correct pH before coagulation with e.g. calcium hydroxide. In higher temperatures of coagulation process (21°C - average temperature in summer) with calcium hydroxide and PIX-111 reagent values of considered pollution parameters in wastewater are similar.
Celem pracy przedstawionej w ninniejszej publikaacji jest opracowwanie technologii oczyszczania poprodukcyjnych ścieków do jakości wody technologicznej , którą będzie można zawrócić do procesu produkcyjnego
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Autoclaved gas concrete is counted to group of light concretes, which volumetric density does not exceed 2 000 kg/m3. There are several methods of production of the typical gas concrete applied in Poland. Components are only domestic mineral materials: binder - cement with the lime or lime itself, aggregate - sand or the mixture of sand with ash or ash from coal burning in power stations; fluffing agent: crumbled aluminum. Reaction of aluminum with calcium hydroxide, coming into being as the result of lime hydration or hydrolysis of cement, causes emission of hydrogen fluffs the mass passing through it and makes possible creation of pores. The air replaces hydrogen in fluffed mass. At present post-production wastewater from PREFABET in Reda is treated in the system, which is presented in the Figure 1. The aim of investigations, presented in this paper, was to work out technology of post-production wastewater treatment to the quality of technological water which can be turned back to production process [7]. Results of investigations of basic contamination parameters of raw wastewater from PREFABET Company in Reda coming from autoclaves are presented in Table 1. There are many methods of industrial wastewater treatment [1,3, 4,5]. Wastewater coming from PRFABET Company were treated under laboratory conditions according to the technology proposed by Authors shown in Figure 2. Overflow from the process of gravitational sedimentation currently piped off to sewage system or to the sludge drying bet located on the terrain of the company does not meet the standards. Furthermore sediments after process of gravitational sedimentation on filter sand makes up currently secondary waste, stored on a heap. Also demand for gas concrete increasing lately on the construction market causes the necessity to increase production, and at the same time causes creation of larger quantities of post-production wastewater. Technology of post-production wastewater treatment proposed by Authors solves presented problems. Post-production wastewater treated according to proposed technology is characterized by 100% reduction of contamination parameters: absorbance, turbidity, biochemical oxygen demand, total organic carbon and ether extract. 99% of reduction was noted for chemical oxygen demand, 63% for total suspension, and 41% for dissolved substances and dry residues. So treated wastewater may again be used in the process of gas concrete production, while dewatered sediments may be utilized in the process of solidification as the addition to the production of plates and cobble stones
3
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Reactions of electron transport in a nitrification route. Nitrification bacteria and their environments. Specification of technological parameters of active sludge. Chemical analysis of tested sewage.
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Composition and analysis of examination results for the influence of the bed height, average diameter of grains and the level of sewage pollution introduced on the filtrate value, referring to ChZT, generał suspension, organie carbon and ether extract.
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Określono skuteczność oczyszczania ścieków z produkcji środków czystości w zintegrowanym układzie oczyszczania łączącym ultrafiltrację i wymianę jonową. Badania zrealizowano na ceramicznym module o granicznej rozdzielczości 5 kDa oraz makroporowatych i żelowych żywicach jonowymiennych. Szczególnie efektywny okazał się zintegrowany układ oczyszczania z makroporowatą magnetyczną żywicą MIEX. Uzyskano obniżenie stężenia anionowych substancji powierzchniowo czynnych i związków organicznych na poziomie 97% i 82%. Proces regeneracji wysyconych żywic jonowymiennych pozwolił na ich wielokrotne wykorzystanie w zintegrowanym układzie oczyszczania.
EN
Three com. ion-exchange resins were used to remove anionic surfactants, org. matter and dyes from surfactants-contg. wastewaters treated previously by ultrafiltration through a ceramic module (cut-off of 5 kDa). The most effective was a macropourous strong base resin. The removal of surfactants and org. matter amounted to 97% and 82%, resp. The spent resins were regenerated by an alk. treatment and recycled.
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W artykule przedstawiono wyniki badań laboratoryjnych nad oczyszczaniem ścieków powstających podczas produkcji drewnianych okien, zawierających duże ilości polioctanu winylu i kopolimeru winylu. Ścieki oczyszczano w układzie chemiczno-biologicznym. Jako pierwszy stopień zastosowano proces chemicznego pogłębionego utleniania odczynnikiem Fentona, a następnie ścieki doczyszczano w porcjowym reaktorze biologicznym SBR. W trakcie prowadzonych badań analizowano warunki panujące w reaktorach oraz wpływ dozowanych ścieków po procesie Fentona na efektywność oczyszczania oraz przebieg poszczególnych procesów biochemicznych w poszczególnych fazach procesowych cyklu SBR. Wprowadzenie chemicznego utleniania zanieczyszczeń, jako pre-oksydacji okazało się efektywną metodą zmniejszenia stężenia substancji organicznych w ściekach klejowych (>80%) oraz umożliwiło ich dalsze skuteczne doczyszczanie w procesach biologicznych.
EN
Results of laboratory tests on the treatment of sewage generated during the manufacture of wooden windows, containing large amounts of polyvinyl chloride and vinyl copolymer. Waste water is purified in a chemical-biological system. As a first step chemical process was used Fenton reagent advanced oxidation and cleaning of waste water in the biological reactor SBR. In the course of the study analyzed the conditions in the reactors and the impact of water dispensed by Fenton's process on the effectiveness of treatment and the course of the various biochemical processes in the various phases of the SBR process cycle.
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