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2 Physicochemical Problems of Mineral Processing

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Recovery of major components of spent zinc electrolyte with di(2-ethylhexyl)phosphoric acid (DEHPA) used as a zinc(II) extractant

100%

Gotfryd L. , Pietek G. , Szołomicki Z. , Becker K.

2014

tom Vol. 50, iss. 1

311--325

Industrial acidic zinc electrolyte has been treated with calcium compounds and/or concentrated ammonia solution and resulting crystalline phases as well as equilibrium mother liquors were analyzed in detail for dependence on preliminary dilution of electrolyte with water. Neutralized zinc electrolyte was an object of investigation in zinc(II) extraction with di(2-ethylhexyl)phosphoric acid (DEHPA) as an extractant. Dependencies of zinc(II) and contaminants extraction on equilibrium pH, isotherms of zinc(II) extraction and stripping have been studied. During simulated laboratory counter-current trial of zinc extraction a new zinc electrolyte (stripped solution) has been produced. Raffinates left after the process were purified and qualified as mineral magnesium-ammonium fertilizer solutions.

Direct measurements of reaction time for extractive processes

88%

Gotfryd L. , Becker K. , Pietek G. , Szołomicki Z. , Piwowonska J.

tom Vol. 52, iss. 2

909--919

Extraction times for selected metal cations (Mg2+, Al3+, Zn2+, Cd2+, Cu2+, Ni2+, Co2+, Mn2+, Fe2+ and Fe3+) have been measured using cation-exchanging extractants - Versatic 10 (neodecanoic acid), DEHPA (bis(2-ethylhexyl)phosphoric acid) and Cyanex 272 (bis(2,4,4-trimetylpentyl)phosphinic acid). Data was collected directly by measuring and recording pH of the two phase reaction mixture with maintaining continuity of the aqueous phase. Similarly, the stripping rate of selected cations (Mg2+, Al3+, Zn2+, Cu2+, Ni2+, Co2+) in a sulphuric acid solution was measured. Viscosities of organic phases, saturated with cations, were measured before their stripping. Additionally, the extraction dependence of Mg2+, Al3+, Fe2+ and Fe3+ on pH was measured using Versatic 10 at various concentrations (7.5, 15 and 30 %).