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Structural and optical properties of Dy3+ doped Sr2SiO4 phosphors

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Verma D. , Patel R. P. , Verma M. L.

Materials Science Poland

2019

tom Vol. 37, No. 1

55--64

Dysprosium doped strontium silicate phosphor namely (Sr2SiO4:Dy3+) was prepared by low-temperature solution combustion method using urea (CO(NH2)2) as a fuel. The material was characterized by powder X-ray diffraction (XRD), FT-IR, SEM and EDX. The average crystallite sizes was calculated by Scherer formula. Thermoluminescence study was carried out for the phosphor which showed single glow curve. The kinetic parameter were calculated by using Chen’s glow curve method. Photoluminescence spectra revealed strong transition at 473 nm (blue), 571 nm (yellow) and weak transition at 645 nm (red). These peaks were assigned to transition 4F9/2 → 6H15/2, 13/2 , 11/2. CIE graph of Sr2SiO4:Dy3+phosphor is suitable for the generation of white light emission.

Optical properties of Sr2SiO4:Eu2+, Dy3+ phosphors prepared by combustion method

100%

Verma D. , Patel R. P. , Verma M. L.

Materials Science Poland

2018

tom Vol. 36, No. 3

387--396

In the present paper, TL and PL study of Dy3+ doped Sr2SiO4:Eu2+ phosphor is reported. A polycrystalline sample of Sr2SiO4:Eu2+, Dy3+ was prepared by combustion method. The obtained phosphor was characterized by powder X-ray diffraction, scanning electron microscopy, UV-Vis spectroscopy, PL and thermoluminescence. The results of the XRD studies obtained for Sr2SiO4:Eu2+, Dy3+ phosphor revealed its monoclinic structure. The average crystallite size was calculated as 12.77 nm. Thermoluminescence study was carried out for the phosphor using UV irradiation and a single glow peak was found. The thermoluminescence glow curves of the samples were measured at various concentrations of co-dopant. The kinetic parameter has been calculated using Chen’s glow curve method. In this paper, the photoluminescence and afterglow behaviour of these phosphors are reported.